公开(公告)号：US09328247B2

公开(公告)日：2016-05-03

申请号：US14356530

申请日：2012-11-07

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Anja Song ,  Thomas Steinmacher ,  Joerg Claussen ,  Philipp Zacharias ,  Vijay Immanuel Raman ,  Petra Schoecker

IPC: C09D7/12 ,  C09D4/06 ,  C08F20/28

CPC classification number: C09D7/1216 ,  C08F20/28 ,  C09D4/06 ,  C09D7/61 ,  Y10T428/31906

Abstract: A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.

Abstract translation: 描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。 添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢 或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c） 除a）和b）以外的非离子共聚单体，其中所述添加剂的重均分子量低于200000，其中叔十二烷基硫醇用作链转移剂。

公开(公告)号：US09950502B2

公开(公告)日：2018-04-24

申请号：US14360803

申请日：2012-12-03

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Heiko Diehl ,  Darijo Mijolovic ,  Andre Van Meer ,  Jan Van Delft ,  Christof Van Sluijs

IPC: B32B27/10 ,  D21H19/12 ,  B65D5/18 ,  B65D5/36 ,  B65D5/20 ,  B65D5/02 ,  B65D5/00 ,  B65D5/40 ,  B65D5/42 ,  B32B27/30 ,  B65D5/56 ,  B32B29/00 ,  B32B1/02 ,  C08F2/22 ,  D21H19/16 ,  D21H19/20 ,  D21H19/52 ,  D21H19/54 ,  D21H27/10 ,  D21H11/14 ,  D21H19/34 ,  D21H19/58 ,  B65D30/00 ,  B65D65/42 ,  B65D85/00

CPC classification number: B32B27/10 ,  B32B1/02 ,  B32B27/30 ,  B32B27/308 ,  B32B29/00 ,  B32B29/002 ,  B65D5/00 ,  B65D5/02 ,  B65D5/18 ,  B65D5/20 ,  B65D5/36 ,  B65D5/40 ,  B65D5/42 ,  B65D5/56 ,  B65D5/563 ,  B65D31/00 ,  B65D65/42 ,  B65D85/70 ,  B65D2565/383 ,  B65D2577/04 ,  C08F2/22 ,  D21H11/14 ,  D21H19/12 ,  D21H19/16 ,  D21H19/20 ,  D21H19/34 ,  D21H19/52 ,  D21H19/54 ,  D21H19/58 ,  D21H27/10 ,  Y10T428/1303 ,  Y10T428/1307 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/264 ,  Y10T428/31906

Abstract: Described is paper or cardboard packaging produced from mineral oil contaminated, (e.g., recycled) paper, wherein the packaging includes a barrier layer obtainable by applying an aqueous polymer dispersion comprising a copolymer obtainable by emulsion polymerization of C1-C4 alkyl (meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0 to 10 wt % of further monomers in an aqueous medium in the presence of a carbohydrate compound, preferably in the form of a degraded starch, wherein the glass transition temperature of the copolymer is in the range from +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.

公开(公告)号：US20140302335A1

公开(公告)日：2014-10-09

申请号：US14356530

申请日：2012-11-07

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Anja Song ,  Thomas Steinmacher ,  Joerg Claussen ,  Philipp Zacharias ,  Vijay Raman ,  Petra Schoecker

IPC: C09D7/12 ,  C08F20/28

CPC classification number: C09D7/1216 ,  C08F20/28 ,  C09D4/06 ,  C09D7/61 ,  Y10T428/31906

Abstract: A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R 2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.

Abstract translation: 描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。 添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢 或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c ）除a）和b）以外的非离子可共聚单体，其中所述添加剂的重均分子量低于200000，并且其中使用叔十二烷基硫醇作为链转移剂。

公开(公告)号：US20150274350A1

公开(公告)日：2015-10-01

申请号：US14360803

申请日：2012-12-03

Applicant: BASF SE

Inventor： Hermann Seyffer ,  Carmen Elena Cimpeanu ,  Heiko Diehl ,  Darijo Mijolovic ,  Andre Van Meer ,  Jan Van Delft ,  Christof Van Sluijs

IPC: B65D5/56 ,  B65D85/00 ,  B65D30/00 ,  B65D65/42

CPC classification number: B32B27/10 ,  B32B1/02 ,  B32B27/30 ,  B32B27/308 ,  B32B29/00 ,  B32B29/002 ,  B65D5/00 ,  B65D5/02 ,  B65D5/18 ,  B65D5/20 ,  B65D5/36 ,  B65D5/40 ,  B65D5/42 ,  B65D5/56 ,  B65D5/563 ,  B65D31/00 ,  B65D65/42 ,  B65D85/70 ,  B65D2565/383 ,  B65D2577/04 ,  C08F2/22 ,  D21H11/14 ,  D21H19/12 ,  D21H19/16 ,  D21H19/20 ,  D21H19/34 ,  D21H19/52 ,  D21H19/54 ,  D21H19/58 ,  D21H27/10 ,  Y10T428/1303 ,  Y10T428/1307 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/264 ,  Y10T428/31906

Abstract: Described is paper or cardboard packaging produced from mineral oil contaminated, (e.g., recycled) paper, wherein the packaging includes a barrier layer obtainable by applying an aqueous polymer dispersion comprising a copolymer obtainable by emulsion polymerization of C1-C4 alkyl (meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0 to 10 wt % of further monomers in an aqueous medium in the presence of a carbohydrate compound, preferably in the form of a degraded starch, wherein the glass transition temperature of the copolymer is in the range from +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.

Abstract translation: 描述的是由矿物油污染的（例如，再循环的）纸产生的纸或纸板包装，其中包装包括通过施加含水聚合物分散体获得的阻隔层，所述聚合物分散体包含可通过乳液聚合的（甲基）丙烯酸C1-C4烷基酯， 酸性单体，例如丙烯酸或甲基丙烯酸，0-20重量％的丙烯腈和0-10重量％的其它单体，在水性介质中，在碳水化合物化合物的存在下，优选为降解淀粉的形式，其中 共聚物的玻璃化转变温度在+ 10℃至+ 45℃的范围内。阻挡层可以位于包装的一个表面上或形成多层包装涂层的多层之一或者作为涂层 位于包装内的内袋的一侧。