公开(公告)号：US20190001298A1

公开(公告)日：2019-01-03

申请号：US16064756

申请日：2016-12-21

Applicant: BASF SE

Inventor： Rainer PAPP ,  Oliver Christian GOBIN ,  Oliver BEY ,  Jens RUDOLPH ,  Hans-Günter THELEN

IPC: B01J19/24 ,  B01J10/00 ,  B01J19/00 ,  C07C45/50

Abstract: Proposed is a cylindrical reactor (1) having a vertical longitudinal axis for continuous hydroformylation of a C6-C20-olefin or a mixture of C6-C20-olefins with synthesis gas in the presence of a homogeneously dissolved metal carbonyl complex catalyst, having a multiplicity of Field tubes (2) which are oriented parallel to the longitudinal axis of the reactor (1) and welded into a tube plate at the upper end of the reactor (1), having a circulation tube (3) open at both ends which envelops the Field tubes (2) and at its lower end projects beyond said tubes, having a jet nozzle (4) at the bottom of the reactor (1) for injecting the reactant mixture comprising the C6-C20-olefin, the synthesis gas and the metal carbonyl complex catalyst, wherein the Field tubes (2) are configured in terms of their number and their dimensions such that the total heat exchanger area of said tubes per unit internal volume of the reactor is in the range from 1 m2/m3 to 11 m2/m3 and the cross sectional area occupied by the Field tubes (2) per unit cross sectional area of the circulation tube (3) is in the range from 0.03 m2/m2 to 0.30 m2/m2, a gas distributor ring (5) is provided at the lower end of the circulation tube (3), at the inner wall thereof, via which a substream of the synthesis gas is feedable, and wherein one or more distributor trays (6) are provided in the circulation tube (3).

公开(公告)号：US20160265084A1

公开(公告)日：2016-09-15

申请号：US14909852

申请日：2014-07-30

Applicant: BASF SE

Inventor： Jens RUDOLPH ,  Rainer PAPP

IPC: C22B3/00 ,  C11D11/00 ,  C11D7/08 ,  C22B7/00 ,  C22B3/44

CPC classification number: C22B23/0438 ,  B01J19/002 ,  B01J19/246 ,  B01J2219/00247 ,  B01J2219/00252 ,  B08B9/08 ,  C07C45/50 ,  C11D7/08 ,  C11D11/0041 ,  C22B3/44 ,  C22B7/009 ,  C07C47/02

Abstract: Method of removing cobalt deposits in a reactor for the cobalt-catalyzed high-pressure hydroformylation of olefins by treatment with aqueous nitric acid, wherein the reactor is at least partly filled with aqueous nitric acid and the temperature of the aqueous nitric acid is increased during the treatment.

Abstract translation: 通过用硝酸水溶液处理，在钴催化的烯烃高压加氢甲酰化反应器中除去钴沉积物的方法，其中反应器至少部分地被硝酸水溶液填充，硝酸水溶液的温度在 治疗。