公开(公告)号：US20180186648A1

公开(公告)日：2018-07-05

申请号：US15315636

申请日：2015-06-03

Applicant: BASF SE

Inventor： Mathias Feyen ,  Jeff YANG ,  Roger RUETZ ,  Andreas MÜLLER

IPC: C01B39/48 ,  B01J20/18 ,  B01J20/30 ,  B01J29/70 ,  B01J37/00 ,  B01J39/14 ,  B01J39/02

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/3057 ,  B01J20/3085 ,  B01J29/7015 ,  B01J29/763 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0018 ,  B01J37/0246 ,  B01J39/02 ,  B01J39/14 ,  B01J2229/186 ,  B01J2229/42

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

公开(公告)号：US20150329368A1

公开(公告)日：2015-11-19

申请号：US14435588

申请日：2013-10-09

Applicant: BASF SE

Inventor： Andrei-Nicolae PARVULESCU ,  Jeff YANG ,  Stefan MAURER ,  Manuela GAAB ,  Karsten SEIDEL ,  Olga GERLACH ,  Ulrich MUELLER

IPC: C01B39/02 ,  C01B39/46 ,  B01J29/70

CPC classification number: C01B39/48 ,  B01J29/7038 ,  B01J35/002 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/40 ,  C01B39/026

Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

Abstract translation: 一种用于后处理具有MWW骨架结构的沸石材料的方法，该方法包括（i）提供具有MWW骨架结构的沸石材料，其中沸石材料的骨架结构包含X 2 O 3和YO 2，其中Y是 四价元素，X是三价元素，其中X 2 O 3 :YO 2的摩尔比大于0.02:1; （ii）用液体溶剂系统处理（i）中提供的沸石材料，从而获得摩尔比X2O3：YO2至多0.02:1的沸石材料，并至少部分地将沸石材料与液体溶剂系统分离; （iii）用pH值在5.5至8范围内和至少75℃的温度的液体水系统处理由（ii）得到的沸石材料。