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公开(公告)号:US20230060044A1
公开(公告)日:2023-02-23
申请号:US17758776
申请日:2021-03-05
申请人: BASF SE
发明人: Zhenji HAN , Suhao WEI , Martin SCHULTZ-DOBRICK , Hitoshi FUKUMITSU , Masatoshi MATSUMOTO , Jumpei NAKAYAMA , Junji KASHIWAGI , Daisuke MORITA
摘要: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+xTM1-xO2, wherein TM is Ni and, optionally, at least one of Co and Mn, and, optionally, at least one element selected from Al, Mg, and Ba, transition metals other than Ni, Co, and Mn, and x is in the range of from zero to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous medium, (c) partially removing water by solid-liquid separation method, (d) treating the solid residue with an aqueous formulation of at least one heteropolyacid or its respective ammonium or lithium salt, (e) treating the residue thermally.
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公开(公告)号:US20210367222A1
公开(公告)日:2021-11-25
申请号:US17250955
申请日:2019-09-20
申请人: BASF SE
发明人: Zhenji HAN , Junji KASHIWAGI , Suhao WEI , Jumpei NAKAYAMA , Daisuke MORITA , Martin SCHULZ-DOBRICK
IPC分类号: H01M4/04 , H01M4/505 , H01M4/525 , H01M4/1391 , H01M4/36 , H01M10/0525 , H01M4/62
摘要: Process for making an at least partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1−xTM1−xO2, wherein TM is Ni and, optionally, at least one of Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from zero to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous formulation containing a compound of Me wherein Me is selected from Sb, Mg, Zn, Sn, and Te, (c) separating off the water, (d) treating the residue thermally.
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公开(公告)号:US20230361295A1
公开(公告)日:2023-11-09
申请号:US18246381
申请日:2021-09-16
申请人: BASF SE
CPC分类号: H01M4/525 , H01M4/505 , H01M4/0471 , H01M4/626 , H01M2004/028
摘要: Disclosed herein is a process for manufacturing a coated cathode active material. The process includes (a) providing a particulate electrode active material according to general formula Li1+xTM1−xO2, where TM includes Ni and optionally Co and/or Mn, optionally Al, Mg, and/or Ba, and transition metals other than Ni, Co, and Mn, and where x is between zero and 0.2, (b) treating said particulate electrode active material with an aqueous solution or slurry such that at least one element selected from Al, Sb, B, Mo, W, Si and P is deposited on the surface of said particulate electrode active material, (c) removing the water by filtration, (d) adding an aqueous solution of a compound of Al, B, or Sb to the solid residue obtained from step (c), thereby depositing Al, B, and/or Sb on the surface of said solid residue, and (e) treating the residue obtained from step (d) thermally.
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4.
公开(公告)号:US20200266489A1
公开(公告)日:2020-08-20
申请号:US16061400
申请日:2016-12-08
申请人: BASF SE
IPC分类号: H01M10/0567 , H01M10/0525 , H01M10/0568 , C07C309/84
摘要: Compounds of formula (I), wherein q is 1, 2 or 3, r is 1, 2 or 3, and Y is a q+r valent non-fluorinated alkylene group Shaving 1 to 12 C-atoms, wherein one or more CH2-units of the alkylene group which are not directly bound to CN or SO2F may be replaced by O, for use in electrolyte compositions.
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公开(公告)号:US20230357051A1
公开(公告)日:2023-11-09
申请号:US18246352
申请日:2021-09-16
申请人: BASF SE
发明人: Zhenji HAN
CPC分类号: C01G53/50 , H01M4/525 , H01M4/505 , C01P2006/40 , C01P2004/61 , C01P2004/51 , C01P2006/82
摘要: Described herein is a process for manufacturing a coated cathode active material including the steps of
(a) providing a particulate electrode active material according to general formula Li1+xTM1−xO2, where TM is Ni,
(b) treating said particulate electrode active material with an aqueous medium that may include a heteropoly acid or a compound of Al or Sb,
(c) removing the water from step (b) at least partially,
(d) optionally, adding at least one heteropoly acid or a compound of Al or Sb, as particulate compound or as aqueous solution or slurry,
(e) optionally, treating the mixture from step (d) thermally,
(f) adding at least one compound selected from the group consisting of B2O3, boric acid and lithium borates to the solid material obtained from step (e), if applicable, or from step (d) or (c), respectively, and
(g) treating the residue obtained from step (f) thermally.-
公开(公告)号:US20210328218A1
公开(公告)日:2021-10-21
申请号:US17250954
申请日:2019-09-20
申请人: BASF SE
发明人: Christoph ERK , Zhenji HAN , Junji KASHIWAGI , Suhao WEI , Takayuki YAMAMURA , Daisuke MORITA , Martin SCHULZ-DOBRICK
摘要: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+1TM1−xO2, wherein TM comprises Ni and, optionally, at least one transition metal selected from Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from −0.05 to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous formulation containing an inorganic aluminum compound dispersed or slurried in water, (c) separating off the water, (d) thermal treatment of the material obtained from step (c).
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公开(公告)号:US20230406723A1
公开(公告)日:2023-12-21
申请号:US18247275
申请日:2021-09-16
申请人: BASF SE
发明人: Zhenji HAN , Jumpei NAKAYAMA , Junji KASHIWAGI , Hitoshi FUKUMITSU , Frank RAUSCHER , Christoph ERK , Thomas LETZELTER
CPC分类号: C01G53/50 , H01M4/505 , H01M4/525 , C01P2002/54 , C01P2006/40 , H01M2004/028
摘要: Described herein is a process for manufacture of a cathode active material including the steps of
(a) providing a particulate electrode active material according to general formula Li1+xTM1−xO2, where TM is Ni and, optionally, at least one element selected from the group consisting of Al, Mg, Ba, and transition metals other than Ni, and x is in a range of from −0.05 to 0.2, and where at least 50 mole-% of TM is Ni,
(b) adding an aqueous medium that includes LiOH in dissolved form to the particulate electrode active material provided in step (a),
(c) removing the liquid phase by a solid-liquid separation method, and
(d) at least partially recycling the liquid phase from step (c) for use in a treatment step.-
公开(公告)号:US20220320496A1
公开(公告)日:2022-10-06
申请号:US17595862
申请日:2020-06-29
申请人: BASF SE
发明人: Zhenji HAN , Junji KASHIWAGI , Suhao WEI , Jumpei NAKAYAMA , Daisuke MORITA
摘要: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+xTM1−xO2, wherein TM is Ni and, optionally, at least one of Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from zero to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous medium, (c) partially removing water by solid-liquid separation method, (d) treating the residue with a compound of Me, Me being selected from at least one of aluminum, boron, phosphorus, antimony, magnesium, vanadium, and tellurium, and (e) treating the residue thermally.
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9.
公开(公告)号:US20200212487A1
公开(公告)日:2020-07-02
申请号:US16619213
申请日:2018-07-18
申请人: BASF SE
发明人: Zhenji HAN , Takeo FUKUZUMI , Eri SAWADA , Martin SCHULZ-DOBRICK , Jinbum KIM
IPC分类号: H01M10/0567 , H01M10/0525 , H01M10/0569
摘要: Heterocyclic sulfonyl fluoride additives for electrolyte composition for lithium batteries An electrolyte composition containing •(i) at least one aprotic organic solvent; •(ii) at least one conducting salt; •(iii) at least one compound of formula (I) wherein R1, R2, and R3 are each independently H or a C1-C20 hydrocarbon group which may be unsubstituted or substituted by one or more substituents selected from F, CN, OS(O)2F, and S(O)2F and which may contain one or more groups selected from —O—, —S—, —C(O)O—, —OC(O)—, and —OS(O)2—; wherein at least one of R1, R2, and R3 is substituted by one or more S(O)2F groups; and •(iv) optionally one or more additives.
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10.
公开(公告)号:US20200075996A1
公开(公告)日:2020-03-05
申请号:US16479642
申请日:2018-02-02
申请人: BASF SE
发明人: Zhenji HAN , Takeo FUKUZUMI , Eri SAWADA , Martin SCHULZ-DOBRICK , Jinbum KIM
IPC分类号: H01M10/0567 , H01M10/0525 , H01M10/0569
摘要: An electrolyte composition containing at least one aprotic organic solvent; at least one conducting salt; at least one compound of formula (I) and (vi) optionally one or more additives.
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