PROCESS FOR THE MANUFACTURE OF A COATED CATHODE ACTIVE MATERIAL

    公开(公告)号:US20230361295A1

    公开(公告)日:2023-11-09

    申请号:US18246381

    申请日:2021-09-16

    申请人: BASF SE

    摘要: Disclosed herein is a process for manufacturing a coated cathode active material. The process includes (a) providing a particulate electrode active material according to general formula Li1+xTM1−xO2, where TM includes Ni and optionally Co and/or Mn, optionally Al, Mg, and/or Ba, and transition metals other than Ni, Co, and Mn, and where x is between zero and 0.2, (b) treating said particulate electrode active material with an aqueous solution or slurry such that at least one element selected from Al, Sb, B, Mo, W, Si and P is deposited on the surface of said particulate electrode active material, (c) removing the water by filtration, (d) adding an aqueous solution of a compound of Al, B, or Sb to the solid residue obtained from step (c), thereby depositing Al, B, and/or Sb on the surface of said solid residue, and (e) treating the residue obtained from step (d) thermally.

    PROCESS FOR MAKING A COATED ELECTRODE ACTIVE MATERIAL

    公开(公告)号:US20230357051A1

    公开(公告)日:2023-11-09

    申请号:US18246352

    申请日:2021-09-16

    申请人: BASF SE

    发明人: Zhenji HAN

    IPC分类号: C01G53/00 H01M4/525 H01M4/505

    摘要: Described herein is a process for manufacturing a coated cathode active material including the steps of

    (a) providing a particulate electrode active material according to general formula Li1+xTM1−xO2, where TM is Ni,
    (b) treating said particulate electrode active material with an aqueous medium that may include a heteropoly acid or a compound of Al or Sb,
    (c) removing the water from step (b) at least partially,
    (d) optionally, adding at least one heteropoly acid or a compound of Al or Sb, as particulate compound or as aqueous solution or slurry,
    (e) optionally, treating the mixture from step (d) thermally,
    (f) adding at least one compound selected from the group consisting of B2O3, boric acid and lithium borates to the solid material obtained from step (e), if applicable, or from step (d) or (c), respectively, and
    (g) treating the residue obtained from step (f) thermally.

    PROCESS FOR MAKING A PARTIALLY COATED ELECTRODE ACTIVE MATERIAL

    公开(公告)号:US20210328218A1

    公开(公告)日:2021-10-21

    申请号:US17250954

    申请日:2019-09-20

    申请人: BASF SE

    IPC分类号: H01M4/525 H01M4/505 H01M4/04

    摘要: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+1TM1−xO2, wherein TM comprises Ni and, optionally, at least one transition metal selected from Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from −0.05 to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous formulation containing an inorganic aluminum compound dispersed or slurried in water, (c) separating off the water, (d) thermal treatment of the material obtained from step (c).

    PROCESS FOR MAKING A COATED ELECTRODE ACTIVE MATERIAL

    公开(公告)号:US20220320496A1

    公开(公告)日:2022-10-06

    申请号:US17595862

    申请日:2020-06-29

    申请人: BASF SE

    摘要: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+xTM1−xO2, wherein TM is Ni and, optionally, at least one of Co and Mn, and, optionally, at least one element selected from Al, Mg, Ba and B, transition metals other than Ni, Co, and Mn, and x is in the range of from zero to 0.2, wherein at least 50 mole-% of the transition metal of TM is Ni, (b) treating said electrode active material with an aqueous medium, (c) partially removing water by solid-liquid separation method, (d) treating the residue with a compound of Me, Me being selected from at least one of aluminum, boron, phosphorus, antimony, magnesium, vanadium, and tellurium, and (e) treating the residue thermally.

    HETEROCYCLIC SULFONYL FLUORIDE ADDITIVES FOR ELECTROLYTE COMPOSITION FOR LITHIUM BATTERIES

    公开(公告)号:US20200212487A1

    公开(公告)日:2020-07-02

    申请号:US16619213

    申请日:2018-07-18

    申请人: BASF SE

    摘要: Heterocyclic sulfonyl fluoride additives for electrolyte composition for lithium batteries An electrolyte composition containing •(i) at least one aprotic organic solvent; •(ii) at least one conducting salt; •(iii) at least one compound of formula (I) wherein R1, R2, and R3 are each independently H or a C1-C20 hydrocarbon group which may be unsubstituted or substituted by one or more substituents selected from F, CN, OS(O)2F, and S(O)2F and which may contain one or more groups selected from —O—, —S—, —C(O)O—, —OC(O)—, and —OS(O)2—; wherein at least one of R1, R2, and R3 is substituted by one or more S(O)2F groups; and •(iv) optionally one or more additives.