公开(公告)号：US20140094561A1

公开(公告)日：2014-04-03

申请号：US14038947

申请日：2013-09-27

Applicant: BASF SE

Inventor： Arno Lange ,  Theo Smit ,  Raineer Dyllick-Brenzinger ,  Oliver Gronwald ,  Gerhard Cox ,  Stefan Spange ,  Patrick Kempe ,  Tina Mark

IPC: C08L83/04

CPC classification number: C08L83/04 ,  C08G77/50

Abstract: The present invention relates to a process for producing a composite material composed of at least one inorganic or organometallic phase and one organic polymer phase with aromatic or heteroaromatic structural units, wherein homo- or copolymerization of the monomers of the formula I is performed in the presence of a base selected from organic nitrogen bases and inorganic or organic oxo bases and fluoride salts.

Abstract translation: 本发明涉及一种由至少一个无机或有机金属相和一个有机聚合物相与芳族或杂芳族结构单元组成的复合材料的制备方法，其中式I的单体的均聚或共聚在存在下进行 的碱选自有机氮碱和无机或有机氧基和氟盐。

公开(公告)号：US20140017411A1

公开(公告)日：2014-01-16

申请号：US13940835

申请日：2013-07-12

Applicant: BASF SE

Inventor： Arno Lange ,  Theo Smit ,  Rainer Dyllick-Brenzinger ,  Gerhard Cox ,  Oliver Gronwald ,  Judith Christine Bräuer ,  Stefan Spange ,  Tina Löschner ,  Patrick Kempe

IPC: C09D183/04

CPC classification number: C09D183/04 ,  C08G77/50

Abstract: The present invention relates to a process for producing composite materials formed from a) at least one inorganic or organometallic phase; and b) at least one organic polymer phase with aromatic or heteroaromatic structural units; comprising the homo- or copolymerization of at least one monomer of the formula I in which M is a metal or semimetal; R1, R2 may be the same or different and are each an Ar—C(Ra,Rb)— radical in which Ar is as defined in claim 1, or the R1Q and R2G radicals together are a radical of the formula A in which A is an aromatic or heteroaromatic ring fused to the double bond, m is 0, 1 or 2, and the R radicals may be the same or different and are as defined in claim 1; G, Q are each O, S or NH; Q is O, S or NH; and in which q, X, Y, R1′, R2′ are each as defined in claim 1; which comprises performing the polymerization of the monomers of the general formula I thermally in the absence or substantial absence of added catalysts.

Abstract translation: 本发明涉及由a）至少一种无机或有机金属相形成的复合材料的制造方法。 和b）至少一个具有芳族或杂芳族结构单元的有机聚合物相; 包括其中M是金属或半金属的至少一种式I的单体的均聚或共聚合; R 1，R 2可以相同或不同，并且各自为Ar-C（Ra，Rb） - 基团，其中Ar如权利要求1所定义，或者R1Q和R2G基团一起是式A的基团，其中A 是与双键稠合的芳族或杂芳族环，m是0,1或2，R基可以相同或不同，如权利要求1所定义; G，Q各自为O，S或NH; Q是O，S或NH; 并且其中q，X，Y，R 1'，R 2'各自如权利要求1所定义; 其包括在不存在或基本不存在添加的催化剂的情况下热分解通式I的单体。

公开(公告)号：US09580550B2

公开(公告)日：2017-02-28

申请号：US14891852

申请日：2014-05-16

Applicant: BASF SE

Inventor： Rolf-Egbert Gruetzner ,  Arno Lange ,  Lysann Kassner ,  Andreas Seifert ,  Stefan Spange

IPC: C08G69/06 ,  C08K3/36 ,  C08G69/02 ,  C08G69/14 ,  C08G69/16 ,  C08G69/42 ,  C08G77/455 ,  C08L77/00 ,  C08L77/02 ,  C08G83/00

CPC classification number: C08G69/06 ,  C08G69/02 ,  C08G69/14 ,  C08G69/16 ,  C08G69/42 ,  C08G77/455 ,  C08G83/001 ,  C08K3/36 ,  C08L77/00 ,  C08L77/02 ,  C08L83/04 ,  C08L83/02

Abstract: The invention relates to a method for producing polyamide composite materials containing silicon, comprising the copolymerisation of: a) at least one silicon compound (SV) having at least one silicon atom, said silicon atom having at least one lactamyl group of formula (A) bonded by means of the nitrogen atom thereof; b) the method also comprises copolymerisation with at least one comonomer (CM) that is selected from among ammonium salts of dicarboxylic acids, amino acids, amino acid amides and lactams. In formula (A), m represents a whole number between 1 and 11, in particular in between 2 and 9, and specifically 3, and # represents the connection to the silicon atom of the compound (SV).

Abstract translation: 本发明涉及一种生产含硅的聚酰胺复合材料的方法，包括以下共聚：a）至少一种具有至少一个硅原子的硅化合物（SV），所述硅原子具有至少一个式（A）的内酰胺基， 通过其氮原子键合; b）该方法还包括与至少一种选自二羧酸，氨基酸，氨基酰胺和内酰胺的铵盐的共聚单体（CM）的共聚。 在式（A）中，m表示1和11之间的整数，特别是在2和9之间，具体地3和＃表示与化合物（SV）的硅原子的连接。