公开(公告)号：US10308738B2

公开(公告)日：2019-06-04

申请号：US15579882

申请日：2016-06-14

Applicant: Basell Polyolefine GmbH

Inventor： Christoph Wolf ,  Andre-Armand Finette ,  Andrei Gonioukh ,  Dieter Littmann ,  Thomas Herrmann ,  Georg Groos

IPC: C08F110/02 ,  C08F2/04 ,  B01J19/24

Abstract: The present disclosure relates to a plant for performing polymerization, such as the polymerization of ethylene, having a recycle connection with two or more cooling channels arranged in parallel, a process for polymerization and downstream processes, and a plant for polymerization, comprising the following plant components in fluid communication: a) A reactor with an inlet side and an outlet side; b) A recycle connection positioned in fluid communication between the outlet side of the reactor and the inlet side of the reactor; wherein the recycle connection comprises two or more cooling channels arranged in parallel.

公开(公告)号：US20170183429A1

公开(公告)日：2017-06-29

申请号：US15461064

申请日：2017-03-16

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jürgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  B01J19/24 ,  C08J5/18

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

公开(公告)号：US20170335028A1

公开(公告)日：2017-11-23

申请号：US15674176

申请日：2017-08-10

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jürgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  B01J19/24 ,  C08J5/18

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

公开(公告)号：US09758603B2

公开(公告)日：2017-09-12

申请号：US15461064

申请日：2017-03-16

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jürgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  C08F2/01 ,  C08J5/18 ,  B01J19/24 ,  C08F2/34 ,  C08F2/38

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

公开(公告)号：US20170022303A1

公开(公告)日：2017-01-26

申请号：US15240084

申请日：2016-08-18

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jurgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  B01J19/24

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

Abstract translation: 本技术涉及在自由基聚合引发剂存在下聚合或共聚烯键式不饱和单体的方法，其中聚合在连续操作的管式反应器中在100℃至350℃的温度下进行，压力 从180MPa到340MPa，比表面积Asp为2m 2 /（t / h）至5.5m 2 /（t / h），并且管式反应器的比值RDsp为0.0050MPa-1至0.0069MPa -1，表面粗糙度Ra为2μm以下的内表面。

公开(公告)号：US20170348658A1

公开(公告)日：2017-12-07

申请号：US15523909

申请日：2015-11-12

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Georg Groos ,  Andre-Armand Finette ,  Michael Deuerling ,  Sven Wolfram ,  Juergen Mohrbutter ,  Danir Khayrullin ,  Claudio Fibla ,  Christoph Wolf

IPC: B01J4/00 ,  C08F2/00 ,  C08F2/01

CPC classification number: B01J4/002 ,  B01J2219/185 ,  B01J2219/1943 ,  B01J2219/1946 ,  C08F2/004 ,  C08F2/01 ,  C08F6/001 ,  C08J11/02 ,  Y02P20/582

Abstract: A process for separating polymeric and gaseous components of a polymer-monomer mixture at a pressure of from 0.12 MPa to 0.6 MPa and a temperature of from 120° C. to 300° C. in a separation vessel is provided. The separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 0.6 to 10 and an inlet pipe capable of introducing the polymer-monomer mixture into the separation vessel which the inlet pipe extends vertically from the top of the separation vessel into the separation vessel. Further a process for preparing ethylene homopolymers or copolymers from ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa comprising such a process for separating a polymer-monomer mixture is provided.

公开(公告)号：US09631035B2

公开(公告)日：2017-04-25

申请号：US15101351

申请日：2014-12-03

Applicant: Basell Polyolefine GmbH

Inventor： Georg Groos ,  Erich Neumann ,  Michael Deuerling ,  Dieter Littmann

IPC: C08F2/00 ,  C08F4/00 ,  C08F210/00 ,  B01J10/00 ,  B01J19/18 ,  C08F6/12 ,  C08F6/00 ,  C08F6/10 ,  C08J11/02 ,  C08F2/01 ,  C08F2/02 ,  C08F2/34

CPC classification number: C08F6/12 ,  C08F2/01 ,  C08F2/02 ,  C08F2/34 ,  C08F6/001 ,  C08F6/10 ,  C08J11/02 ,  Y02P20/582 ,  C08L23/04 ,  C08F10/02 ,  C08F2/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/08

Abstract: The present disclosure relates to a process for separating polymeric and gaseous components of a reaction mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers in the presence of free-radical polymerization initiators into in a gaseous fraction and a liquid fraction, wherein the separation is carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120° C. to 300° C. in a separation vessel which has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 4 to 10 and which is equipped with an inlet pipe which extends vertically from the top into the separation vessel; and the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.2 to 0.4.

公开(公告)号：US20180171044A1

公开(公告)日：2018-06-21

申请号：US15579882

申请日：2016-06-14

Applicant: Basell Polyolefine GmbH

Inventor： Christoph Wolf ,  Andre-Armand Finette ,  Andrei Gonioukh ,  Dieter Littmann ,  Thomas Herrmann ,  Georg Groos

IPC: C08F110/02 ,  B01J19/24

CPC classification number: C08F110/02 ,  B01J19/2415 ,  B01J19/2465 ,  B01J2219/00081 ,  B01J2219/00092 ,  B01J2219/24 ,  C08F2/04 ,  Y02P20/582

Abstract: The present disclosure relates to a plant for performing polymerization, such as the polymerization of ethylene, having a recycle connection with two or more cooling channels arranged in parallel, a process for polymerization and downstream processes, and a plant for polymerization, comprising the following plant components in fluid communication: a) A reactor with an inlet side and an outlet side; b) A recycle connection positioned in fluid communication between the outlet side of the reactor and the inlet side of the reactor; wherein the recycle connection comprises two or more cooling channels arranged in parallel.

公开(公告)号：US09631037B2

公开(公告)日：2017-04-25

申请号：US15240084

申请日：2016-08-18

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jurgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  B01J19/24 ,  C08F2/38

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

公开(公告)号：US09441057B1

公开(公告)日：2016-09-13

申请号：US15044855

申请日：2016-02-16

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jurgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F2/01 ,  C08F2/34 ,  C08F2/38 ,  C08F110/02 ,  C08J5/18

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

Abstract translation: 本技术涉及在自由基聚合引发剂存在下聚合或共聚烯属不饱和单体的方法，其中聚合在连续操作的管式反应器中在100℃至350℃的温度下进行，压力 从180MPa到340MPa，比表面积Asp为2m 2 /（t / h）至5.5m 2 /（t / h），并且管式反应器的比值RDsp为0.0050MPa-1至0.0069MPa -1，表面粗糙度Ra为2μm以下的内表面。