Process for producing 1,3-propanediol

    公开(公告)号:US20060124545A1

    公开(公告)日:2006-06-15

    申请号:US11352593

    申请日:2006-02-13

    IPC分类号: B01D11/00

    摘要: Disclosed herein are processes for the recovery of 1,3-propanediol from an aqueous feed stream. The present invention involves contacting an aqueous feed stream that comprises water, 1,3-propanediol, and at least one contaminant with at least one solvent extractant to form a mixture. The mixture is separated into a first phase and a second phase. The second phase comprises a majority of the water from the aqueous feed stream. The first phase comprises solvent extractant and at least some of the 1,3-propanediol that was present in the aqueous feed stream. The weight ratio in the first phase of 1,3-propanediol to any one contaminant present is greater than the weight ratio of 1,3-propanediol to the same contaminant in the aqueous feed stream prior to the aqueous feed stream being contacted with the solvent extractant. The first phase can be removed from the separated second phase in order to recover the 1,3-propanediol.

    Process for the recovery of citric acid
    2.
    发明申请
    Process for the recovery of citric acid 失效
    回收柠檬酸的方法

    公开(公告)号:US20060247468A1

    公开(公告)日:2006-11-02

    申请号:US10548171

    申请日:2004-03-03

    IPC分类号: C07C59/265

    摘要: The invention provides a process for the recovery of citric acid from an aqueous solution feed stream originating in fermentation of carbohydrates and utilizing an amine solvent extraction step for separation of impurities comprising: subjecting said aqueous solution feed stream A to a treatment for partial recovery of citric acid, wherein said treatment is other than amine solvent extraction, to form a first portion of purified citric acid B and a secondary feed stream F; subjecting at least a portion G of said secondary feed stream F to a treatment consisting of amine solvent extraction to form a second portion of purified citric acid solution and to reject substantial of impurities initially present in said portion of said secondary feed stream; subjecting said second portion of purified citric acid solution to crystallization; and recycling mother liquor from said crystallization.

    摘要翻译: 本发明提供了一种从源于碳水化合物发酵的水溶液进料流中回收柠檬酸的方法,并利用胺溶剂萃取步骤分离杂质,其包括:使所述水溶液进料流A处理部分回收柠檬酸 酸,其中所述处理不是胺溶剂萃取,以形成纯化柠檬酸B的第一部分和第二进料流F; 使至少一部分G的所述二次进料流F经受由胺溶剂萃取组成的处理以形成第二部分纯化的柠檬酸溶液并且排除最初存在于所述第二进料流的所述部分中的大量杂质; 对所述第二部分纯化柠檬酸溶液进行结晶; 并从所述结晶中回收母液。

    PROCESS FOR THE RECOVERY OF CITRIC ACID
    3.
    发明申请
    PROCESS FOR THE RECOVERY OF CITRIC ACID 审中-公开
    柠檬酸回收方法

    公开(公告)号:US20080161601A1

    公开(公告)日:2008-07-03

    申请号:US12049994

    申请日:2008-03-17

    IPC分类号: C07C51/00

    摘要: The invention provides a process for the recovery of citric acid from an aqueous solution feed stream originating in germination of carbohydrates and utilizing an amine solvent extraction step for separation of impurities comprising: subjecting said aqueous solution feed stream A to a treatment for partial recovery of citric acid, wherein said treatment is other than amine solvent extraction, to form a first portion of purified citric acid B and a secondary feed stream F; subjecting at least a portion G of said secondary feed stream F to a treatment consisting of amine solvent extraction to form a second portion of purified citric acid solution and to reject substantial of impurities initially present in said portion of said secondary feed stream; subjecting said second portion of purified citric acid solution to crystallization; and recycling mother liquor from said crystallization.

    摘要翻译: 本发明提供了一种从源于碳水化合物发芽的水溶液进料流中回收柠檬酸的方法,并利用胺溶剂萃取步骤分离杂质,其包括:使所述水溶液进料流A处理部分回收柠檬酸 酸,其中所述处理不是胺溶剂萃取,以形成纯化柠檬酸B的第一部分和第二进料流F; 使至少一部分G的所述二次进料流F经受由胺溶剂萃取组成的处理以形成第二部分纯化的柠檬酸溶液并且排除最初存在于所述第二进料流的所述部分中的大量杂质; 对所述第二部分纯化柠檬酸溶液进行结晶; 并从所述结晶中回收母液。

    Process for the recovery of citric acid
    4.
    发明授权
    Process for the recovery of citric acid 失效
    回收柠檬酸的方法

    公开(公告)号:US07411090B2

    公开(公告)日:2008-08-12

    申请号:US10548171

    申请日:2004-03-03

    IPC分类号: C07C51/42 C07C55/00

    摘要: The invention provides a process for the recovery of citric acid from an aqueous solution feed stream originating in fermentation of carbohydrates and utilizing an amine solvent extraction step for separation of impurities comprising: subjecting said aqueous solution feed stream A to a treatment for partial recovery of citric acid, wherein said treatment is other than amine solvent extraction, to form a first portion of purified citric acid B and a secondary feed stream F; subjecting at least a portion G of said secondary feed stream F to a treatment consisting of amine solvent extraction to form a second portion of purified citric acid solution and to reject substantial of impurities initially present in said portion of said secondary feed stream; subjecting said second portion of purified citric acid solution to crystallization; and recycling mother liquor from said crystallization.

    摘要翻译: 本发明提供了一种从源于碳水化合物发酵的水溶液进料流中回收柠檬酸的方法,并利用胺溶剂萃取步骤分离杂质,其包括:使所述水溶液进料流A处理部分回收柠檬酸 酸,其中所述处理不是胺溶剂萃取,以形成纯化柠檬酸B的第一部分和第二进料流F; 使至少一部分G的所述二次进料流F经受由胺溶剂萃取组成的处理以形成第二部分纯化的柠檬酸溶液并且排除最初存在于所述第二进料流的所述部分中的大量杂质; 对所述第二部分纯化柠檬酸溶液进行结晶; 并从所述结晶中回收母液。

    Process for producing 1, 3-propanediol
    5.
    发明授权
    Process for producing 1, 3-propanediol 有权
    1,3-丙二醇生产方法

    公开(公告)号:US07056439B2

    公开(公告)日:2006-06-06

    申请号:US10430498

    申请日:2003-05-06

    IPC分类号: B01D11/00 C07C7/10

    摘要: Disclosed herein are processes for the recovery of 1,3-propanediol from an aqueous feed stream. The present invention involves contacting an aqueous feed stream that comprises water, 1,3-propanediol, and at least one contaminant with at least one solvent extractant to form a mixture. The mixture is separated into a first phase and a second phase. The second phase comprises a majority of the water from the aqueous feed stream. The first phase comprises solvent extractant and at least some of the 1,3-propanediol that was present in the aqueous feed stream. The weight ratio in the first phase of 1,3-propanediol to any one contaminant present is greater than the weight ratio of 1,3-propanediol to the same contaminant in the aqueous feed stream prior to the aqueous feed stream being contacted with the solvent extractant. The first phase can be removed from the separated second phase in order to recover the 1,3-propanediol.

    摘要翻译: 本文公开了从含水原料流中回收1,3-丙二醇的方法。 本发明涉及将包含水,1,3-丙二醇和至少一种污染物的含水进料流与至少一种溶剂萃取剂接触以形成混合物。 将混合物分离成第一相和第二相。 第二相包含来自含水进料流的大部分水。 第一阶段包括溶剂萃取剂和存在于含水进料流中的至少一些1,3-丙二醇。 在水性进料流与溶剂接触之前,1,3-丙二醇与任何一种污染物的第一相中的重量比大于1,3-丙二醇与含水进料流中相同污染物的重量比 萃取剂。 为了回收1,3-丙二醇,可以将第一相从分离的第二相中除去。

    Process for producing 1,3-propanediol
    6.
    发明授权
    Process for producing 1,3-propanediol 有权
    1,3-丙二醇生产工艺

    公开(公告)号:US07572376B2

    公开(公告)日:2009-08-11

    申请号:US11352593

    申请日:2006-02-13

    IPC分类号: B01D11/00 C07C31/18

    摘要: Disclosed herein are processes for the recovery of 1,3-propanediol from an aqueous feed stream. The present invention involves contacting an aqueous feed stream that comprises water, 1,3-propanediol, and at least one contaminant with at least one solvent extractant to form a mixture. The mixture is separated into a first phase and a second phase. The second phase comprises a majority of the water from the aqueous feed stream. The first phase comprises solvent extractant and at least some of the 1,3-propanediol that was present in the aqueous feed stream. The weight ratio in the first phase of 1,3-propanediol to any one contaminant present is greater than the weight ratio of 1,3-propanediol to the same contaminant in the aqueous feed stream prior to the aqueous feed stream being contacted with the solvent extractant. The first phase can be removed from the separated second phase in order to recover the 1,3-propanediol.

    摘要翻译: 本文公开了从含水原料流中回收1,3-丙二醇的方法。 本发明涉及将包含水,1,3-丙二醇和至少一种污染物的含水进料流与至少一种溶剂萃取剂接触以形成混合物。 将混合物分离成第一相和第二相。 第二相包含来自含水进料流的大部分水。 第一阶段包括溶剂萃取剂和存在于含水进料流中的至少一些1,3-丙二醇。 在水性进料流与溶剂接触之前,1,3-丙二醇与任何一种污染物的第一相中的重量比大于1,3-丙二醇与含水进料流中相同污染物的重量比 萃取剂。 为了回收1,3-丙二醇,可以将第一相从分离的第二相中除去。

    METHODS AND SYSTEMS FOR PROCESSING A SUCROSE CROP AND SUGAR MIXTURES
    7.
    发明申请
    METHODS AND SYSTEMS FOR PROCESSING A SUCROSE CROP AND SUGAR MIXTURES 有权
    用于加工蔗糖和糖混合物的方法和系统

    公开(公告)号:US20140190470A1

    公开(公告)日:2014-07-10

    申请号:US13807479

    申请日:2011-06-28

    IPC分类号: C13K11/00 C13K1/02

    摘要: A method comprising: (a) providing a partially processed sucrose crop product containing at least 2% optionally at least 5% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin; (b) hydrolyzing said partially processed crop product with HCl to produce an acid hydrolyzate stream and a lignin stream; and (c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution and an HCl recovery stream. Additional, methods, systems and sugar mixtures are also disclosed.

    摘要翻译: 一种方法,包括:(a)提供部分加工的蔗糖作物产品,其在干固体收获时提供含有至少2%任选至少5%的所述作物蔗糖含量的纤维素和木质素; (b)用HCl水解所述部分加工的作物产物以产生酸水解产物流和木质素流; 和(c)使所述水解产物流脱酸以产生脱酸糖溶液和HCl回收流。 还公开了方法,系统和糖混合物。

    Methods and systems for processing a sucrose crop and sugar mixtures
    8.
    发明授权
    Methods and systems for processing a sucrose crop and sugar mixtures 有权
    用于加工蔗糖作物和糖混合物的方法和系统

    公开(公告)号:US09476106B2

    公开(公告)日:2016-10-25

    申请号:US13807479

    申请日:2011-06-28

    摘要: A method comprising: (a) providing a partially processed sucrose crop product containing at least 2% optionally at least 5% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin; (b) hydrolyzing said partially processed crop product with HCl to produce an acid hydrolyzate stream and a lignin stream; and (c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution and an HCl recovery stream. Additional, methods, systems and sugar mixtures are also disclosed.

    摘要翻译: 一种方法,包括:(a)提供部分加工的蔗糖作物产品,其在干固体收获时提供含有至少2%任选至少5%的所述作物蔗糖含量的纤维素和木质素; (b)用HCl水解所述部分加工的作物产物以产生酸水解产物流和木质素流; 和(c)使所述水解产物流脱酸以产生脱酸糖溶液和HCl回收流。 还公开了方法,系统和糖混合物。

    PROCESS FOR THE PRODUCTION OF TITANIUM SALTS
    9.
    发明申请
    PROCESS FOR THE PRODUCTION OF TITANIUM SALTS 失效
    生产钛盐的方法

    公开(公告)号:US20100257977A1

    公开(公告)日:2010-10-14

    申请号:US12666947

    申请日:2008-06-29

    申请人: Asher Vitner

    发明人: Asher Vitner

    IPC分类号: C22B34/12 C01G23/00

    摘要: The present invention provides a method for the Industrial production of a titanium salt TP, said method comprising the steps of: i. Precipitation of titanic acid from a solution comprising titanium salt TP1; ii. Production of a titanium containing product TP2 from a medium comprising of said titanic acid and an acid; and iii. Thermal conversion of titanium containing product TP3 to a titanium salt TP at temperature higher than 17O° C.

    摘要翻译: 本发明提供了钛盐TP的工业化生产方法,所述方法包括以下步骤: 从包含钛盐TP1的溶液中沉淀钛酸; ii。 从包含所述钛酸和酸的介质中制备含钛产物TP2; 和iii。 含钛产物TP3在高于170℃的温度下热转化成钛盐TP

    Process for the production of aspartic acid condensate
    10.
    发明授权
    Process for the production of aspartic acid condensate 失效
    生产天冬氨酸缩合物的方法

    公开(公告)号:US06344348B1

    公开(公告)日:2002-02-05

    申请号:US09284234

    申请日:1999-11-22

    IPC分类号: C12P1320

    CPC分类号: C12P13/20 C08G73/1092

    摘要: The invention provides a process for the production of aspartic acid poly-condensate from a carbohydrate comprising the steps of: fermenting a carbohydrate-containing medium by means of a fumaric acid-producing microorganism, whereby a fumarate-containing fermentation liquor is formed; forming a purified ammonium fumarate solution from the fumarate-containing fermentation liquor; enzymatically converting the purified ammonium fumarate into purified ammonium aspartate; heating an aqueous solution of an aspartate salt derived from the purified ammonium aspartate whereby water is removed, an aspartic acid condensate is formed and a second product is formed, which second product is basic and contains the cation of the aspartate salt; and removing and using the basic second product as a reagent in another step of the process.

    摘要翻译: 本发明提供了一种从碳水化合物制备天冬氨酸聚缩合物的方法,包括以下步骤:通过产生富马酸的微生物发酵含碳水化合物的培养基,从而形成含富马酸的发酵液; 从含富马酸的发酵液中形成纯化的富马酸铵溶液; 将纯化的富马酸铵酶促转化成纯天然天冬氨酸铵; 加热源自纯化天冬氨酸铵的天冬氨酸盐的水溶液,由此除去水,形成天冬氨酸缩合物并形成第二产物,该第二产物是碱性的,并含有天冬氨酸盐的阳离子; 以及在该方法的另一步骤中除去和使用碱性第二产物作为试剂。