公开(公告)号：US11642666B2

公开(公告)日：2023-05-09

申请号：US16979131

申请日：2019-02-19

申请人： BASF SE

发明人： Christian Walsdorff ,  Marco Oskar Kennema ,  Marcelo Daniel Kaufman Rechulski ,  Holger Borchert

IPC分类号： B01J35/02 ,  B01J21/08 ,  B01J23/22 ,  B01J27/055 ,  B01J6/00 ,  B01J35/04

CPC分类号： B01J35/026 ,  B01J6/001 ,  B01J21/08 ,  B01J23/22 ,  B01J27/055 ,  B01J35/023 ,  B01J35/04

摘要： The invention relates to a shaped catalyst body in the form of a tetralobe having four circular through-passages, with the midpoints of the through-passages forming a square and the spacings between in each case two adjacent through-passages being from 0.8 to 1.2 times the thickness of the outer walls of the through-passages. The shaped catalyst body is used for the oxidation of S02 to S03.

公开(公告)号：US20150133686A1

公开(公告)日：2015-05-14

申请号：US14535743

申请日：2014-11-07

申请人： BASF SE

发明人： Josef Macht ,  Christian Walsdorff ,  Cornelia Katharina Dobner ,  Stefan Lipp ,  Cathrin Alexandra Welker-Nieuwoudt ,  Ulrich Hammon ,  Holger Borchert

IPC分类号： B01J23/888 ,  C07C45/35 ,  C07C51/25 ,  B01J35/04

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/8876 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/026 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01G49/0036 ,  C01G51/00 ,  C01G53/00 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C04B35/495 ,  C04B35/6261 ,  C04B35/62655 ,  C04B35/62675 ,  C04B35/62685 ,  C04B35/64 ,  C04B2235/3201 ,  C04B2235/3256 ,  C04B2235/326 ,  C04B2235/3275 ,  C04B2235/3298 ,  C04B2235/44 ,  C04B2235/443 ,  C04B2235/5409 ,  C04B2235/5427 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/604 ,  C04B2235/608 ,  C04B2235/656 ,  C04B2235/72 ,  C04B2235/95 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C47/22 ,  C07C57/04

摘要： A hollow cylindrical shaped catalyst body for gas phase oxidation of an alkene to an α,β-unsaturated aldehyde and/or an α,β-unsaturated carboxylic acid comprises a compacted multimetal oxide having an external diameter ED, an internal diameter ID and a height H, wherein ED is in the range from 3.5 to 4.5 mm; the ratio q=ID/ED is in the range from 0.4 to 0.55; and the ratio p=H/ED is in the range from 0.5 to 1. The shaped catalyst body is mechanically stable and catalyzes the partial oxidation of an alkene to the products of value with high selectivity. It provides a sufficiently high catalyst mass density of the catalyst bed and good long-term stability with acceptable pressure drop.

摘要翻译： 用于将烯烃气相氧化成α，β-不饱和醛和/或α，β-不饱和羧酸的中空圆柱形催化剂体包括具有外径ED，内径ID的压实多金属氧化物，和 高度H，其中ED在3.5至4.5mm的范围内; 比值q = ID / ED在0.4至0.55的范围内; 并且比例p = H / ED在0.5至1的范围内。成形的催化剂体是机械稳定的并且以高选择性催化烯烃部分氧化成价值的产物。 它提供催化剂床的足够高的催化剂质量密度，并具有良好的长期稳定性和可接受的压降。

公开(公告)号：US20140296558A1

公开(公告)日：2014-10-02

申请号：US14305548

申请日：2014-06-16

申请人： BASF SE

发明人： Andreas RAICHLE ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel ,  Holger Borchert ,  Gerhard Cox ,  Ulrich Cremer

IPC分类号： C07C253/26 ,  C07C45/35 ,  B01J23/888

CPC分类号： C07C45/28 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/04 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [Bi1WbOx]a[Mo12Z1cZ2dFeeZ3fZ4gZ5hOy]1, in which a finely divided oxide Bi1WbOx with the particle size d50A1 and, formed from element sources, a finely divided intimate mixture of stoichiometry Mo12Z1cZ2dFeeZ3fZ4gZ5h with the particle size d90A2 are mixed in a ratio of a:1, this mixture is used to form shaped bodies and these are treated thermally, where (d50A1)0.7·(d90A2)1.5·(a)−1≧820. A shaped catalyst body obtained by the process. A catalyst obtained by grinding the shaped catalyst body. A process for heterogeneously catalyzing the partial gas phase oxidation of an alkane, alkanol, alkanal and/or an alkenal of 3 to 6 carbon atoms using the catalyst.

摘要翻译： 一种生产几何形状的催化剂体K的方法，其活性材料是化学计量[Bi1WbOx] a [Mo12Z1cZ2dFeeZ3fZ4gZ5hOy] 1的多元素氧化物，其中粒径为d50A1的细分的氧化物Bi1WbOx由元素源形成， 化学计量比的混合物Mo12Z1cZ2dFeeZ3fZ4gZ5h与粒径d90A2的混合比例为：1，该混合物用于形成成型体，热处理，其中（d50A1）0.7·（d90A2）1.5·（a）-1≧ 820。 通过该方法获得的成型催化剂体。 通过研磨成形催化剂体获得的催化剂。 使用该催化剂非均相催化烷烃，链烷醇，链烷烃和/或具有3至6个碳原子的烯烃的部分气相氧化的方法。

公开(公告)号：US20140039213A1

公开(公告)日：2014-02-06

申请号：US13958655

申请日：2013-08-05

申请人： BASF SE

发明人： Andreas RAICHLE ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel ,  Holger Borchert ,  Gerhard Cox ,  Ulrich Cremer

IPC分类号： B01J23/888 ,  C07C253/26 ,  C07C45/28

CPC分类号： C07C45/28 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/04 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [Bi1WbOx]a[Mo12Z1cZ2dFeeZ3fZ4gZ5hOy]1, in which a finely divided oxide Bi1WbOx with the particle size d50A1 and, formed from element sources, a finely divided intimate mixture of stoichiometry Mo12Z1cZ2dFeeZ3fZ4gZ5h with the particle size d90A2 are mixed in a ratio of a:1, this mixture is used to form shaped bodies and these are treated thermally, where (d50A1)0.7·(d90A2)1.5·(a)−1≧820. A shaped catalyst body obtained by the process. A catalyst obtained by grinding the shaped catalyst body. A process for heterogeneously catalyzing the partial gas phase oxidation of an alkane, alkanol, alkanal and/or an alkenal of 3 to 6 carbon atoms using the catalyst.

摘要翻译： 一种生产几何形状的催化剂体K的方法，其活性材料是化学计量[Bi1WbOx] a [Mo12Z1cZ2dFeeZ3fZ4gZ5hOy] 1的多元素氧化物，其中具有粒度d50A1的细分离氧化物Bi1WbOx，并且由元素源形成， 化学计量比的混合物Mo12Z1cZ2dFeeZ3fZ4gZ5h以a：1的比例混合，该混合物用于形成成型体，热处理，其中（d50A1）0.7·（d90A2）1.5·（a）-1> = 820。 通过该方法获得的成型催化剂体。 通过研磨成形催化剂体获得的催化剂。 使用该催化剂非均相催化烷烃，链烷醇，链烷烃和/或具有3至6个碳原子的烯烃的部分气相氧化的方法。

公开(公告)号：US20150080605A1

公开(公告)日：2015-03-19

申请号：US14487383

申请日：2014-09-16

申请人： BASF SE

发明人： Cathrin Alexandra WELKER-NIEUWOUDT ,  Cornelia Katharina Dobner ,  Holger Borchert ,  Ulrich Hammon ,  Josef Macht ,  Andrey Karpov ,  Christian Walsdorff

IPC分类号： B01J23/888 ,  B01J37/04 ,  C07C51/25 ,  B01J35/04

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0232 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  Y02P20/584 ,  Y10T428/13 ,  Y10T428/249953 ,  Y10T428/273 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  C07C57/04

摘要： What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q )  S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.

摘要翻译： 所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为至多0.3mg / mm 2，其中Q为催化剂的活性组成含量，重量％，Sm为成形载体的特定几何表面积，单位为mm2 / mg。 还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。 具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。

公开(公告)号：US20130172577A1

公开(公告)日：2013-07-04

申请号：US13779995

申请日：2013-02-28

申请人： BASF SE

发明人： Knut EGER ,  Jens Uwe Faust ,  Holger Borchert ,  Ralf Streibert ,  Klaus Joachim Mueller-Engel ,  Andreas Raichle

IPC分类号： B01J37/00 ,  C07C51/16 ,  B01J19/00 ,  C07C45/29 ,  C07C17/02 ,  C07C45/28 ,  C07D307/60

CPC分类号： B01J37/0009 ,  B01J19/00 ,  B01J23/002 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/08 ,  B01J2523/00 ,  B22F3/03 ,  B22F7/08 ,  B30B11/005 ,  B30B15/022 ,  C04B35/495 ,  C04B35/6261 ,  C04B35/62635 ,  C04B35/62655 ,  C04B35/62685 ,  C04B35/62695 ,  C04B35/64 ,  C04B2235/3201 ,  C04B2235/3256 ,  C04B2235/3258 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3298 ,  C04B2235/3418 ,  C04B2235/425 ,  C04B2235/44 ,  C04B2235/443 ,  C04B2235/5409 ,  C04B2235/5436 ,  C04B2235/5463 ,  C04B2235/6021 ,  C04B2235/604 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/6581 ,  C04B2235/6586 ,  C04B2235/80 ,  C04B2235/94 ,  C07C17/02 ,  C07C45/28 ,  C07C45/29 ,  C07C51/16 ,  C07D307/60 ,  C22C29/08 ,  C22C2204/00 ,  Y10T428/13 ,  Y10T428/131 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62 ,  B01J2523/68 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845

摘要： A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.

摘要翻译： 通过机械压实引入到模头的填充室中的粉状聚集体来生产环状氧化物体的方法，其中所得的压块的外表面相当于截头圆锥体的外表面。

公开(公告)号：US10307741B2

公开(公告)日：2019-06-04

申请号：US15562019

申请日：2016-03-16

申请人： BASF SE

发明人： Philipp Grüne ,  Christian Walsdorff ,  Markus Schubert ,  Holger Borchert ,  Jacob Cornelis Van Dorland ,  Jürgen Zühlke ,  Stefan Lipp ,  Michael Krämer

IPC分类号： B01J27/055 ,  B01J21/08 ,  B01J35/00 ,  B01J35/04 ,  B01J37/00 ,  B01J23/22 ,  B01J35/02 ,  B01J35/10 ,  C01B17/79

摘要： The invention relates to shaped catalyst bodies for the oxidation of SO2 to SO3, which comprise vanadium, at least one alkali metal and sulfate on a silicon dioxide support material, wherein the shaped body has the shape of a cylinder having 3 or 4 hollow-cylindrical convexities, obtainable by extrusion of a catalyst precursor composition comprising vanadium, at least one alkali metal and sulfate on a silicon dioxide support material through the opening of an extrusion tool, wherein the opening of the extrusion tool has a cross section formed by 3 or 4 partly overlapping rings whose midpoints lie essentially on a circular line having a diameter of y, wherein the rings are bounded by an outer line lying on a circle having an external diameter x1 and an inner line lying on a circle having an internal diameter x2.

公开(公告)号：US09700876B2

公开(公告)日：2017-07-11

申请号：US14535743

申请日：2014-11-07

申请人： BASF SE

发明人： Josef Macht ,  Christian Walsdorff ,  Cornelia Katharina Dobner ,  Stefan Lipp ,  Cathrin Alexandra Welker-Nieuwoudt ,  Ulrich Hammon ,  Holger Borchert

IPC分类号： B01J23/00 ,  B01J23/28 ,  B01J23/881 ,  B01J23/887 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  C01G39/00 ,  B01J23/888 ,  C07C45/35 ,  C07C51/25 ,  B01J37/08 ,  B01J37/00 ,  C04B35/495 ,  C04B35/626 ,  C04B35/64 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  B01J37/04

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/8876 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/026 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01G49/0036 ,  C01G51/00 ,  C01G53/00 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C04B35/495 ,  C04B35/6261 ,  C04B35/62655 ,  C04B35/62675 ,  C04B35/62685 ,  C04B35/64 ,  C04B2235/3201 ,  C04B2235/3256 ,  C04B2235/326 ,  C04B2235/3275 ,  C04B2235/3298 ,  C04B2235/44 ,  C04B2235/443 ,  C04B2235/5409 ,  C04B2235/5427 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/604 ,  C04B2235/608 ,  C04B2235/656 ,  C04B2235/72 ,  C04B2235/95 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C47/22 ,  C07C57/04

摘要： A hollow cylindrical shaped catalyst body for gas phase oxidation of an alkene to an α,β-unsaturated aldehyde and/or an α,β-unsaturated carboxylic acid comprises a compacted multimetal oxide having an external diameter ED, an internal diameter ID and a height H, wherein ED is in the range from 3.5 to 4.5 mm; the ratio q=ID/ED is in the range from 0.4 to 0.55; and the ratio p=H/ED is in the range from 0.5 to 1. The shaped catalyst body is mechanically stable and catalyzes the partial oxidation of an alkene to the products of value with high selectivity. It provides a sufficiently high catalyst mass density of the catalyst bed and good long-term stability with acceptable pressure drop.

公开(公告)号：US09238217B2

公开(公告)日：2016-01-19

申请号：US14487383

申请日：2014-09-16

申请人： BASF SE

发明人： Cathrin Alexandra Welker-Nieuwoudt ,  Cornelia Katharina Dobner ,  Holger Borchert ,  Ulrich Hammon ,  Josef Macht ,  Andrey Karpov ,  Christian Walsdorff

IPC分类号： C07C51/235 ,  B01J23/888 ,  B01J37/04 ,  B01J37/08 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J35/04 ,  C07C51/25 ,  B01J37/02 ,  B01J23/94 ,  B01J35/00 ,  B01J23/00 ,  B01J23/887

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0232 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  Y02P20/584 ,  Y10T428/13 ,  Y10T428/249953 ,  Y10T428/273 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  C07C57/04

摘要： What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) ⁢ S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.

摘要翻译： 所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为0.3mg / mm 2以下，其中，Q为催化剂的活性成分含量，重量％，Sm为成形体的比表面积，单位为mm2 / mg。 还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。 具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。

公开(公告)号：US09079840B2

公开(公告)日：2015-07-14

申请号：US13958655

申请日：2013-08-05

申请人： BASF SE

发明人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel ,  Holger Borchert ,  Gerhard Cox ,  Ulrich Cremer

IPC分类号： B01J23/00 ,  C07C45/28 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  C07C45/35 ,  C07C45/37 ,  C07C51/25 ,  C07C253/26 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04

CPC分类号： C07C45/28 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/04 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [Bi1WbOx]a[Mo12Z1cZ2dFeeZ3fZ4gZ5hOy]1, in which a finely divided oxide Bi1WbOx with the particle size d50A1 and, formed from element sources, a finely divided intimate mixture of stoichiometry Mo12Z1cZ2dFeeZ3fZ4gZ5h with the particle size d90A2 are mixed in a ratio of a:1, this mixture is used to form shaped bodies and these are treated thermally, where (d50A1)0.7·(d90A2)1.5·(a)−1≧820. A shaped catalyst body obtained by the process. A catalyst obtained by grinding the shaped catalyst body. A process for heterogeneously catalyzing the partial gas phase oxidation of an alkane, alkanol, alkanal and/or an alkenal of 3 to 6 carbon atoms using the catalyst.

摘要翻译： 一种生产几何形状的催化剂体K的方法，其活性材料是化学计量[Bi1WbOx] a [Mo12Z1cZ2dFeeZ3fZ4gZ5hOy] 1的多元素氧化物，其中粒径为d50A1的细分的氧化物Bi1WbOx由元素源形成， 化学计量比的混合物Mo12Z1cZ2dFeeZ3fZ4gZ5h与粒径d90A2的混合比例为：1，该混合物用于形成成型体，热处理，其中（d50A1）0.7·（d90A2）1.5·（a）-1≧ 820。 通过该方法获得的成型催化剂体。 通过研磨成形催化剂体获得的催化剂。 使用该催化剂非均相催化烷烃，链烷醇，链烷烃和/或具有3至6个碳原子的烯烃的部分气相氧化的方法。