摘要:
An optical recording material for an optical recording medium capable of recording information by irradiation of light including: a cation represented by the following general formula (1); and a chelate compound formed by an azo compound and a metal, wherein at least one of R1, R2, R3 and R4 is an optionally substituted benzyl group, and at least one of R5 and R6 is an optionally substituted alkyl group having a carbon number of at least 5 or an optionally substituted aryl group having a carbon number of at least 5.
摘要:
The present invention aims to provide a coating liquid for producing an optical recording medium that can record large volumes of data and can respond sufficiently to high speed writing, a method for producing an optical recording medium using the same, and an optical recording medium. The coating liquid for use in a method for producing an optical recording medium according one embodiment of the invention contains a solvent and a pigment dissolved in the solvent. The solvent includes TFP and/or OFP and an aliphatic saturated alcohol having 1-4 carbon atoms by 0.01-10% by mass relative to the total amount of the solvent, and the pigment includes the compound represented by the following general formula (1) and a chelate compound consisting of an azo compound and a metal. [where, each of R11, R12, R13 and R14 (hereinafter, represented as “R11-R14”) represents independently from one another a benzyl group that may have a substituent or an alkyl group having 1-4 carbon atoms, R15 represents a trimethine chain that may have a substituent, each of R16 and R17 represents independently from each other a group of atoms that constitute a benzene ring that may have a substituent or a naphthalene ring that may have a substituent, and each of R18 and R19 represents independently from each other an aryl group that may have a substituent or an alkyl group having 1-4 carbon atoms, provided that at least one group among R11, R12, R13 and R14 is not a methyl group. In this case, respective carbons of R11 and R12 and/or R13 and R14 may make a bond to form a 3- to 6-membered ring.]
摘要:
The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要:
The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要:
A photoelectric conversion device capable of improving conversion efficiency is provided. The photoelectric conversion device includes a work electrode, a counter electrode, and an electrolyte-containing layer. In the work electrode, a metal oxide semiconductor layer supporting a dye is provided. The dye contains a cyanine compound. The cyanine compound has heterocyclic skeletons containing indolenine skeletons bonded with both ends of a methine chain, an anchor group introduced to a nitrogen atom contained in the indolenine skeletons, and a phenanthrene skeleton contained in one of the heterocyclic skeletons. In the case where light enters the dye, electron injection efficiency to the metal oxide semiconductor layer is improved.
摘要:
An optical recording material used in an optical recording medium capable of recording information by irradiation of light, which comprises a cation represented by general formula (1a) below and a chelate compound of an azo compound and a metal, the content ratio of the chelate compound being 10 to 70 mole percent based on the total of the cation and the chelate compound, wherein R1, R2, R3, R4, R5 and R6 each independently represent C1-4 alkyl, etc., R7 represents hydrogen, etc. and Q1 and Q2 each independently represent a group of atoms constituting a benzene ring, etc., with the proviso that at least one from among R1, R2, R3 and R4 is a non-methyl group.
摘要:
A photoelectric conversion device capable of improving conversion efficiency is provided. The photoelectric conversion device includes a work electrode, a counter electrode, and an electrolyte-containing layer. In the work electrode, a metal oxide semiconductor layer supporting a dye is provided. The dye contains a cyanine compound. The cyanine compound has heterocyclic skeletons containing indolenine skeletons bonded with both ends of a methine chain, an anchor group introduced to a nitrogen atom contained in the indolenine skeletons, and a phenanthrene skeleton contained in one of the heterocyclic skeletons. In the case where light enters the dye, electron injection efficiency to the metal oxide semiconductor layer is improved.
摘要:
Provided is a photoelectric conversion device capable of improving a conversion efficiency. In a dye-sensitized photoelectric conversion device including a working electrode and a facing electrode, and an electrolyte inclusion, a dye is carried on a metal-oxide semiconductor layer of the working electrode. The dye includes cyanine dye having a benzyl group and an indolenine skeleton. Therefore, crystallization of the dye on the surface of the metal-oxide semiconductor layer is suppressed.
摘要:
Provided is a photoelectric conversion device capable of improving a conversion efficiency. In a dye-sensitized photoelectric conversion device including a working electrode and a facing electrode, and an electrolyte inclusion, a dye is carried on a metal-oxide semiconductor layer of the working electrode. The dye includes cyanine dye having a benzyl group and an indolenine skeleton. Therefore, crystallization of the dye on the surface of the metal-oxide semiconductor layer is suppressed.
摘要:
A photoelectric conversion device capable of improving conversion efficiency is provided. The photoelectric conversion device includes a work electrode, an opposed electrode, and an electrolyte-containing layer. In the work electrode, a metal oxide semiconductor layer supporting a dye is provided. The dye contains a cyanine compound that has a methine chain, an indolenine skeleton bonded with both ends of the methine chain, and anchor groups introduced to a nitrogen atom included in the indolenine skeleton. Electron injection efficiency to the metal oxide semiconductor layer is improved, and the dye is hardly exfoliated from the metal oxide semiconductor layer.