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公开(公告)号：US09765286B2
公开(公告)日：2017-09-19
申请号：US14578878
申请日：2014-12-22
Applicant: Ecolab USA Inc.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters
CPC classification number: C11D3/044 , C11D3/10 , C11D3/364 , C11D3/3765 , C11D3/3773
Abstract: Alkaline ware wash detergents containing an alkali metal alkalinity source and alkanol amine phosphonate scale inhibitors and methods of employing the same for superior cleaning efficacy and hard water scale control are disclosed. Alkanol amine phosphonates beneficially reduce scale build-up, including calcium carbonate scale build-up from alkaline detergents used with hard water sources. Methods of employing the detergent compositions are also disclosed.
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2.发明申请公开(公告)号：US20150099686A1
公开(公告)日：2015-04-09
申请号：US14049951
申请日：2013-10-09
Applicant: BASF SE , ECOLAB USA INC.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
IPC: C11D3/04
CPC classification number: C11D3/3757 , C02F1/683 , C02F5/08 , C02F2303/22 , C11D3/044 , C11D3/3707 , C11D3/3761 , C11D3/3765 , C11D3/378 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: A highly alkaline detergent is described which includes the use of a carboxylic acid terpolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling at application temperatures, for example at temperatures of between about 145-180 degrees Fahrenheit and, for example, at a pH of 9.5 to about 13.
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公开(公告)号：US20170009190A1
公开(公告)日：2017-01-12
申请号：US15272848
申请日：2016-09-22
Applicant: Ecolab USA Inc.
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D17/0047 , C11D3/0036 , C11D3/10 , C11D3/378 , C11D17/0052
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
Abstract translation: 描述了用于固化基质和固体洗涤剂组合物的稳定性增强剂。 通过形成尺寸稳定的固体组合物的可水合盐，水和羧酸三元共聚物来提供稳定性增强。 优选的羧酸三元共聚物包括约40至90重量％的羧酸单体，其酸酐或其盐，约4至40重量％的包含磺基的单体和约4至40重量％的 式（I）所示的非离子单体。 用于固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的，并且可以基本上不含磷酸盐和/或无NTA，并提供有益的硬水垢控制。
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4.发明申请WAREWASHING COMPOSITION CONTAINING ALKANOL AMINE PHOSPHONATE AND METHODS OF USE 有权含有ALKANOL氨基磷酸酯的组合物及其使用方法公开(公告)号：US20160177233A1
公开(公告)日：2016-06-23
申请号：US14578878
申请日：2014-12-22
Applicant: Ecolab USA Inc.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters
CPC classification number: C11D3/044 , C11D3/10 , C11D3/364 , C11D3/3765 , C11D3/3773
Abstract: Alkaline ware wash detergents containing an alkali metal alkalinity source and alkanol amine phosphonate scale inhibitors and methods of employing the same for superior cleaning efficacy and hard water scale control are disclosed. Alkanol amine phosphonates beneficially reduce scale build-up, including calcium carbonate scale build-up from alkaline detergents used with hard water sources. Methods of employing the detergent compositions are also disclosed.
Abstract translation: 公开了含有碱金属碱性源和烷醇胺膦酸盐垢抑制剂的碱性洗涤剂洗涤剂及其用于优异的清洁效果和硬水垢控制的方法。 烷醇胺膦酸盐有利地减少了由硬水源使用的碱性洗涤剂的碳酸钙垢积累的积垢。 还公开了使用洗涤剂组合物的方法。
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公开(公告)号：US20130109606A1
公开(公告)日：2013-05-02
申请号：US13719383
申请日：2012-12-19
Applicant: ECOLAB USA INC.
Inventor： Carter M. Silvernail , Kerrie Walters
IPC: C11D17/00
CPC classification number: C11D17/0047 , C11D3/2082
Abstract: A stability enhancement agent for use in a solid detergent and solid detergent compositions is described. Stability enhancement is provided by a hydratable salt, water and a polyepoxysuccinic acid or polyepoxysuccinic acid metal salt binding agent forming a dimensionally stable composition. Preferred polyepoxysuccinic acid or polyepoxysuccinic acid metal salts have a molecular weight of between about 400 and about 1,500 g/mol. The stability enhancement composition for use in a solid detergent and solid detergent compositions are preferably biodegradable and substantially free of phosphorus and NTA.
Abstract translation: 描述了用于固体洗涤剂和固体洗涤剂组合物的稳定性增强剂。 通过可水合的盐，水和形成尺寸稳定的组合物的聚环氧琥珀酸或聚环氧琥珀酸金属盐粘合剂提供稳定性增强。 优选的聚环氧琥珀酸或聚环氧琥珀酸金属盐的分子量为约400至约1,500g / mol。 用于固体洗涤剂和固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的并且基本上不含磷和NTA。
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Patent Agency Ranking
公开(公告)号：US09487738B2
公开(公告)日：2016-11-08
申请号：US14049989
申请日：2013-10-09
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D17/0047 , C11D3/0036 , C11D3/10 , C11D3/378 , C11D17/0052
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
Abstract translation: 描述了用于固化基质和固体洗涤剂组合物的稳定性增强剂。 通过形成尺寸稳定的固体组合物的可水合盐，水和羧酸三元共聚物来提供稳定性增强。 优选的羧酸三元共聚物包括约40至90重量％的羧酸单体，其酸酐或其盐，约4至40重量％的包含磺基的单体和约4至40重量％的 式（I）所示的非离子单体。 用于固体洗涤剂组合物的稳定性增强组合物优选是可生物降解的，并且可以基本上不含磷酸盐和/或无NTA，并提供有益的硬水垢控制。
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7.发明授权Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control 有权含有用于硬水垢控制的羧酸/聚环氧烷共聚物的碱性洗涤剂组合物公开(公告)号：US09127235B2
公开(公告)日：2015-09-08
申请号：US14049883
申请日：2013-10-09
Applicant: ECOLAB USA INC. , BASF SE
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
Abstract translation: 描述了一种碱性洗涤剂，其包括使用与碱金属氢氧化物组合的共聚物。 洗涤剂保持清洁功能，并且还防止硬水垢，例如在145-180华氏度的应用温度和9.5至约13的pH之间。
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8.发明申请ALKALINE DETERGENT COMPOSITION CONTAINING A CARBOXYLIC ACID/POLYALKYLENE OXIDE COPOLYMER FOR HARD WATER SCALE CONTROL 有权含有羧酸/碱金属氧化物共聚物的碱性洗涤剂组合物用于硬水规模控制公开(公告)号：US20150099685A1
公开(公告)日：2015-04-09
申请号：US14049883
申请日：2013-10-09
Applicant: BASF SE , Ecolab USA Inc.
Inventor： Carter M. Silvernail , Erik C. Olson , Kerrie Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
IPC: C11D3/04
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
Abstract translation: 描述了一种碱性洗涤剂，其包括使用与碱金属氢氧化物组合的共聚物。 洗涤剂保持清洁功能，并且还防止硬水垢，例如在145-180华氏度的应用温度和9.5至约13的pH之间。
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9.发明申请DETERGENT COMPOSITION COMPRISING ALKALI METAL HYDROXIDE AND METHODS OF MODIFYING A SURFACE 审中-公开包含碱金属氢氧化物的洗涤剂组合物和修饰表面的方法公开(公告)号：US20140121150A1
公开(公告)日：2014-05-01
申请号：US13786760
申请日：2013-03-06
Applicant: ECOLAB USA INC.
Inventor： Kerrie Walters , Monique Roerdink-Lander , Carter M. Silvernail
IPC: C11D3/37
CPC classification number: C11D1/66 , C11D3/044 , C11D3/365 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D3/3784 , C11D11/0023
Abstract: An alkaline detergent is described which includes the use of polycarboxylic acid copolymers or salts thereof in combination with alkali metal hydroxide. The detergent composition reduces spotting and filming and prevents hard water scale accumulation between 145-180 degrees Fahrenheit and with a pH of 10.5 to about 13.
Abstract translation: 描述了一种碱性洗涤剂，其包括使用多元羧酸共聚物或其盐与碱金属氢氧化物的组合。 洗涤剂组合物减少斑点和成膜，并防止145-180华氏度之间的硬水垢积聚和10.5至约13的pH。
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公开(公告)号：US10364409B2
公开(公告)日：2019-07-30
申请号：US15272848
申请日：2016-09-22
Applicant: Ecolab USA Inc.
Inventor： Kerrie Walters , Carter M. Silvernail , Juergen Detering , Arend Jouke Kingma , James S. Dailey
Abstract: Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
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