公开(公告)号：US11459281B2

公开(公告)日：2022-10-04

申请号：US17048342

申请日：2019-04-08

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Christian Weichert ,  Christopher Alec Anderlohr ,  Wolfgang Reif

IPC: C07C2/78 ,  C01B3/36 ,  C07C11/24

Abstract: A process for producing acetylene and syngas by partial oxidation of hydrocarbons with oxygen, involving: separately preheating a hydrocarbon and a oxygen-comprising input stream; mixing in a mass flow ratio of the oxygen-comprising to hydrocarbon stream at an oxygen number no more than 0.31; feeding the streams via a burner block to a combustion chamber and therein partially oxidizing the hydrocarbon(s) to a cracking gas; quenching the cracking gas to 80 to 90° C. downstream by injecting an aqueous quench medium to obtain a process water stream-1 and a product gas stream-2; cooling the product gas stream-2 in a cooling column by direct heat exchange with cooling water to obtain a process water stream-2 as bottoms, a product gas stream-2 as uppers, and a sidestream; and depleting the sidestream of soot in an electrofilter to generate therein a process water stream-3 combined with water streams-1/2 to afford the process water stream-4.

公开(公告)号：US10059640B2

公开(公告)日：2018-08-28

申请号：US15129094

申请日：2015-03-25

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Susanne Britzius ,  Lilian Kara-Hippen ,  Michael Russ ,  Matthias Kern ,  Christian Weichert

IPC: C07C11/24 ,  C07C2/78 ,  B01D3/14 ,  C01B3/36 ,  C07D207/267 ,  C07C15/073 ,  C07C15/06 ,  C07C9/04 ,  C07C9/06 ,  C07C11/04 ,  C07C9/14 ,  C07C15/58 ,  C07C15/04 ,  C07C15/08

CPC classification number: C07C2/78 ,  B01D3/14 ,  B01J2219/00006 ,  C01B3/36 ,  C07C9/04 ,  C07C9/06 ,  C07C9/14 ,  C07C11/04 ,  C07C11/24 ,  C07C15/04 ,  C07C15/06 ,  C07C15/073 ,  C07C15/08 ,  C07C15/58 ,  C07D207/267

Abstract: An apparatus (10) for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed. The apparatus (10) comprises a reactor (12), wherein the reactor (12) comprises a burner block (14) with a furnace chamber for the preparation of a composition C1 comprising at least acetylene and substituted acetylene, a first scrubber (22) which is constructed for adding a solvent to the composition C1 to obtain a composition C2, a second scrubber (26) which is constructed for adding the solvent to the composition C2 to obtain a composition C3, a first stripper (36) which is constructed for stripping the composition C3 to obtain a composition C4 comprising the substituted acetylene, acetylene and the solvent and for separating off the acetylene, a first column (46) which is constructed for partial degassing of the composition C4 under a pressure of from 1.0 bar to 1.5 bar to obtain a composition C5 and a first amount A1 of the solvent, a second stripper (56) to which the composition C5 can be fed for stripping a composition C9 to obtain a second amount A2 of the solvent and a composition C6, a third stripper (68) which is constructed for stripping the solvent from the first scrubber (22) to obtain a composition C9, wherein the third striper (68) is connected to the second stripper (56) for feeding the composition C9 to the second stripper (56), an apparatus (72) for adding a diluting gas to the composition C5, which is arranged between the first column (46) and the second stripper (56), a second column (76) which is constructed for adding water to the composition C6 to obtain a composition C7 comprising a third amount A3 of the solvent and water and to obtain a composition C8 comprising the substituted acetylene, and a mixing condenser (82) which is constructed for adding water to the composition C8 to obtain a composition C11 comprising the substituted acetylene.A process for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is further proposed.

公开(公告)号：US09290384B2

公开(公告)日：2016-03-22

申请号：US13902175

申请日：2013-05-24

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Christian Weichert ,  Dirk Grossschmidt ,  Michael Russ ,  Mirko Haider ,  Horst Neuhauser ,  Michael L. Hayes

IPC: C01B3/38 ,  C01B3/24 ,  C01B3/36

CPC classification number: C01B3/36 ,  C01B2203/0255 ,  C07C2/78 ,  C07C4/025 ,  C07C11/24

Abstract: A process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, is disclosed. The process consists of separately preheating and then mixing a first input stream containing a hydrocarbon and a second input stream containing oxygen, supplying the first input stream and the second input stream via a burner block to a firing space, quenching a cracking gas obtained to produce a process water stream and a product gas stream, cooling the product gas stream in a cooling column by direct heat exchange with cooling water, depleting soot in an electrostatic filter, combining all process water streams and passing through soot channels, subjecting the combined process water stream to a cleaning operation by partial vaporization in a one-stage flash vessel to obtain a cleaned process water stream, and recycling the cleaned process water stream into the process.

Abstract translation: 公开了通过用氧气分解氧化烃来制备乙炔和合成气的方法。 该方法包括单独地预热，然后混合含有烃的第一输入流和含有氧的第二输入流，经由燃烧器块将第一输入流和第二输入流提供到燃烧空间，淬火产生的裂解气 工艺水流和产物气流，通过与冷却水直接热交换在冷却塔中冷却产物气流，在静电过滤器中消除烟灰，将所有工艺水流合并通过烟灰通道，对组合的工艺水 通过在一级闪蒸容器中部分蒸发而进行清洁操作以获得清洁的工艺水流，并将清洁的工艺水流循环到该过程中。

公开(公告)号：US09580312B2

公开(公告)日：2017-02-28

申请号：US14758649

申请日：2014-01-15

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Christian Weichert ,  Dirk Grossschmidt ,  Michael Russ ,  Kai Rainer Ehrhardt ,  Horst Neuhauser ,  Michael L. Hayes

IPC: C01B3/38 ,  C01B3/36 ,  C07C2/78

CPC classification number: C01B3/36 ,  C01B2203/025 ,  C01B2203/0255 ,  C01B2203/062 ,  C01B2203/0877 ,  C01B2203/0894 ,  C01B2203/1235 ,  C01B2203/148 ,  C07C2/78 ,  C07C11/24

Abstract: The invention relates to a continuous method for producing acetylenes and syngas by partially oxidizing hydrocarbons with oxygen. A first feed stream (1) containing one or more hydrocarbons and a second feed stream (2) containing oxygen are —mixed in a ratio of the mass flows of the second feed stream (2) to the first feed stream (1) corresponding to an oxygen number of less than or equal to 0.31, said streams being heated separately from each other, —and fed to a combustion chamber (FR) via a burner block (BR), the partial oxidation of the hydrocarbons being carried out in said combustion chamber, —thereby obtaining a first cracked gas stream Ig. The invention is characterized in that —the first cracked gas stream Ig is precooled to a temperature ranging from 100 to 1000° C. in a prequench region (H), thereby obtaining a second cracked gas stream IIg, —50 to 90% of the solids contained in the second cracked gas stream IIg are separated therefrom in a solid-gas separating device (A), thereby obtaining a solid stream If and a third cracked gas stream IIIg, —the third cracked gas stream IIIg is cooled to 80 to 90° C. by injecting water in a total quench region (B), thereby obtaining a fourth cracked gas stream IVg and a first process water stream Iliq, —the fourth cracked gas stream IVg undergoes a fine separation of solids in one or more scrubbing devices (C, D), thereby obtaining one or more process water streams IIliq, IIIliq and a product gas stream VIg, —the process water streams Iliq, IIliq, IIIliq are merged into a combined process water stream IVliq, —the combined process water stream IVliq is partly recirculated, as stream Vliq, into the total quench region (B) and otherwise undergoes a cleaning process, as stream VIliq, by means of a partial evaporation process, thereby obtaining a cleaned process water stream VIIliq, —which is cooled by a recooling device (F), partially recycled, as stream VIIIliq, into the method, and otherwise discharged, as stream IXliq.

公开(公告)号：US09145297B2

公开(公告)日：2015-09-29

申请号：US14422978

申请日：2013-09-02

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Christian Weichert ,  Dirk Grossschmidt ,  Michael Russ ,  Mirko Haider ,  Horst Neuhauser

IPC: C01B3/38 ,  C01B3/36

CPC classification number: C01B3/363 ,  C01B3/36 ,  C01B2203/0255 ,  C01B2203/04 ,  C01B2203/0465 ,  C01B2203/062 ,  C01B2203/0805 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/1235 ,  C07C2/78 ,  C07C11/24

Abstract: The invention proposes a method for producing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, wherein a first feedstock (1), containing one or more hydrocarbons, and a second feedstock (2), containing oxygen, —are preheated separately from one another, —are fed via a burner block (B) to a combustion chamber (F), in which the partial oxidation of the hydrocarbons takes place, —obtaining a cracked gas, which is quenched by injecting a quench oil downstream of the furnace body at 200° C. to 250° C., wherein —a flow of product gas Ig is obtained, which —is cooled in a burner column (BK) with further quench oil, obtaining —a flow of product gas IIg cooled to 60° C. to 90° C., which —is guided into a final cooler (SK), in which a flow of product gas IIIg, cooled to 20° C. to 50° C., is obtained by direct thermal exchange with water, as well as a flow of process water I liq —which is characterized in that the flow of process water I liq is subjected to purification by partial evaporation in a single-stage expansion chamber, wherein the flow of process water I liq is vaporized to a proportion of 0.01 percent by weight to 10 percent by weight, relative to the total weight of same, obtaining a purified flow of process water II liq which is removed in the waste water.

Abstract translation: 本发明提出了一种通过用氧气对烃进行部分氧化生产乙炔和合成气的方法，其中含有一种或多种烃的第一原料（1）和含有氧的第二原料（2） - 与一种 另一个 - 通过燃烧器块（B）被供给到燃烧室（F），其中发生烃的部分氧化， - 产生裂化气体，其通过在炉体下游注入骤冷油来淬火 在200℃至250℃下，其中 - 获得产物气体Ig的流量，该流量在具有另外的骤冷油的燃烧器塔（BK）中冷却，获得将产物气体IIg流冷却至60℃ 将其导入到通过与水直接热交换而获得的冷却至20℃至50℃的产物气体IIIg流的最终冷却器（SK）中， 以及工艺水I liq的流程，其特征在于工艺水I liq的流量为s 通过部分蒸发在单级膨胀室中纯化，其中工艺水I liq的流动相对于其总重量蒸发为0.01重量％至10重量％的比例，获得纯化流 的废水中除去的过程水II liq。

公开(公告)号：US20150217999A1

公开(公告)日：2015-08-06

申请号：US14422978

申请日：2013-09-02

Applicant: BASF SE

Inventor： Maximilian Vicari ,  Christian Weichert ,  Dirk Grossschmidt ,  Michael Russ ,  Mirko Haider ,  Horst Neuhauser

IPC: C01B3/36

CPC classification number: C01B3/363 ,  C01B3/36 ,  C01B2203/0255 ,  C01B2203/04 ,  C01B2203/0465 ,  C01B2203/062 ,  C01B2203/0805 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/1235 ,  C07C2/78 ,  C07C11/24

Abstract: The invention proposes a method for producing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, wherein a first feedstock (1), containing one or more hydrocarbons, and a second feedstock (2), containing oxygen, are preheated separately from one another, are fed via a burner block (B) to a combustion chamber (F), in which the partial oxidation of the hydrocarbons takes place, obtaining a cracked gas, which is quenched by injecting a quench oil downstream of the furnace body at 200° C. to 250° C., wherein a flow of product gas Ig is obtained, which is cooled in a burner column (BK) with further quench oil, obtaining a flow of product gas IIg cooled to 60° C. to 90° C., which is guided into a final cooler (SK), in which a flow of product gas IIIg, cooled to 20° C. to 50° C., is obtained by direct thermal exchange with water, as well as a flow of process water I liq which is characterised in that the flow of process water I liq is subjected to purification by partial evaporation in a single-stage expansion chamber, wherein the flow of process water I liq is vaporised to a proportion of 0.01 percent by weight to 10 percent by weight, relative to the total weight of same, obtaining a purified flow of process water II liq which is removed in the waste water.

Abstract translation: 本发明提出了一种用氧气对烃进行部分氧化生产乙炔和合成气的方法，其中含有一种或多种烃的第一原料（1）和含有氧的第二原料（2）彼此分开预热 通过燃烧器块（B）被供给到燃烧室（F），其中发生烃的部分氧化，获得破裂气体，其通过在炉体的下游将注入的淬火油在200℃淬火 C至250℃，其中获得产物气体Ig的流动，其在具有另外的骤冷油的燃烧器塔（BK）中冷却，获得冷却至60℃至90℃的产物气体IIg流 ，其被引导到最终冷却器（SK）中，其中通过与水直接热交换获得冷却至20℃至50℃的产物气体IIIg流，以及流程 水I liq，其特征在于对工艺水I liq的流动进行纯化 通过在单级膨胀室中部分蒸发，其中工艺水I liq的流动相对于其总重量蒸发为0.01重量％至10重量％的比例，获得净化的工艺水流 II liq在废水中被清除。