公开(公告)号：US09978943B2

公开(公告)日：2018-05-22

申请号：US14361129

申请日：2012-12-03

Applicant: BASF SE

Inventor： Patrice Bujard ,  Natalia Chebotareva ,  Thomas Weitz ,  Pascal Hayoz

IPC: H01L29/08 ,  H01L51/00 ,  C09B57/00 ,  C09B69/10 ,  C08G61/12 ,  C08L65/00 ,  H01L51/05

CPC classification number: H01L51/0003 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/226 ,  C08G2261/228 ,  C08G2261/3223 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  C08L2205/02 ,  C09B57/004 ,  C09B69/105 ,  C09B69/109 ,  H01L51/002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0512 ,  H01L51/0545 ,  H01L51/0558

Abstract: The present invention provides an electronic component or device comprising a gate electrode, a source electrode and a drain electrode, wherein said component or device further comprising an organic semiconducting (OSC) material that is provided between the source and drain electrode, wherein the OSC material comprises (a) a polymer represented by formula: (I), and (b) a compound of formula (II). High quality OFETs can be fabricated by the choice of a semiconductor material, which is comprised of a polymer represented by formula I and (b) a compound of formula II.

公开(公告)号：US09550791B2

公开(公告)日：2017-01-24

申请号：US14649352

申请日：2013-12-02

Applicant: BASF SE

Inventor： Matthias Welker ,  Mathieu G. R. Turbiez ,  Natalia Chebotareva ,  Hans Jürg Kirner

IPC: C07F5/04 ,  C07F7/08 ,  C08G61/12 ,  C07D495/04 ,  H01L51/00 ,  C07F5/02 ,  C09B57/00 ,  C09B69/00 ,  C09B69/10 ,  H01L51/42 ,  H01L51/05

CPC classification number: C07D495/04 ,  C07F5/025 ,  C07F7/0814 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/1432 ,  C08G2261/146 ,  C08G2261/3243 ,  C08G2261/344 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/91 ,  C08G2261/92 ,  C09B57/00 ,  C09B57/004 ,  C09B69/008 ,  C09B69/102 ,  C09B69/109 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/0545 ,  H01L51/4253 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising a repeating unit of the formula (I), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含式（I）的重复单元的聚合物及其在有机电子器件中的用途，特别是有机光伏和光电二极管中的有机半导体，或者含有二极管和/或有机场效应晶体管的器件 。 根据本发明的聚合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

公开(公告)号：US09434812B2

公开(公告)日：2016-09-06

申请号：US14555367

申请日：2014-11-26

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Mathias Düggeli ,  Natalia Chebotareva ,  Olivier Frédéric Aebischer

IPC: C08G75/00 ,  C08G61/12 ,  B82Y10/00 ,  C08F232/08 ,  C08F234/04 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14 ,  C09B69/10 ,  H01L51/05 ,  H01L51/42

CPC classification number: C08G61/125 ,  B82Y10/00 ,  C08F232/08 ,  C08F234/04 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/12 ,  C08G2261/141 ,  C08G2261/18 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/5222 ,  C08G2261/91 ,  C08G2261/92 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1475 ,  C09K2211/1483 ,  C09K2211/1491 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0094 ,  H01L51/0512 ,  H01L51/0525 ,  H01L51/0545 ,  H01L51/424 ,  H01L51/4253 ,  H05B33/14 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula *A-D* (I), or a polymer of formula *A-DxB-Dy* (II), or *A-DrB-DsA-EtB-Eu (III), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含式* AD *（I）的一种或多种（重复）单元或式* A-DxB-Dy *（II）的聚合物或* A-DrB-DsA -EtB-Eu（III），以及它们在有机器件中的用途，特别是在有机光伏（太阳能电池）和光电二极管中的有机半导体，或在含有二极管和/或有机场效应晶体管的器件中的用途。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

公开(公告)号：US20150132887A1

公开(公告)日：2015-05-14

申请号：US14414527

申请日：2013-07-19

Applicant: BASF SE

Inventor： Matthias Welker ,  Mathieu G.R. Turbiez ,  Natalia Chebotareva ,  Hans Juerg Kirner ,  Thomas Schaefer

IPC: C08G61/12 ,  C07F5/04 ,  H01L51/00 ,  C07D519/00 ,  C07D495/14

CPC classification number: C08G61/126 ,  C07D495/14 ,  C07D519/00 ,  C07F5/04 ,  C08G61/125 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3242 ,  C08G2261/3243 ,  C08G2261/3247 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/91 ,  C08G2261/92 ,  C09B57/00 ,  C09B57/004 ,  C09B69/109 ,  H01B1/124 ,  H01L51/0002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/05 ,  H01L51/0558 ,  H01L51/42 ,  H01L51/4253 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising a repeating unit of the formula (I), and compounds of formula (VIII), or (IX), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (I), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含式（I）的重复单元和式（VIII）或（IX）的化合物的聚合物，其中Y，Y15，Y16和Y17彼此独立地是式（I）的基团， 以及它们在有机电子器件中的有机半导体的使用，特别是在有机光伏和光电二极管中的用途，或者在包含二极管和/或有机场效应晶体管的器件中的用途。 根据本发明的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物和化合物用于有机场效应晶体管，有机光伏电池（有机光伏电池）中时，可以观察到能量转换的高效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 太阳能电池）和光电二极管。

公开(公告)号：US20140299871A1

公开(公告)日：2014-10-09

申请号：US14361129

申请日：2012-12-03

Applicant: BASF SE

Inventor： Patrice Bujard ,  Natalia Chebotareva ,  Thomas Weitz ,  Pascal Hayoz

IPC: H01L51/00 ,  H01L51/05

CPC classification number: H01L51/0003 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/226 ,  C08G2261/228 ,  C08G2261/3223 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  C08L2205/02 ,  C09B57/004 ,  C09B69/105 ,  C09B69/109 ,  H01L51/002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0512 ,  H01L51/0545 ,  H01L51/0558

Abstract: The present invention provides an electronic component or device comprising a gate electrode, a source electrode and a drain electrode, wherein said component or device further comprising an organic semiconducting (OSC) material that is provided between the source and drain electrode, wherein the OSC material comprises (a) a polymer represented by formula: (I), and (b) a compound of formula (II). High quality OFETs can be fabricated by the choice of a semiconductor material, which is comprised of a polymer represented by formula I and (b) a compound of formula II.

Abstract translation: 本发明提供了一种包括栅电极，源电极和漏电极的电子部件或器件，其中所述组件或器件还包括设置在源电极和漏电极之间的有机半导体（OSC）材料，其中OSC材料 包括（a）由式（I）表示的聚合物和（b）式（II）的化合物。 可以通过选择由式I和（b）式II化合物表示的聚合物组成的半导体材料来制造高质量OFET。

公开(公告)号：US09716241B2

公开(公告)日：2017-07-25

申请号：US14965128

申请日：2015-12-10

Applicant: BASF SE

Inventor： Hans Juerg Kirner ,  Natalia Chebotareva ,  Olivier Frederic Aebischer

IPC: C08G75/00 ,  H01L51/00 ,  C07D233/28 ,  C08G61/12 ,  C07D495/04 ,  C07D513/14 ,  C07F7/08 ,  C08F128/06 ,  C08G75/06 ,  C08G75/32 ,  H01L51/05

CPC classification number: H01L51/0094 ,  C07D233/28 ,  C07D495/04 ,  C07D513/14 ,  C07F7/0814 ,  C08F128/06 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G75/06 ,  C08G75/32 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3247 ,  C08G2261/414 ,  C08G2261/92 ,  C09B57/00 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0545 ,  H01L51/0558 ,  Y02E10/549

Abstract: The present invention relates to novel compounds, corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

公开(公告)号：US20150111337A1

公开(公告)日：2015-04-23

申请号：US14385696

申请日：2013-03-27

Applicant: BASF SE

Inventor： Matthias Welker ,  Thomas Schaefer ,  Natalia Chebotareva ,  Matthias Duebner ,  Mathieu G.R. Turbiez

IPC: C08G61/12 ,  H01L51/00

CPC classification number: C08G61/126 ,  C07D405/14 ,  C07D417/14 ,  C07D519/00 ,  C08G61/125 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/18 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3242 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C09B57/00 ,  C09B57/004 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/145 ,  H01B1/127 ,  H01B1/128 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0508 ,  H01L51/0558 ,  H01L51/42 ,  H01L51/4253 ,  Y02E10/549

Abstract: Phenanthro[9,10-b]furan polymers and small molecules for electronic applications. The present invention relates to polymers comprising a repeating unit of the formula (I), (II), (VIII), (IX) and compounds of formula (VIII), or (IX), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (I), or (II), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 菲咯罗[9,10-b]呋喃聚合物和小分子电子应用。 本发明涉及包含式（I），（II），（VIII），（IX）和式（VIII）或（IX）的化合物的重复单元的聚合物，其中Y，Y15，Y16和Y17为 彼此独立地是式（I）或（II）的基团，以及它们在有机电子器件中的有机半导体的用途，特别是在有机光伏和光电二极管中，或者在含有二极管和/或有机场效应晶体管的器件中 。 根据本发明的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物和化合物用于有机场效应晶体管，有机光伏电池（有机光伏电池）中时，可以观察到能量转换的高效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 太阳能电池）和光电二极管。

公开(公告)号：US09505877B2

公开(公告)日：2016-11-29

申请号：US14385696

申请日：2013-03-27

Applicant: BASF SE

Inventor： Matthias Welker ,  Thomas Schaefer ,  Natalia Chebotareva ,  Matthias Duebner ,  Mathieu G. R. Turbiez

IPC: C08G75/00 ,  C08G61/12 ,  H01B1/12 ,  C07D405/14 ,  C07D417/14 ,  C07D519/00 ,  H01L51/00 ,  H01L51/42 ,  C09B57/00 ,  C09B69/10 ,  C09K11/06 ,  H01L51/05

CPC classification number: C08G61/126 ,  C07D405/14 ,  C07D417/14 ,  C07D519/00 ,  C08G61/125 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/18 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3242 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C09B57/00 ,  C09B57/004 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/145 ,  H01B1/127 ,  H01B1/128 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0508 ,  H01L51/0558 ,  H01L51/42 ,  H01L51/4253 ,  Y02E10/549

Abstract: Phenanthro[9,10-b]furan polymers and small molecules for electronic applications. The present invention relates to polymers comprising a repeating unit of the formula (I), (II), (VIII), (IX) and compounds of formula (VIII), or (IX), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (I), or (II), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

公开(公告)号：US09359470B2

公开(公告)日：2016-06-07

申请号：US14414527

申请日：2013-07-19

Applicant: BASF SE

Inventor： Matthias Welker ,  Mathieu G. R. Turbiez ,  Natalia Chebotareva ,  Hans Juerg Kirner ,  Thomas Schaefer

IPC: C08G75/00 ,  C08G61/12 ,  C07D495/14 ,  C07D519/00 ,  H01B1/12 ,  H01L51/00 ,  H01L51/05 ,  H01L51/42 ,  C09B57/00 ,  C09B69/10 ,  C07F5/04

CPC classification number: C08G61/126 ,  C07D495/14 ,  C07D519/00 ,  C07F5/04 ,  C08G61/125 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3242 ,  C08G2261/3243 ,  C08G2261/3247 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/91 ,  C08G2261/92 ,  C09B57/00 ,  C09B57/004 ,  C09B69/109 ,  H01B1/124 ,  H01L51/0002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/05 ,  H01L51/0558 ,  H01L51/42 ,  H01L51/4253 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising a repeating unit of the formula (I), and compounds of formula (VIII), or (IX), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (I), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含式（I）的重复单元和式（VIII）或（IX）的化合物的聚合物，其中Y，Y15，Y16和Y17彼此独立地是式（I）的基团， 以及它们在有机电子器件中的有机半导体的使用，特别是在有机光伏和光电二极管中的用途，或者在包含二极管和/或有机场效应晶体管的器件中的用途。 根据本发明的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物和化合物用于有机场效应晶体管，有机光伏电池（有机光伏电池）中时，可以观察到能量转换的高效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 太阳能电池）和光电二极管。

公开(公告)号：US20150087109A1

公开(公告)日：2015-03-26

申请号：US14555367

申请日：2014-11-26

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Mathias Düggeli ,  Natalia Chebotareva ,  Olivier Frédéric Aebischer

IPC: C08G61/12 ,  H01L51/00

CPC classification number: C08G61/125 ,  B82Y10/00 ,  C08F232/08 ,  C08F234/04 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/12 ,  C08G2261/141 ,  C08G2261/18 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/5222 ,  C08G2261/91 ,  C08G2261/92 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1475 ,  C09K2211/1483 ,  C09K2211/1491 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0094 ,  H01L51/0512 ,  H01L51/0525 ,  H01L51/0545 ,  H01L51/424 ,  H01L51/4253 ,  H05B33/14 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula *A-D* (I), or a polymer of formula *A-DxB-Dy* (II), or *A-DrB-DsA-EtB-Eu (III), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含一种或多种式（Ⅸ）的（重复）单元的聚合物，或式（Ⅸ）所示的聚合物，或* 它们用作有机器件中的有机半导体，特别是在有机光伏（太阳能电池）和光电二极管中的有机半导体，或者在含有二极管和/ 或有机场效应晶体管。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。