Abstract:
New N-arylcarbamic acid esters of the formula
wherein R4 is hydrogen or is defined as R4 is defined above, and Y and Y'' are oxygen or sulfur, ARE OUTSTANDINGLY EFFECTIVE IN REGULATING THE GROWTH OF PLANTS, I.E., TO INHIBIT, STIMULATE OR ALTER THE GROWTH OF PLANTS.
IN WHICH R is lower aliphatic hydrocarbyl, optionally substituted, R1, R2 and R3, which may be identical or different, are each hydrogen, alkyl, cycloalkyl, alkoxy, haloalkyl or halogen, R4 is alkyl, alkenyl, alkynyl, cycloalkenyl, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl or alkylthioalkyl, acylalkyl (i.e., alkanoyloxyalkyl), alkoxycarbonylalkyl, carbalkoxyalkyl, carbalkoxyalkenyl, or an optionally substituted cycloalkyl, aryl, aralkyl, aryloxyalkyl or arylthioalkyl radical, or the grouping
Abstract:
PHENYL-IMIDAZOLYLALKANYL DERIVATIVES ARE ANTIMYCOTIC AGENTS. THEY ARE PREPARED BY A NUMBER OF PROCESSES INCLUDING ACYLATION OR SULFONYLATION OF A PHENYL-IMIDAZOLYLALKANOL, TREATMENT OF A PHENYL-ALKANYL-CARBINOL WITH A DIIMIDAZOLLYL SULFONE, OXIDATION OF A PHENYL-IMIDAZOLYLALKYLMERCAPTAN OR REDUCTION OF A PHENYL-IMIDAZOLYLALKYLANOTE OR ALKANONITRILE. A TYPICAL EMBODIMENT IS 1-(1,1-DIPHENYL-2-ACETOXYETHYL) IMIDAZOLE.
Abstract:
Phenyl-imidazolylalkanyl derivatives are antimycotic agents. They are prepared by a number of processes including acylation or sulfonylation of a phenyl-imidazolylalkanol, treatment of a phenyl-alkanyl-carbinol with a diimidazolyl sulfone, oxidation of a phenyl-imidazolylalkylmercaptan or reduction of a phenylimidazolylalkanoate or alkanonitrile. A typical embodiment is 1(1,1-diphenyl-2-acetoxyethyl)imidazole.
Abstract:
N-(3-(ALKYL, ALKYLMERCAPTO, DIALKYLAMINO AND PHENYLSUBSTITUTED)-1,2,4-THIADIAZOL-5-YL) - N - (UNSUBSTITUTED AND ALKYL-SUBSTITUTED)-N'',N''-(MONO- AND DI-ALKYL-SUBSTITUTED) UREAS WHICH POSSESS HERBICIDAL PROPERTIES, AND WHICH MAY BE PRODUCED BY CONVENTIONAL METHODS.
Abstract:
((ALKYL,HALOALKYL, ALKOXY AND PHENOXY)-CARBONYL)-N(3-ALKYL AND PHENYL-1,2,4-THIADIAZOL-5-YL)-AMIDES, I.E. (ALKANOYL, HALOALKANOYL, CARBOALKOXY AND CARBOPHENOXY)-N-(3-ALKYL AND PHENYL-1,2,4-THIADIAZOL-5-YL)-AMIDES OR (ALKANOIC, HALOAKANOIC, MONOALKYL CARBONIC AND MONOPHENYL CARBONIC ACID)-N-(3-ALKYL AND PHENYL-1,2,4THIADIAZOL-5-YL)-AMIDES, WHICH POSSESS HERBICIDAL PROPERTIES, AND WHICH MAY BE PRUCED BY CONVENTIONAL METHODS.
Abstract:
N-(3-(alkyl, alkylmercapto, dialkylamino and phenylsubstituted)-1,2,4-thiadiazol-5-yl)-N-(unsubstituted and alkylsubstituted)-N'',N''-(mono- and di- -alkyl-substituted) ureas which possess herbicidal properties, and which may be produced by conventional methods.
Abstract:
Antimicrobial aminoalkyl phenyl-azolylalkanoates and N(aminoalkyl)phenyl-azolylalkanamides and salts thereof are prepared by treatment of the corresponding phenyl-halo-alkanoate or alkanamide with an azolyl compound or saalt thereof, treatment of the corresponding phenyl-hydroxyalkanoate or phenylhydroxyalkanamide with an azole compound under dehydration conditions or with a thionyl-bis-azole, or transesterification or amidation of a (lower)alkyl phenyl-azolylalkanoate. A typical embodiment is diphenyl-imidazolyl-acetic acid 1-dimethylamino-2propyl ester.
ARE OUTSTANDINGLY EFFECTIVE HERBICIDES PARTICULARLY WHEN USED AS SELECTIVE HERBICIDES AND ARE OUTSTANDINGLY TOLERATED BY CROP PLANTS.
IN WHICH R and R4 are, e.g., optionally substituted aliphatic hydrocarbyl; R1, R2, and R3 represent hydrogen, alkyl, cycloalkyl, alkoxy, haloalkyl and/or halogen; Furthermore R2 and R3 conjointly may represent a -(CH)4grouping to form a fused benzene ring with the adjacent atoms of the phenyl ring shown in the formula X is sulfur; Y is oxygen, sulfur or a group of the formula