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1.
公开(公告)号:US08289125B2
公开(公告)日:2012-10-16
申请号:US13111194
申请日:2011-05-19
申请人: Atsushi Kishimoto , Hayato Katsu , Masato Goto , Naoaki Abe , Akinori Nakayama
发明人: Atsushi Kishimoto , Hayato Katsu , Masato Goto , Naoaki Abe , Akinori Nakayama
IPC分类号: H01C7/10
CPC分类号: H01C7/025 , C04B35/4682 , C04B35/6262 , C04B35/62645 , C04B2235/3201 , C04B2235/3203 , C04B2235/3208 , C04B2235/3224 , C04B2235/3227 , C04B2235/3262 , C04B2235/3298 , C04B2235/6584 , C04B2235/79 , C04B2235/87 , Y10T428/256
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. The molar ratio m between the A site and the B site satisfies 1.001≦m≦1.01. Part of Ba constituting the A site is replaced with Bi, Ca, a rare-earth element, and Na. The molar content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.05 to 0.20 (preferably 0.125 to 0.175). A PTC thermistor includes a component body formed of the semiconductor ceramic. Accordingly, there is provided a lead-free semiconductor ceramic that substantially does not contain lead and that has desired PTC characteristics and high reliability.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构的作为主要成分的基于BamTiO 3的组合物。 A位点和B位点之间的摩尔比m满足1.001≦̸ m≦̸ 1.01。 构成A位点的Ba的一部分被Bi,Ca,稀土元素和Na代替。 构成A位点的元素的总摩尔数为1摩尔时的摩尔含量为0.05〜0.20(优选为0.125〜0.175)。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 因此,提供了一种基本上不含铅并具有期望的PTC特性和高可靠性的无铅半导体陶瓷。
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2.
公开(公告)号:US20110215895A1
公开(公告)日:2011-09-08
申请号:US13111085
申请日:2011-05-19
申请人: Masato Goto , Hayato Katsu , Naoaki Abe , Atsushi Kishimoto , Akinori Nakayama
发明人: Masato Goto , Hayato Katsu , Naoaki Abe , Atsushi Kishimoto , Akinori Nakayama
CPC分类号: C04B35/638 , C04B35/4682 , C04B2235/3201 , C04B2235/3208 , C04B2235/3213 , C04B2235/3225 , C04B2235/3262 , C04B2235/3272 , C04B2235/3281 , C04B2235/3298 , C04B2235/3418 , C04B2235/604 , C04B2235/6584 , C04B2235/72 , C04B2235/79 , C04B2235/85 , C04B2235/9661 , H01C7/025 , Y10T428/252
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. Part of Ba constituting an A site is replaced with at least an alkali metal element, Bi, and a rare-earth element, and the molar ratio m between the A site and a B site is 0.990≦m≦0.999 (preferably 0.990≦m≦0.995). Preferably, part of the Ba is replaced with Ca, and the content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.042 to 0.20 (preferably 0.125 to 0.175) on a molar basis. A PTC thermistor includes a component body formed of the semiconductor ceramic. Accordingly, there are provided satisfactory rise characteristics even if an alkali metal element is present.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构的作为主要成分的基于BamTiO 3的组合物。 构成A位置的Ba的一部分被至少一种碱金属元素Bi和稀土元素代替,并且A位点和B位点之间的摩尔比m为0.990& NlE; m≦̸ 0.999(优选0.990&nlE ; m≦̸ 0.995)。 优选地,将Ba的一部分替换为Ca,当构成A位点的元素的总摩尔数为1摩尔时,Ca的含量为摩尔比为0.042〜0.20(优选为0.125〜0.175)。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 因此,即使存在碱金属元素,也提供令人满意的升高特性。
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3.
公开(公告)号:US20110234364A1
公开(公告)日:2011-09-29
申请号:US13154601
申请日:2011-06-07
申请人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
发明人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
CPC分类号: H01C7/025 , C04B35/46 , C04B35/4682 , C04B2235/3201 , C04B2235/3208 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3262 , C04B2235/3298 , C04B2235/6584 , C04B2235/79
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3, wherein part of Ba constituting the A site is replaced with Na, Bi, Ca, and a rare-earth element having an ionic radius smaller than that of the Na; the content of the rare-earth element when the total number of moles of the elements constituting the A site is 1 mole is 0.0005 to 0.015 on a molar basis; and the content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.05 to 0.20 (preferably 0.125 or more and 0.175 or less) on a molar basis. A PTC thermistor includes a component body 1 formed of the semiconductor ceramic. Accordingly, high reliability is achieved even if an alkali metal element is present.
摘要翻译: 半导体陶瓷包括作为主要成分的作为主要成分的具有由通式AmBO 3表示的钙钛矿结构的基于BamTiO 3的组合物,其中构成A位的Ba的一部分被Na,Bi,Ca和具有 离子半径小于Na; 当构成A位点的元素的总摩尔数为1摩尔时,稀土元素的含量为摩尔计为0.0005〜0.015。 当构成A位点的元素的总摩尔数为1摩尔时,Ca的含量为摩尔为0.05〜0.20(优选为0.125以上且0.175以下)。 PTC热敏电阻包括由半导体陶瓷形成的部件主体1。 因此,即使存在碱金属元素,也可实现高的可靠性。
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4.
公开(公告)号:US20110215894A1
公开(公告)日:2011-09-08
申请号:US13111194
申请日:2011-05-19
申请人: Atsushi Kishimoto , Hayato Katsu , Masato Goto , Naoaki Abe , Akinori Nakayama
发明人: Atsushi Kishimoto , Hayato Katsu , Masato Goto , Naoaki Abe , Akinori Nakayama
CPC分类号: H01C7/025 , C04B35/4682 , C04B35/6262 , C04B35/62645 , C04B2235/3201 , C04B2235/3203 , C04B2235/3208 , C04B2235/3224 , C04B2235/3227 , C04B2235/3262 , C04B2235/3298 , C04B2235/6584 , C04B2235/79 , C04B2235/87 , Y10T428/256
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. The molar ratio m between the A site and the B site satisfies 1.001≦m≦1.01. Part of Ba constituting the A site is replaced with Bi, Ca, a rare-earth element, and Na. The molar content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.05 to 0.20 (preferably 0.125 to 0.175). A PTC thermistor includes a component body formed of the semiconductor ceramic. Accordingly, there is provided a lead-free semiconductor ceramic that substantially does not contain lead and that has desired PTC characteristics and high reliability.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构的作为主要成分的基于BamTiO 3的组合物。 A位点和B位点之间的摩尔比m满足1.001≦̸ m≦̸ 1.01。 构成A位点的Ba的一部分被Bi,Ca,稀土元素和Na代替。 构成A位点的元素的总摩尔数为1摩尔时的摩尔含量为0.05〜0.20(优选为0.125〜0.175)。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 因此,提供了一种基本上不含铅并具有期望的PTC特性和高可靠性的无铅半导体陶瓷。
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5.
公开(公告)号:US08350662B2
公开(公告)日:2013-01-08
申请号:US13154601
申请日:2011-06-07
申请人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
发明人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
IPC分类号: H01C7/10
CPC分类号: H01C7/025 , C04B35/46 , C04B35/4682 , C04B2235/3201 , C04B2235/3208 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3262 , C04B2235/3298 , C04B2235/6584 , C04B2235/79
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3, wherein part of Ba constituting the A site is replaced with Na, Bi, Ca, and a rare-earth element having an ionic radius smaller than that of the Na; the content of the rare-earth element when the total number of moles of the elements constituting the A site is 1 mole is 0.0005 to 0.015 on a molar basis; and the content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.05 to 0.20 (preferably 0.125 or more and 0.175 or less) on a molar basis. A PTC thermistor includes a component body 1 formed of the semiconductor ceramic. Accordingly, high reliability is achieved even if an alkali metal element is present.
摘要翻译: 半导体陶瓷包括作为主要成分的作为主要成分的具有由通式AmBO 3表示的钙钛矿结构的基于BamTiO 3的组合物,其中构成A位点的Ba的一部分被Na,Bi,Ca和具有 离子半径小于Na; 当构成A位点的元素的总摩尔数为1摩尔时,稀土元素的含量为摩尔计为0.0005〜0.015。 当构成A位点的元素的总摩尔数为1摩尔时,Ca的含量为摩尔为0.05〜0.20(优选为0.125以上且0.175以下)。 PTC热敏电阻包括由半导体陶瓷形成的部件主体1。 因此,即使存在碱金属元素,也可实现高的可靠性。
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6.
公开(公告)号:US08284013B2
公开(公告)日:2012-10-09
申请号:US13111085
申请日:2011-05-19
申请人: Masato Goto , Hayato Katsu , Naoaki Abe , Atsushi Kishimoto , Akinori Nakayama
发明人: Masato Goto , Hayato Katsu , Naoaki Abe , Atsushi Kishimoto , Akinori Nakayama
IPC分类号: H01C7/10
CPC分类号: C04B35/638 , C04B35/4682 , C04B2235/3201 , C04B2235/3208 , C04B2235/3213 , C04B2235/3225 , C04B2235/3262 , C04B2235/3272 , C04B2235/3281 , C04B2235/3298 , C04B2235/3418 , C04B2235/604 , C04B2235/6584 , C04B2235/72 , C04B2235/79 , C04B2235/85 , C04B2235/9661 , H01C7/025 , Y10T428/252
摘要: A semiconductor ceramic includes a BamTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. Part of Ba constituting an A site is replaced with at least an alkali metal element, Bi, and a rare-earth element, and the molar ratio m between the A site and a B site is 0.990≦m≦0.999 (preferably 0.990≦m≦0.995). Preferably, part of the Ba is replaced with Ca, and the content of the Ca when the total number of moles of the elements constituting the A site is 1 mole is 0.042 to 0.20 (preferably 0.125 to 0.175) on a molar basis. A PTC thermistor includes a component body formed of the semiconductor ceramic. Accordingly, there are provided satisfactory rise characteristics even if an alkali metal element is present.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构的作为主要成分的基于BamTiO 3的组合物。 构成A位置的Ba的一部分被至少一种碱金属元素Bi和稀土元素代替,并且A位点和B位点之间的摩尔比m为0.990< NlE; m< lE; 0.999(优选为0.990&nlE ; m≦̸ 0.995)。 优选地,将Ba的一部分替换为Ca,当构成A位点的元素的总摩尔数为1摩尔时,Ca的含量为摩尔比为0.042〜0.20(优选为0.125〜0.175)。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 因此,即使存在碱金属元素,也提供令人满意的升高特性。
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7.
公开(公告)号:US08228161B2
公开(公告)日:2012-07-24
申请号:US13104298
申请日:2011-05-10
申请人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
发明人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
IPC分类号: H01C7/10
CPC分类号: C04B35/4682 , C04B35/638 , C04B2235/3201 , C04B2235/3208 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3262 , C04B2235/3272 , C04B2235/3281 , C04B2235/3298 , C04B2235/3418 , C04B2235/604 , C04B2235/6584 , C04B2235/72 , C04B2235/79 , C04B2235/85 , C04B2235/9661 , H01C7/025 , Y10T428/2993
摘要: A semiconductor ceramic includes a BaTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. Part of the A site Ba is replaced with an alkali metal element, Bi, Ca, Sr, and a rare-earth element. When the molar amounts of Ca and Sr are x and y, respectively, and the total number of moles of the elements constituting the A site is 1 mole, 0.05≦x≦0.20, 0.02≦y≦0.12, and 2x+5y≦0.7. A PTC thermistor includes a component body formed of the semiconductor ceramic. Even when an alkali metal element and Bi are present, there is provided a lead-free semiconductor ceramic with high reliability in which the surface discoloration is not caused and the degradation of resistance over time can be suppressed even after the application of an electric current for a long time.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构作为主要成分的基于BaTiO 3的组合物。 A部位的一部分Ba被碱金属元素Bi,Ca,Sr和稀土元素代替。 当Ca和Sr的摩尔量分别为x和y,并且构成A位点的元素的总摩尔数为1摩尔,0.05和1埃; x和nlE; 0.20,0.02和nlE; y和nlE; 0.12和2x + 5y ; 0.7。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 即使存在碱金属元素和Bi,也可以提供无可靠性的无铅半导体陶瓷,其中不会引起表面变色,即使在施加电流以后也可以抑制电阻随时间的劣化 很长时间。
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8.
公开(公告)号:US20110210815A1
公开(公告)日:2011-09-01
申请号:US13104298
申请日:2011-05-10
申请人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
发明人: Naoaki Abe , Hayato Katsu , Masato Goto , Atsushi Kishimoto , Akinori Nakayama
CPC分类号: C04B35/4682 , C04B35/638 , C04B2235/3201 , C04B2235/3208 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3262 , C04B2235/3272 , C04B2235/3281 , C04B2235/3298 , C04B2235/3418 , C04B2235/604 , C04B2235/6584 , C04B2235/72 , C04B2235/79 , C04B2235/85 , C04B2235/9661 , H01C7/025 , Y10T428/2993
摘要: A semiconductor ceramic includes a BaTiO3-based composition, as a main component, having a perovskite structure represented by general formula AmBO3. Part of the A site Ba is replaced with an alkali metal element, Bi, Ca, Sr, and a rare-earth element. When the molar amounts of Ca and Sr are x and y, respectively, and the total number of moles of the elements constituting the A site is 1 mole, 0.05≦x≦0.20, 0.02≦y≦0.12, and 2x+5y≦0.7. A PTC thermistor includes a component body formed of the semiconductor ceramic. Even when an alkali metal element and Bi are present, there is provided a lead-free semiconductor ceramic with high reliability in which the surface discoloration is not caused and the degradation of resistance over time can be suppressed even after the application of an electric current for a long time.
摘要翻译: 半导体陶瓷包括具有由通式AmBO 3表示的钙钛矿结构作为主要成分的基于BaTiO 3的组合物。 A部位的一部分Ba被碱金属元素Bi,Ca,Sr和稀土元素代替。 当Ca和Sr的摩尔量分别为x和y,并且构成A位点的元素的总摩尔数为1摩尔,0.05和1埃; x和nlE; 0.20,0.02和nlE; y和nlE; 0.12和2x + 5y ; 0.7。 PTC热敏电阻包括由半导体陶瓷形成的部件体。 即使存在碱金属元素和Bi,也可以提供无可靠性的无铅半导体陶瓷,其中不会引起表面变色,即使在施加电流之后也可以抑制电阻随时间的劣化 很长时间。
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9.
公开(公告)号:US08390421B2
公开(公告)日:2013-03-05
申请号:US13326706
申请日:2011-12-15
申请人: Atsushi Kishimoto , Wataru Aoto , Akinori Nakayama
发明人: Atsushi Kishimoto , Wataru Aoto , Akinori Nakayama
IPC分类号: H01C7/10
CPC分类号: H01C7/025 , C04B35/4682 , C04B2235/3208 , C04B2235/3258 , C04B2235/77 , C04B2235/79 , H01C17/06533
摘要: A semiconductor ceramic and a positive-coefficient characteristic thermistor are provided which have a stable PTC characteristic, a high double point, and a wide operating temperature range. The semiconductor ceramic contains, as a main component, a barium titanate-based composition having a perovskite structure expressed by a general formula AmBO3. Out of 100 mol % of the Ti, an amount in a range of 0.05 mol % or more to 0.3 mol % or less of Ti is replaced with W as a semiconductor forming agent, the ratio m of A sites mainly to B sites is 0.99≦m≦1.002, and an actually-measured sintered density is 70% or more and 90% or less of the theoretical sintered density. In the positive-coefficient characteristic thermistor, a component body is formed of the semiconductor ceramic.
摘要翻译: 提供了具有稳定的PTC特性,高双点和宽工作温度范围的半导体陶瓷和正系数特性热敏电阻。 半导体陶瓷作为主要成分含有具有由通式AmBO 3表示的钙钛矿结构的钛酸钡类组合物。 在100摩尔%的Ti中,作为半导体形成剂的W被替换为0.05摩尔%以上至0.3摩尔%以下的Ti的量,作为主要部位的A部位的比例m为0.99 ≦̸ m≦̸ 1.002,实际测量的烧结密度为理论烧结密度的70%以上且90%以下。 在正系数特性热敏电阻中,由半导体陶瓷形成元件体。
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10.
公开(公告)号:US20120081206A1
公开(公告)日:2012-04-05
申请号:US13326706
申请日:2011-12-15
申请人: Atsushi Kishimoto , Wataru Aoto , Akinori Nakayama
发明人: Atsushi Kishimoto , Wataru Aoto , Akinori Nakayama
CPC分类号: H01C7/025 , C04B35/4682 , C04B2235/3208 , C04B2235/3258 , C04B2235/77 , C04B2235/79 , H01C17/06533
摘要: A semiconductor ceramic and a positive-coefficient characteristic thermistor are provided which have a stable PTC characteristic, a high double point, and a wide operating temperature range. The semiconductor ceramic contains, as a main component, a barium titanate-based composition having a perovskite structure expressed by a general formula AmBO3. Out of 100 mol % of the Ti, an amount in a range of 0.05 mol % or more to 0.3 mol % or less of Ti is replaced with W as a semiconductor forming agent, the ratio m of A sites mainly to B sites is 0.99≦m≦1.002, and an actually-measured sintered density is 70% or more and 90% or less of the theoretical sintered density. In the positive-coefficient characteristic thermistor, a component body is formed of the semiconductor ceramic.
摘要翻译: 提供了具有稳定的PTC特性,高双点和宽工作温度范围的半导体陶瓷和正系数特性热敏电阻。 半导体陶瓷作为主要成分含有具有由通式AmBO 3表示的钙钛矿结构的钛酸钡类组合物。 在100摩尔%的Ti中,作为半导体形成剂的W被替换为0.05摩尔%以上至0.3摩尔%以下的Ti的量,作为主要部位的A部位的比例m为0.99 ≦̸ m≦̸ 1.002,实际测量的烧结密度为理论烧结密度的70%以上且90%以下。 在正系数特性热敏电阻中,由半导体陶瓷形成元件体。
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