公开(公告)号：US3871970A

公开(公告)日：1975-03-18

申请号：US28475972

申请日：1972-08-30

Applicant: BASF AG

Inventor： NIENBURG HANS JUERGEN ,  KUMMER RUDOLF

IPC: C07C45/82 ,  B01J31/22 ,  B01J31/24 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00 ,  B01D3/34

CPC classification number: B01J31/04 ,  B01J31/20 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/403 ,  B01J31/4038 ,  B01J31/4046 ,  B01J2231/321 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: A process for working up by distillation hydroformylation reaction mixtures which have been obtained by the reaction of olefins with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a carbonyl complex of a metal of Group VIII of the Periodic Table which has been modified with an organic phosphine, wherein said mixture is distilled in the presence of a carboxylic acid.

Abstract translation: 一种通过蒸馏加氢甲酰基化反应混合物处理的方法，其通过烯烃与一氧化碳和氢气在升高的温度和超大气压下在周期表第VIII族金属的羰基络合物的存在下反应获得 用有机膦改性，其中所述混合物在羧酸存在下蒸馏。

公开(公告)号：US3929898A

公开(公告)日：1975-12-30

申请号：US27693672

申请日：1972-08-01

Applicant: BASF AG

Inventor： NIENBURG HANS-JUERGEN ,  KUMMER RUDOLF ,  HOHENSCHUTZ HEINZ ,  STROHMEYER MAX ,  TAVS PETER

IPC: C07C67/333 ,  B01J23/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00 ,  C07C45/08

CPC classification number: C07C45/50 ,  C07C47/02

Abstract: A process for the production of mainly linear aldehydes by hydroformylation of an olefinically unsaturated compound of from two to twenty carbon atoms with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a cobalt carbonyl complex prepared prior to the hydroformylation from an aqueous solution of a cobalt salt, wherein in a first stage an aqueous solution of a cobalt salt is treated with carbon monoxide and hydrogen at a temperature of from 50* to 200*C and at a pressure of from 100 to 400 atmospheres in the presence of activated carbon, a zeolite or a basic ion exchanger which has been loaded with cobalt carbonyl, the aqueous solution containing cobalt salt and cobalt carbonyl hydride thus obtained and the mixture of carbon monoxide and hydrogen, without releasing the pressure, are extracted at a temperature of 20* to 100*C and at a pressure of 100 to 400 atmospheres in a second stage with a saturated hydrocarbon or the olefinically unsaturated compound used for the hydroformylation (provided they are insoluble in water and liquid under the conditions used), water-insoluble oxo reaction product or hydrogenated oxo reaction product, the aqueous phase is separated and the organic phase containing the carbonyl complex thus obtained and the mixture of carbon monoxide and hydrogen are transferred to a third stage and, after supplying olefinically unsaturated compound (if this has not been used or has only partly been used for extraction in the abovementioned stage) hydroformylation is carried out at a temperature of from 70* to 170*C and a pressure of from 100 to 400 atmospheres. The products of the process are suitable for the production of detergent alcohols and plasticizers and for the production of carboxylic acids and amines.

Abstract translation: 通过在二氧化碳和氢气的烯属不饱和化合物与一氧化碳和氢气在升高的温度和超大气压下，在羰基化羰基络合物存在下，在氢化甲酰化之前，从水溶液中加氢甲酰化制备主要线性醛的方法 钴盐溶液，其中在第一阶段中钴盐的水溶液用一氧化碳和氢气在50至200℃的温度和100至400大气压的压力下在有 活性炭，已经负载有羰基钴的沸石或碱性离子交换剂，由此获得的含有钴盐和羰基氢化钴的水溶液和一氧化碳和氢气的混合物而不释放压力，在 20〜100℃，在100〜400个大气压的压力下，在第二阶段用饱和烃或硫酸 用于加氢甲酰化的烯属不饱和化合物（只要它们在所用条件下不溶于水和液体），水不溶性氧代反应产物或氢化羰基反应产物，分离水相，并将含有羰基络合物的有机相如此得到 将一氧化碳和氢气的混合物转移到第三阶段，在提供烯属不饱和化合物（如果没有使用或仅在上述阶段中仅部分用于萃取）之后，加氢甲酰化在 70〜170℃，压力为100〜400个大气压。