公开(公告)号：US09328247B2

公开(公告)日：2016-05-03

申请号：US14356530

申请日：2012-11-07

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Anja Song ,  Thomas Steinmacher ,  Joerg Claussen ,  Philipp Zacharias ,  Vijay Immanuel Raman ,  Petra Schoecker

IPC: C09D7/12 ,  C09D4/06 ,  C08F20/28

CPC classification number: C09D7/1216 ,  C08F20/28 ,  C09D4/06 ,  C09D7/61 ,  Y10T428/31906

Abstract: A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.

Abstract translation: 描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。 添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢 或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c） 除a）和b）以外的非离子共聚单体，其中所述添加剂的重均分子量低于200000，其中叔十二烷基硫醇用作链转移剂。

公开(公告)号：US09334398B2

公开(公告)日：2016-05-10

申请号：US14375937

申请日：2013-02-11

Applicant: BASF SE

Inventor： Rabie Al-Hellani ,  Carmen-Elena Cimpeanu ,  Juergen Schmidt-Thuemmes ,  Dirk Lawrenz ,  Kristina Georgieva ,  Anja Song

IPC: C08L25/14 ,  C08F2/22 ,  C08F2/44 ,  C08L33/08 ,  C09D4/06 ,  C09D7/12 ,  D21H19/56

CPC classification number: C08L25/14 ,  C08F2/22 ,  C08F2/44 ,  C08L33/08 ,  C09D4/06 ,  C09D7/65 ,  D21H19/56 ,  Y10T428/31906

Abstract: Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable via free-radically initiated emulsion polymerization from ethylenically unsaturated, free-radically polymerizable monomers, wherein the chain growth addition polymer is formed to an extent of not less than 60 wt % from primary monomers selected from vinylaromatic compounds, conjugated aliphatic dienes, vinyl esters of saturated C1- to C20-carboxylic acids, esters of acrylic acid or of methacrylic acid with monohydric C1- to C20-alcohols, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, or mixtures thereof, wherein the monomers are polymerized in the presence of lignosulfonate and wherein the chain growth addition polymer is branched or crosslinked. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful for preparing paper coating compositions.

Abstract translation: 描述了一种含水聚合物分散体，其包含通过烯键式不饱和的可自由基聚合的单体经由自由基引发的乳液聚合而获得的链增长加成聚合物，其中链生长加成聚合物形成至少不少于60重量％ 选自乙烯基芳族化合物，共轭脂族二烯，饱和C 1〜C 20羧酸的乙烯基酯，丙烯酸或甲基丙烯酸与一元C 1〜C 20醇的酯，碳原子数2〜8的脂肪族烃和1〜 两个双键或其混合物，其中所述单体在木素磺酸盐存在下聚合，并且其中链生长加成聚合物是支链或交联的。 还描述了制备聚合物水分散体的方法。 聚合物分散体可用于制备纸涂料组合物。

公开(公告)号：US20140342171A1

公开(公告)日：2014-11-20

申请号：US14375937

申请日：2013-02-11

Applicant: BASF SE

Inventor： Rabie Al-Hellani ,  Carmen-Elena Cimpeanu ,  Juergen Schmidt-Thuemmes ,  Dirk Lawrenz ,  Kristina Georgieva ,  Anja Song

IPC: C08L25/14 ,  D21H19/56 ,  C09D7/12 ,  C08L33/08 ,  C09D4/06

CPC classification number: C08L25/14 ,  C08F2/22 ,  C08F2/44 ,  C08L33/08 ,  C09D4/06 ,  C09D7/65 ,  D21H19/56 ,  Y10T428/31906

Abstract: Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable via free-radically initiated emulsion polymerization from ethylenically unsaturated, free-radically polymerizable monomers, wherein the chain growth addition polymer is formed to an extent of not less than 60 wt % from primary monomers selected from vinylaromatic compounds, conjugated aliphatic dienes, vinyl esters of saturated C1- to C20-carboxylic acids, esters of acrylic acid or of methacrylic acid with monohydric C1- to C20-alcohols, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, or mixtures thereof, wherein the monomers are polymerized in the presence of lignosulfonate and wherein the chain growth addition polymer is branched or crosslinked. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful for preparing paper coating compositions.

Abstract translation: 描述了一种含水聚合物分散体，其包含通过烯键式不饱和的可自由基聚合的单体经由自由基引发的乳液聚合而获得的链增长加成聚合物，其中链生长加成聚合物形成至少不少于60重量％ 选自乙烯基芳族化合物，共轭脂族二烯，饱和C 1〜C 20羧酸的乙烯基酯，丙烯酸或甲基丙烯酸与一元C 1〜C 20醇的酯，碳原子数2〜8的脂肪族烃和1〜 两个双键或其混合物，其中所述单体在木素磺酸盐存在下聚合，并且其中链生长加成聚合物是支链或交联的。 还描述了制备聚合物水分散体的方法。 聚合物分散体可用于制备纸涂料组合物。

公开(公告)号：US20140302335A1

公开(公告)日：2014-10-09

申请号：US14356530

申请日：2012-11-07

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Anja Song ,  Thomas Steinmacher ,  Joerg Claussen ,  Philipp Zacharias ,  Vijay Raman ,  Petra Schoecker

IPC: C09D7/12 ,  C08F20/28

CPC classification number: C09D7/1216 ,  C08F20/28 ,  C09D4/06 ,  C09D7/61 ,  Y10T428/31906

Abstract: A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R 2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.

Abstract translation: 描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。 添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢 或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c ）除a）和b）以外的非离子可共聚单体，其中所述添加剂的重均分子量低于200000，并且其中使用叔十二烷基硫醇作为链转移剂。