公开(公告)号：US20150218393A1

公开(公告)日：2015-08-06

申请号：US14421492

申请日：2013-08-09

Applicant: BASF SE

Inventor： Daniel Rogez ,  Silke Fischer ,  Axel Becker ,  Delphine Kimpel

IPC: C09D5/32 ,  B05D3/06

CPC classification number: C09D5/32 ,  B05D3/067 ,  C08F2220/286 ,  C08F2222/1086 ,  C08K5/005 ,  C09D4/00 ,  C08L33/06

Abstract: The invention relates to a novel stabilizer mixture comprising certain UV absorbers and specific (meth)acrylates, which are stable during storage and which are easily miscible with radiation curable coatings.

Abstract translation: 本发明涉及包含某些UV吸收剂和特定（甲基）丙烯酸酯的新型稳定剂混合物，其在储存期间是稳定的并且易于与可辐射固化涂层混溶。

公开(公告)号：US20190233655A1

公开(公告)日：2019-08-01

申请号：US16341196

申请日：2017-10-02

Applicant: BASF SE

Inventor： Delphine Kimpel ,  Kenneth Shaun Tranter ,  Daniel Kunz ,  Kathrin Cohen ,  Peter Thuery ,  Christine Roesch ,  Stefan Wahl

IPC: C09D4/06 ,  C09D167/06 ,  C08J7/04

CPC classification number: C09D4/06 ,  C08F290/061 ,  C08G63/47 ,  C08G63/914 ,  C08J7/047 ,  C08J2327/06 ,  C08J2397/00 ,  C08J2467/06 ,  C09D151/08 ,  C09D167/06 ,  C08F2222/1013 ,  C08F222/1006

Abstract: Radiation-curable, polyester acrylate-containing compositions (I) obtainable by reacting 0.5 to 20 mol % of a polyester polyol (A) and 0.5 to 30 mol % of a polyester diol (B) with 1 to 10 mol % of phthalic anhydride (C) and 65 to 75 mol % of (meth)acrylic acid (D) in the presence of an acidic esterification catalyst, a hydrocarbon (L), and a polymerization inhibitor. Reaction temperatures range from 60 to 140° C. The hydrocarbon (L) functions as solvent, forms an azeotropic mixture with water, and is removed distillatively after esterification. Water formed in the reaction is removed azeotropically. After neutralization of the esterification catalyst, free (meth)acrylic acid is reacted with an epoxide compound (E) in an amount equivalent to the acid number of the reaction mixture. The compound (E) has at least two epoxide groups per molecule. The compositions are suitable for coating the surfaces of solid substrates.

公开(公告)号：US09738597B2

公开(公告)日：2017-08-22

申请号：US14892027

申请日：2014-05-16

Applicant: BASF SE

Inventor： Reinhold Schwalm ,  Susanne Neumann ,  Delphine Kimpel

IPC: C07C261/00 ,  C07C269/00 ,  C07C271/00 ,  C07C269/02 ,  C08G18/67 ,  C08G18/68 ,  C08G18/22 ,  C09D175/16 ,  C07C271/12 ,  C09D4/00

CPC classification number: C07C269/02 ,  C07C271/12 ,  C08G18/222 ,  C08G18/227 ,  C08G18/672 ,  C08G18/6725 ,  C08G18/68 ,  C09D4/00 ,  C09D175/16

Abstract: Described herein is a process for preparing urethane (meth)acrylates. In a first step, a hydroxyalkyl (meth)acrylate is reacted with a lactone (B) in the presence of at least one zinc compound and/or bismuth compound (C) to produce a resulting zinc-containing product and/or a bismuth-containing product, and, in a further step, the zinc-containing product and/or the bismuth-containing product is reacted with at least one cycloaliphatic or asymmetric aliphatic diisocyanate (D).

公开(公告)号：US20160107987A1

公开(公告)日：2016-04-21

申请号：US14892027

申请日：2014-05-16

Applicant: BASF SE

Inventor： Reinhold Schwalm ,  Susanne Neumann ,  Delphine Kimpel

IPC: C07C269/02 ,  C09D4/00 ,  C07C271/12

CPC classification number: C07C269/02 ,  C07C271/12 ,  C08G18/222 ,  C08G18/227 ,  C08G18/672 ,  C08G18/6725 ,  C08G18/68 ,  C09D4/00 ,  C09D175/16

Abstract: Described is a process for preparing urethane (meth)acrylates. In a first step, a hydroxyalkyl (meth)acrylate is reacted with a lactone (B) in the presence of at least one zinc compound and/or bismuth compound (C) to produce a bismuth-containing product, and, in a further step, the bismuth-containing product is reacted with at least one cycloaliphatic or asymmetric aliphatic diisocyanate (D).

Abstract translation: 描述了制备聚氨酯（甲基）丙烯酸酯的方法。 在第一步骤中，在至少一种锌化合物和/或铋化合物（C）的存在下，使（甲基）丙烯酸羟烷基酯与内酯（B）反应，以制备含铋的产物，并且在另一步骤 ，含铋产物与至少一种脂环族或不对称脂族二异氰酸酯（D）反应。

公开(公告)号：US20160090485A1

公开(公告)日：2016-03-31

申请号：US14892371

申请日：2014-05-16

Applicant: BASF SE

Inventor： Reinhold Schwalm ,  Susanne Neumann ,  Delphine Kimpel ,  Erich Beck ,  Klaus Menzel

IPC: C09D4/00 ,  C07C269/02 ,  C07C271/20

CPC classification number: C09D4/00 ,  C07C269/02 ,  C07C271/20 ,  C08G18/672 ,  C08G18/6725 ,  C08G18/68 ,  C08G18/7837 ,  C08G18/8175 ,  C09D175/16

Abstract: Described is a process for preparing urethane (meth)acrylates. In a first step, a hydroxyalkyl (meth)acrylate (A) is reacted with a lactone (B) in the presence of at least one catalyst (C), selected from the group consisting of iron compounds, titanium compounds, aluminum compounds, zirconium compounds, manganese compounds, nickel compounds, zinc compounds, cobalt compounds, and bismuth compounds to provide a product; and, in a further step, the product is reacted with a polyisocyanate (D) which comprises at least one hydroxyalkyl (meth)acrylate bonded via an allophanate group.

Abstract translation: 描述了制备聚氨酯（甲基）丙烯酸酯的方法。 在第一步中，在至少一种催化剂（C）的存在下，使（A）羟基烷基酯与内酯（B）反应，所述催化剂（C）选自铁化合物，钛化合物，铝化合物，锆 化合物，锰化合物，镍化合物，锌化合物，钴化合物和铋化合物以提供产物; 并且在另一步骤中，使产物与包含至少一种通过脲基甲酸酯基团键合的（甲基）丙烯酸羟烷基酯的多异氰酸酯（D）反应。