公开(公告)号：US20100243060A1

公开(公告)日：2010-09-30

申请号：US12659741

申请日：2010-03-19

申请人： Tokuhiko Handa ,  Atsushi Monden

发明人： Tokuhiko Handa ,  Atsushi Monden

IPC分类号： H01L31/00 ,  H01L31/04 ,  H01L31/18

CPC分类号： H01G9/204 ,  H01G9/2059 ,  H01L51/0026 ,  H01L51/0064 ,  Y02E10/542 ,  Y02P70/521

摘要： An electrode for photoelectric conversion elements having high initial characteristics and excellent durability, a manufacturing method of the electrode for photoelectric conversion elements, and a dye-sensitized solar cell are provided. An electrode for photoelectric conversion elements according to the present invention has a structure in which a metal oxide layer containing zinc oxide is provided on a base. The metal oxide layer has a plurality of bump-like protrusions formed so as to protrude radially from the base side, and also has an emission peak in a region of 350 to 400 nm in cathodoluminescence measurement. The metal oxide layer is preferably heat treated at 220 to 500° C.

摘要翻译： 提供具有高初始特性和优异耐久性的光电转换元件用电极，用于光电转换元件的电极的制造方法和染料敏化太阳能电池。 根据本发明的用于光电转换元件的电极具有在基底上设置含有氧化锌的金属氧化物层的结构。 金属氧化物层具有形成为从基底侧径向突出的多个凸起状突起，并且在阴极发光测定中也具有350〜400nm的区域的发光峰。 金属氧化物层优选在220〜500℃下热处理。

公开(公告)号：US20090038676A1

公开(公告)日：2009-02-12

申请号：US12078042

申请日：2008-03-26

申请人： Atsushi Monden ,  Tokuhiko Handa

发明人： Atsushi Monden ,  Tokuhiko Handa

IPC分类号： H01L31/00 ,  C25D5/00 ,  C25D5/48

CPC分类号： H01G9/204 ,  H01G9/2004 ,  H01G9/2059 ,  H01L2251/306 ,  Y02E10/542 ,  Y02P70/521

摘要： There are disclosed a photoelectric conversion electrode having a large amount of a dye to be supported and an excellent dye replacement property and having a capability of improving a photoelectric conversion efficiency, a manufacturing method of the photoelectric conversion electrode and the like. A photoelectric conversion electrode 11 according to the present invention can be manufactured by laminating a porous metal oxide layer 14 including a metal oxide and a dye on a substrate 12 having a conductive surface 12a, and the metal oxide layer 14 has a specific surface area of 70 to 250 m2/g and a void ratio of 50 to 75%. Specifically, the metal oxide layer 14 can be formed by a cathode electrolytic deposition process using an electrolyte containing a metal salt and 80 to 500 μM of template dye, the template dye co-adsorbed on the metal oxide layer 14 is desorbed, and a sensitizing dye different from the template dye is more preferably re-adsorbed.

摘要翻译： 公开了具有大量待负载的染料和优异的染料替代性能并且具有提高光电转换效率的能力的光电转换电极，光电转换电极的制造方法等。 根据本发明的光电转换电极11可以通过在具有导电表面12a的基板12上层压包含金属氧化物和染料的多孔金属氧化物层14，并且金属氧化物层14的比表面积 70〜250m 2 / g，空隙率为50〜75％。 具体地说，金属氧化物层14可以通过使用含有金属盐的电解质和80〜500μm的模板染料的阴极电解沉积法形成，共吸附在金属氧化物层14上的模板染料被解吸， 与模板染料不同的染料更优选被再吸附。

公开(公告)号：US20080236658A1

公开(公告)日：2008-10-02

申请号：US12078040

申请日：2008-03-26

申请人： Tokuhiko Handa ,  Atsushi Monden

发明人： Tokuhiko Handa ,  Atsushi Monden

IPC分类号： H01L31/0224 ,  H01L31/04 ,  B05D1/00 ,  C25D5/00

CPC分类号： C25D15/02 ,  C25D9/08 ,  H01G9/2027 ,  H01G9/2059 ,  Y02E10/542 ,  Y02P70/521

摘要： There are disclosed an electrode having a large amount of a dye to be supported, having an excellent dye replacement property and having a capability of improving a photoelectric conversion efficiency, a manufacturing method of the electrode and a dye-sensitized solar cell including the electrode. An electrode 11 according to the present invention includes a dye-supported layer 14 laminated on a substrate 12 and including zinc oxide and a dye. The dye-supported layer 14 has at least a plurality of bump-like protrusions formed so that zinc oxide protrudes radially from the substrate 12, or satisfies represented by the following formula (1): 2≦I002/I101≦12, in which I002 is a peak intensity attributed to a zinc oxide (002) face in X-ray diffraction measurement of the dye-supported layer 14, and I101 is a peak intensity attributed to a zinc oxide (101) face in the X-ray diffraction measurement.

摘要翻译： 公开了具有大量待负载的染料，具有优异的染料替代性并具有提高光电转换效率的能力的电极，电极的制造方法和包括该电极的染料敏化太阳能电池。 根据本发明的电极11包括层叠在基板12上并包含氧化锌和染料的染料负载层14。 染料负载层14具有形成为使得氧化锌从基板12径向突出的多个凸起状突起，或满足下式（1）所示的2个以上的隆起状突起：2 <= 1 002 染料负载型的X射线衍射测定中归属于氧化锌（002）面的峰强度为/ 层14和I 101是在X射线衍射测量中归因于氧化锌（101）面的峰强度。

公开(公告)号：US07218506B2

公开(公告)日：2007-05-15

申请号：US11089227

申请日：2005-03-25

申请人： Masaaki Kobayashi ,  Atsushi Monden ,  Tokuhiko Handa

发明人： Masaaki Kobayashi ,  Atsushi Monden ,  Tokuhiko Handa

IPC分类号： H01G9/00

CPC分类号： H01G9/042 ,  H01G9/0032 ,  H01G9/15 ,  Y10T29/41 ,  Y10T29/417

摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.

摘要翻译： 本发明提供一种电解电容器制造方法，其能够制造尽可能容易地具有PTC功能的电解电容器。 阴极中的主电极层形成为具有PTC功能。 与将PTC热敏电阻连接到电容器元件以将PTC功能连接到电解电容器的常规电解电容器制造方法不同，使得电解电容器制造工艺复杂并且制造工艺的数量增加了对应于PTC的量 热敏电阻连接工艺，不需要将PTC热敏电阻连接到电容器元件的过程。 因此，可以防止电解电容器制造工艺的复杂化和由PTC热敏电阻连接工艺引起的制造工艺数量的增加。

公开(公告)号：US06842103B2

公开(公告)日：2005-01-11

申请号：US10443757

申请日：2003-05-23

申请人： Yukie Yoshinari ,  Tokuhiko Handa

发明人： Yukie Yoshinari ,  Tokuhiko Handa

IPC分类号： H01C7/02 ,  H01C17/065 ,  H01C7/10

CPC分类号： H01C17/06586 ,  H01C7/027

摘要： In an organic PTC thermistor comprising a thermistor body comprising a high-molecular weight organic compound-containing matrix and metal particles, conductive non-metallic fines, typically carbon black, are attached to surfaces of the metal particles. The device has a low room-temperature resistance and a high change rate of resistance, and prevents degradation of its performance during storage under hot humid conditions.

摘要翻译： 在包含含有高分子量含有机化合物的基质和金属颗粒的热敏电阻体的有机PTC热敏电阻中，金属颗粒的表面附着有导电的非金属微粒（通常为炭黑）。 该装置具有低的室温电阻和高的电阻变化率，并且防止在热潮湿条件下储存期间其性能的降低。

公开(公告)号：US5470628A

公开(公告)日：1995-11-28

申请号：US340340

申请日：1994-11-14

申请人： Junji Tominaga ,  Susumu Haratani ,  Tokuhiko Handa ,  Ryo Inaba

发明人： Junji Tominaga ,  Susumu Haratani ,  Tokuhiko Handa ,  Ryo Inaba

IPC分类号： G11B7/0045 ,  G11B7/0055 ,  G11B7/24 ,  G11B7/241 ,  G11B7/243 ,  G11B7/257 ,  B32B3/00

CPC分类号： G11B7/252 ,  G11B7/00454 ,  G11B7/00557 ,  G11B7/24 ,  G11B2007/24306 ,  G11B2007/24308 ,  G11B2007/2431 ,  G11B2007/24312 ,  G11B2007/24314 ,  G11B2007/24316 ,  G11B2007/25706 ,  G11B2007/25708 ,  G11B2007/2571 ,  G11B2007/25713 ,  G11B2007/25715 ,  G11B2007/25716 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2542 ,  G11B7/2595 ,  Y10S428/913 ,  Y10S430/146

摘要： An optical recording medium has a mask layer 4, an intermediate dielectric layer 5, a recording layer 6, and a reflective layer 8 on a transparent substrate 2. The recording layer 6 contains a recording material which changes its crystallographic structure upon exposure to recording light for recording information. The mask layer 4 contains a mask material which increases its light transmittance when melted and has a complex refractive index (n.sub.0 -ik.sub.0), of which the real part n.sub.0 drops by 1.0 or less and the imaginary part k.sub.0 drops by 0.25-1.0 when the mask material converts from a crystalline state to an amorphous or microcrystalline state. Signals can be reproduced from the medium with high C/N without resorting to reading light of shorter wavelength or an optical pickup objective lens having a larger numerical aperture and even when the linear velocity of the medium relative to recording and reproducing light is low.

摘要翻译： 光学记录介质在透明基板2上具有掩模层4，中间介电层5，记录层6和反射层8.记录层6包含在曝光到记录光时改变其结晶结构的记录材料 用于记录信息。 掩模层4包含当熔化时增加其透光率并且具有复数折射率（n0-ik0）的掩模材料，其中实部n0下降1.0或更小，虚部k0下降0.25-1.0 掩模材料从晶体状态转变为非晶态或微晶状态。 信号可以从具有高C / N的介质再现，而不需要使用较短波长的读取光或具有较大数值孔径的光学拾取物镜，甚至当介质相对于记录和再现光的线速度较低时。

公开(公告)号：US20100243045A1

公开(公告)日：2010-09-30

申请号：US12659493

申请日：2010-03-10

申请人： Masahiro Tsuchiya ,  Miki Murai ,  Tokuhiko Handa ,  Masahiro Shinkai

发明人： Masahiro Tsuchiya ,  Miki Murai ,  Tokuhiko Handa ,  Masahiro Shinkai

IPC分类号： H01L31/00 ,  H01L31/18 ,  H01L31/0296

CPC分类号： H01G9/2009 ,  H01G9/2004 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521

摘要： To provide a photoelectric conversion device that has excellent photoelectric conversion efficiency and enhanced reliability without wide variations in performance. A manufacturing method of a photoelectric conversion device that includes a working electrode having a dye-supported metal oxide layer, a counter electrode disposed so as to face the working electrode, and an electrolyte layer enclosed between the working electrode and the counter electrode, includes: a step of preparing an electrolyte sheet in which an electrolyte is retained by a reticulated support member; and a step of enclosing the electrolyte sheet between the working electrode and the counter electrode.

摘要翻译： 提供具有优异的光电转换效率和增强的可靠性而不会出现性能变化的光电转换装置。 一种光电转换装置的制造方法，其特征在于，包括：具有染料负载型金属氧化物层的工作电极，与上述工作电极相对配置的对置电极以及包围在上述工作电极与对置电极之间的电解质层的制造方法， 制备其中电解质被网状支撑构件保持的电解质片的步骤; 以及将电解质片包围在工作电极和对电极之间的步骤。

公开(公告)号：US20080236659A1

公开(公告)日：2008-10-02

申请号：US12078041

申请日：2008-03-26

申请人： Atsushi Monden ,  Tokuhiko Handa

发明人： Atsushi Monden ,  Tokuhiko Handa

IPC分类号： H01L31/0224 ,  H01L31/04 ,  C25D5/10

CPC分类号： H01G9/2027 ,  H01G9/2059 ,  H01L51/0006 ,  H01L51/4233 ,  Y02E10/542 ,  Y02P70/521

摘要： There are disclosed a photoelectric conversion electrode having a large amount of a dye to be supported and an excellent dye replacement property and capability of improving a mechanical strength and a photoelectric conversion efficiency. In a photoelectric conversion electrode 11 according to the present invention, on a substrate 12 having a conductive surface 12a, an underlayer 13 containing a metal oxide and a porous metal oxide layer 14 including a metal oxide and a dye can be prepared by an electrolytic deposition process, and an electrolysis potential of the underlayer 13 is set to a potential or less of a flection point having a minimum potential among a plurality of flection points observed in a range of 0 to −1.5 V (vs. Ag/AgCl) in a current-potential profile during electrolytic deposition, whereby the underlayer is formed so that pointed crystal particles 13a of the metal oxide are piled up in a layer thickness direction.

摘要翻译： 公开了一种具有大量待负载染料的光电转换电极，并且具有优异的染料替代性和提高机械强度和光电转换效率的能力。 在根据本发明的光电转换电极11中，在具有导电表面12a的基板12上，含有金属氧化物的底层13和包含金属氧化物的多孔金属氧化物层14和染料可以通过电解 沉积工艺，并且底层13的电解电位被设定为在0至-1.5V（相对于Ag / AgCl）的范围内观察到的多个反射点中具有最小电位的反射点的电位或更小的电位 电解沉积期间的电流 - 电位分布，由此形成底层，使得金属氧化物的尖晶体颗粒13a在层厚度方向上堆积。

公开(公告)号：US07414515B2

公开(公告)日：2008-08-19

申请号：US11508924

申请日：2006-08-24

申请人： Noriaki Hirano ,  Kunio Mogi ,  Tsutomu Hatakeyama ,  Tsukasa Kon ,  Tokuhiko Handa ,  Hisanao Tosaka

发明人： Noriaki Hirano ,  Kunio Mogi ,  Tsutomu Hatakeyama ,  Tsukasa Kon ,  Tokuhiko Handa ,  Hisanao Tosaka

IPC分类号： H01C10/48

CPC分类号： H05B3/146 ,  H01C1/1406 ,  H01C7/02 ,  H01C7/027 ,  H05B2203/02

摘要： An object is to provide a PTC element capable of preventing lead terminals from delaminating from an element body. This PTC element 1 is a PTC element comprising an element body 10 in which an electroconductive filler is dispersed in a crystalline polymer, and a pair of terminal electrodes 12, 14 thermocompression-bonded with the element body 10 in between, wherein each of the pair of terminal electrodes 12, 14 has an overlapping region 121, 141 overlapping with the element body 10, and a nonoverlapping region 122, 142 not overlapping with the element body 10, and wherein the nonoverlapping region 122, 142 of each of the pair of terminal electrodes 12, 14 is constructed of a succession of a wide portion 122a a width of which is large across a direction in which the terminal electrode 12, 14 extends from the element body 10, and a narrow portion 122b a width of which is smaller than the width of the wide portion 122a.

摘要翻译： 目的在于提供能够防止引线端子从元件体分层的PTC元件。 该PTC元件1是包括元件体10的PTC元件，其中导电填料分散在结晶聚合物中，以及一对与其间的元件体10热压粘合的端子电极12,14，其中每对 端子电极12,14具有与元件主体10重叠的重叠区域121,141以及与元件主体10不重叠的非重叠区域122,142，并且其中每对端子的非重叠区域122,142 电极12,14由一连串的宽度部分122a构成，宽度部分122a的宽度在端子电极12,14从元件体10延伸的方向上较大，其宽度小于 宽部分122a的宽度。

公开(公告)号：US07245479B2

公开(公告)日：2007-07-17

申请号：US11634126

申请日：2006-12-06

申请人： Masaaki Kobayashi ,  Atsushi Monden ,  Tokuhiko Handa

发明人： Masaaki Kobayashi ,  Atsushi Monden ,  Tokuhiko Handa

IPC分类号： H01G9/00

CPC分类号： H01G9/042 ,  H01G9/0032 ,  H01G9/15 ,  Y10T29/41 ,  Y10T29/417

摘要： The present invention provides an electrolytic capacitor manufacturing method capable of manufacturing an electrolytic capacitor having the PTC function as easy as possible. A main electrode layer in a cathode is formed so as to have the PTC function. Different from a conventional electrolytic capacitor manufacturing method of connecting a PTC thermistor to a capacitor element to give the PTC function to an electrolytic capacitor so that an electrolytic capacitor manufacturing process is complicated and the number of manufacturing processes is increased by the amount corresponding to the PTC thermistor connecting process, the process of connecting the PTC thermistor to the capacitor element is unnecessary. Consequently, complication of the electrolytic capacitor manufacturing process and increase in the number of manufacturing processes caused by the PTC thermistor connecting process can be prevented.