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公开(公告)号：US09840683B2
公开(公告)日：2017-12-12
申请号：US14807924
申请日：2015-07-24
Applicant: Ecolab USA Inc. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie E. Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
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2.发明授权公开(公告)号：US10858613B2
公开(公告)日：2020-12-08
申请号：US16267037
申请日：2019-02-04
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie E. Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
Abstract: A highly alkaline detergent is described which includes the use of a carboxylic acid terpolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling at application temperatures, for example at temperatures of between about 145-180 degrees Fahrenheit and, for example, at a pH of 9.5 to about 13.
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公开(公告)号：US09487738B2
公开(公告)日：2016-11-08
申请号：US14049989
申请日：2013-10-09
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D17/0047 , C11D3/0036 , C11D3/10 , C11D3/378 , C11D17/0052
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
Abstract translation: 描述了用于固化基质和固体洗涤剂组合物的稳定性增强剂。 通过形成尺寸稳定的固体组合物的可水合盐，水和羧酸三元共聚物来提供稳定性增强。 优选的羧酸三元共聚物包括约40至90重量％的羧酸单体，其酸酐或其盐，约4至40重量％的包含磺基的单体和约4至40重量％的 式（I）所示的非离子单体。 用于固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的，并且可以基本上不含磷酸盐和/或无NTA，并提供有益的硬水垢控制。
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4.发明授权Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control 有权含有用于硬水垢控制的羧酸/聚环氧烷共聚物的碱性洗涤剂组合物公开(公告)号：US09127235B2
公开(公告)日：2015-09-08
申请号：US14049883
申请日：2013-10-09
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
Abstract translation: 描述了一种碱性洗涤剂，其包括使用与碱金属氢氧化物组合的共聚物。 洗涤剂保持清洁功能，并且还防止硬水垢，例如在145-180华氏度的应用温度和9.5至约13的pH之间。
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5.发明申请ALKALINE DETERGENT COMPOSITION CONTAINING A CARBOXYLIC ACID/POLYALKYLENE OXIDE COPOLYMER FOR HARD WATER SCALE CONTROL 有权含有羧酸/碱金属氧化物共聚物的碱性洗涤剂组合物用于硬水规模控制公开(公告)号：US20150099685A1
公开(公告)日：2015-04-09
申请号：US14049883
申请日：2013-10-09
Applicant: BASF SE , Ecolab USA Inc.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
IPC: C11D3/04
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
Abstract translation: 描述了一种碱性洗涤剂，其包括使用与碱金属氢氧化物组合的共聚物。 洗涤剂保持清洁功能，并且还防止硬水垢，例如在145-180华氏度的应用温度和9.5至约13的pH之间。
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Patent Agency Ranking
6.发明授权Alkaline detergent composition containing a carboxylic acid terpolymer for hard water scale control 有权含有用于硬水垢控制的羧酸三元共聚物的碱性洗涤剂组合物公开(公告)号：US09127236B2
公开(公告)日：2015-09-08
申请号：US14049951
申请日：2013-10-09
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/3757 , C02F1/683 , C02F5/08 , C02F2303/22 , C11D3/044 , C11D3/3707 , C11D3/3761 , C11D3/3765 , C11D3/378 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: A highly alkaline detergent is described which includes the use of a carboxylic acid terpolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling at application temperatures, for example at temperatures of between about 145-180 degrees Fahrenheit and, for example, at a pH of 9.5 to about 13.
Abstract translation: 描述了一种高碱性洗涤剂，其包括使用与碱金属氢氧化物组合的羧酸三元共聚物。 洗涤剂保持清洁功能并且还防止在施用温度下的硬水垢，例如在约145-180华氏度的温度和例如9.5至约13的pH之间。
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公开(公告)号：US20150099687A1
公开(公告)日：2015-04-09
申请号：US14049989
申请日：2013-10-09
Applicant: BASF SE , ECOLAB USA INC.
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
IPC: C11D3/37
CPC classification number: C11D17/0047 , C11D3/0036 , C11D3/10 , C11D3/378 , C11D17/0052
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
Abstract translation: 描述了用于固化基质和固体洗涤剂组合物的稳定性增强剂。 通过形成尺寸稳定的固体组合物的可水合盐，水和羧酸三元共聚物来提供稳定性增强。 优选的羧酸三元共聚物包括约40至90重量％的羧酸单体，其酸酐或其盐，约4至40重量％的包含磺基的单体和约4至40重量％的 式（I）所示的非离子单体。 用于固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的，并且可以基本上不含磷酸盐和/或无NTA，并提供有益的硬水垢控制。
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公开(公告)号：US20150329804A1
公开(公告)日：2015-11-19
申请号：US14807924
申请日：2015-07-24
Applicant: Ecolab USA Inc. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie E. Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
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9.发明申请公开(公告)号：US20150099686A1
公开(公告)日：2015-04-09
申请号：US14049951
申请日：2013-10-09
Applicant: BASF SE , ECOLAB USA INC.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
IPC: C11D3/04
CPC classification number: C11D3/3757 , C02F1/683 , C02F5/08 , C02F2303/22 , C11D3/044 , C11D3/3707 , C11D3/3761 , C11D3/3765 , C11D3/378 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: A highly alkaline detergent is described which includes the use of a carboxylic acid terpolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling at application temperatures, for example at temperatures of between about 145-180 degrees Fahrenheit and, for example, at a pH of 9.5 to about 13.
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公开(公告)号：US20170009190A1
公开(公告)日：2017-01-12
申请号：US15272848
申请日：2016-09-22
Applicant: Ecolab USA Inc.
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D17/0047 , C11D3/0036 , C11D3/10 , C11D3/378 , C11D17/0052
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
Abstract translation: 描述了用于固化基质和固体洗涤剂组合物的稳定性增强剂。 通过形成尺寸稳定的固体组合物的可水合盐，水和羧酸三元共聚物来提供稳定性增强。 优选的羧酸三元共聚物包括约40至90重量％的羧酸单体，其酸酐或其盐，约4至40重量％的包含磺基的单体和约4至40重量％的 式（I）所示的非离子单体。 用于固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的，并且可以基本上不含磷酸盐和/或无NTA，并提供有益的硬水垢控制。
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