公开(公告)号：US20130109563A1

公开(公告)日：2013-05-02

申请号：US13661706

申请日：2012-10-26

Applicant: BASF SE

Inventor： Nils Bottke ,  Markus Schubert ,  Markus Ruf ,  Christian Walsdorff

IPC: B01J23/83 ,  C22B59/00 ,  B01J23/745

CPC classification number: B01J37/031 ,  B01J23/002 ,  B01J23/83 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2523/00 ,  C01F17/0018 ,  C07D233/32 ,  C07D487/04 ,  C22B59/00 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/842

Abstract: The invention relates to a process for preparing cerium(III) compounds which comprises the steps of a) contacting a starting composition A comprising cerium dioxide and at least one further metal oxide selected from the group consisting of iron oxide, silicon dioxide, molybdenum oxide, lanthanum oxide, magnesium oxide and calcium oxide with at least one acid S and at least one iron component E comprising iron in the oxidation state 0 and/or II at a temperature ranging from 40 to 160° C. and at a pH of not more than 2 to obtain a solution L comprising cerium in the oxidation state III; b) adding at least one basic compound C to said solution L to obtain a solid F comprising at least one cerium(III) compound; c) separating off said solid F comprising at least one cerium(III) compound.

Abstract translation: 本发明涉及一种制备铈（III）化合物的方法，其包括以下步骤：a）使包含二氧化铈和至少一种另外的金属氧化物的起始组合物A与氧化铁，二氧化硅，氧化钼， 氧化镧，氧化镁和氧化钙与至少一种酸S和至少一种含有氧化态0和/或II的铁的铁组分E在40至160℃的温度和不超过pH 以获得包含处于氧化态III的铈的溶液L; b）向所述溶液L中加入至少一种碱性化合物C以获得包含至少一种铈（III）化合物的固体F; c）分离包含至少一种铈（III）化合物的所述固体F。

公开(公告)号：US20130210620A1

公开(公告)日：2013-08-15

申请号：US13759393

申请日：2013-02-05

Applicant: BASF SE

Inventor： Christoph Kiener ,  Ulrich Müller ,  Markus Schubert

IPC: B01J20/30 ,  B01J20/28

CPC classification number: B01J20/0211 ,  B01J20/226 ,  B01J20/28042 ,  B01J20/28066 ,  B01J20/3085 ,  B01J31/1691 ,  B01J31/2239 ,  B01J2231/48 ,  B01J2231/72 ,  B01J2531/31 ,  C01B3/001 ,  C01B3/508 ,  C07C51/418 ,  Y02C10/08 ,  Y02E60/324 ,  Y10T428/249953 ,  C07C63/38 ,  C07C57/15 ,  C07C63/26

Abstract: Porous metal organic frameworks formed by AlIII ions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.

公开(公告)号：US08734652B2

公开(公告)日：2014-05-27

申请号：US13759393

申请日：2013-02-05

Applicant: BASF SE

Inventor： Christoph Kiener ,  Ulrich Müller ,  Markus Schubert

IPC: B01D15/00

CPC classification number: B01J20/0211 ,  B01J20/226 ,  B01J20/28042 ,  B01J20/28066 ,  B01J20/3085 ,  B01J31/1691 ,  B01J31/2239 ,  B01J2231/48 ,  B01J2231/72 ,  B01J2531/31 ,  C01B3/001 ,  C01B3/508 ,  C07C51/418 ,  Y02C10/08 ,  Y02E60/324 ,  Y10T428/249953 ,  C07C63/38 ,  C07C57/15 ,  C07C63/26

Abstract: Porous metal organic frameworks formed by AlIII ions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.

Abstract translation: 多孔金属有机骨架由AlIII离子形成，富马酸盐离子与其配位以产生骨架结构; 包括这种多孔金属有机骨架的成形体，以及用于为了其储存，控制释放，分离，化学反应或作为支持目的吸收物质的制备和用途。

公开(公告)号：US10307741B2

公开(公告)日：2019-06-04

申请号：US15562019

申请日：2016-03-16

Applicant: BASF SE

Inventor： Philipp Grüne ,  Christian Walsdorff ,  Markus Schubert ,  Holger Borchert ,  Jacob Cornelis Van Dorland ,  Jürgen Zühlke ,  Stefan Lipp ,  Michael Krämer

IPC: B01J27/055 ,  B01J21/08 ,  B01J35/00 ,  B01J35/04 ,  B01J37/00 ,  B01J23/22 ,  B01J35/02 ,  B01J35/10 ,  C01B17/79

Abstract: The invention relates to shaped catalyst bodies for the oxidation of SO2 to SO3, which comprise vanadium, at least one alkali metal and sulfate on a silicon dioxide support material, wherein the shaped body has the shape of a cylinder having 3 or 4 hollow-cylindrical convexities, obtainable by extrusion of a catalyst precursor composition comprising vanadium, at least one alkali metal and sulfate on a silicon dioxide support material through the opening of an extrusion tool, wherein the opening of the extrusion tool has a cross section formed by 3 or 4 partly overlapping rings whose midpoints lie essentially on a circular line having a diameter of y, wherein the rings are bounded by an outer line lying on a circle having an external diameter x1 and an inner line lying on a circle having an internal diameter x2.

公开(公告)号：US08648002B2

公开(公告)日：2014-02-11

申请号：US13734490

申请日：2013-01-04

Applicant: BASF SE

Inventor： Markus Schubert ,  Ulrich Müller ,  Stefan Marx

IPC: B01J31/00

CPC classification number: B01D53/02 ,  B01D2253/204 ,  B01J20/226 ,  B01J20/28014 ,  B01J20/28042 ,  B01J20/28054 ,  B01J31/1691 ,  B01J31/2239 ,  B01J35/1028 ,  B01J2531/31 ,  B01J2531/62 ,  B01J2531/842 ,  C07C51/418 ,  C07C63/28 ,  C07C63/38

Abstract: The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along [001] has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.

Abstract translation: 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 沿[001]的投影具有六边形的每一边由三角形界定的图案的结构。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。

公开(公告)号：US09868713B2

公开(公告)日：2018-01-16

申请号：US15119238

申请日：2015-02-17

Applicant: BASF SE

Inventor： Nico F. Fischer ,  Diana C. Galeano Nunez ,  Michael Krämer ,  Markus Schubert ,  Jürgen Zühlke ,  Hans-Martin Allmann

IPC: C07D307/89 ,  B01J35/00 ,  B01J23/18 ,  B01J23/22 ,  B01J27/198 ,  B01J35/02 ,  B01J8/06 ,  C01G30/00

CPC classification number: C07D307/89 ,  B01J8/06 ,  B01J23/18 ,  B01J23/22 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/023 ,  B01J2208/06 ,  B01J2523/00 ,  C01G30/005 ,  C01P2002/60 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/51

Abstract: The present invention relates to a catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride (PA), comprising a plurality of catalyst zones arranged in succession in the reaction tube, which have been produced using antimony trioxide comprising a noticeable proportion of senarmontite wherein some of the primary crystallites have a size of less than 200 nm. The present invention further relates to a process for gas phase oxidation, in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst system which comprises a plurality of catalyst zones arranged in succession in the reaction tube and which has been produced using an antimony trioxide comprising a noticeable proportion of senarmontite wherein some of the primary crystallites have a size of less than 200 nm.

公开(公告)号：US20130108526A1

公开(公告)日：2013-05-02

申请号：US13665166

申请日：2012-10-31

Applicant: BASF SE

Inventor： Christian Walsdorff ,  Markus Schubert ,  Stefan Altwasser ,  Steffen Buch

IPC: C22B7/00 ,  C21B3/00 ,  C22B34/34 ,  C22B59/00

CPC classification number: C22B7/009 ,  C21B3/00 ,  C22B26/00 ,  C22B34/345 ,  C22B59/00 ,  Y02P10/214 ,  Y02P10/23 ,  Y02P10/234

Abstract: A method for materials recovery from a catalyst comprising oxides of iron, cerium, molybdenum, and potassium, in which potassium and molybdenum are removed by treating the catalyst with an aqueous leachant, giving an aqueous solution S1 comprising potassium and molybdenum, and a solid residue R1 comprising cerium oxide and iron oxide, and recovering cerium in the form of a solid comprising a cerium(III) compound or cerium(IV) oxide from the solid residue R1.

Abstract translation: 从包含铁，铈，钼和钾的氧化物的催化剂中回收材料的方法，其中通过用含水浸出剂处理催化剂除去钾和钼，得到包含钾和钼的水溶液S1和固体残余物 R1包含氧化铈和氧化铁，并从固体残渣R1中回收包含铈（III）化合物或氧化铈（IV））的固体形式的铈。