Process for preparing pure cyanogen chloride
    1.
    发明授权
    Process for preparing pure cyanogen chloride 失效
    纯氯化氰的制备方法

    公开(公告)号:US3897541A

    公开(公告)日:1975-07-29

    申请号:US30766372

    申请日:1972-11-17

    Applicant: BAYER AG

    CPC classification number: C01C3/004

    Abstract: Pure cyanogen chloride free of water and cyanuric chloride is prepared by reacting gaseous hydrocyanic acid and chlorine gas in the presence of an active carbon catalyst at temperatures of from 500*C to 700*C to form cyanogen chloride and hydrogen chloride and thereafter recovering the pure cyanogen chloride. The active carbon has a specific surface of from about 800 to 1,100 m2/g and the residence time of the reaction gas is between about 0.02 and 2.0 seconds.

    Abstract translation: 通过在活性炭催化剂存在下,在500-700℃的温度下使气体氢氰酸和氯气反应制备纯水和氰尿酰氯,形成氯化氰和氯化氢,然后回收纯的 氯化氰 活性炭的比表面积为约800〜1100m 2 / g,反应气体的停留时间为约0.02〜2.0秒。

    Process for purifying liquid hydrocyanic acid by acid addition and subsequent separation
    2.
    发明授权
    Process for purifying liquid hydrocyanic acid by acid addition and subsequent separation 失效
    通过酸添加和后续分离来净化液体酸的方法

    公开(公告)号:US3655519A

    公开(公告)日:1972-04-11

    申请号:US3655519D

    申请日:1969-01-31

    CPC classification number: C01C3/0295

    Abstract: Purification of hydrocyanic acid such as obtained from ammoxidation by reacting the crude product containing aliphatic and/or isocyclic unsaturated hydrocarbons and/or heterocyclic compounds with a hydrohalic acid or an oxyacid of sulfur or phosphorus, preferably in concentrated form, and thereafter separating the reaction products from the hydrocyanic acid, such as by distillation or adsorption, and recovering substantially pure hydrocyanic acid.

    Abstract translation: 通过将含有脂族和/或环状不饱和烃和/或杂环化合物的粗产物与硫酸或磷的氢卤酸或含氧酸反应,优选浓缩形式,然后将反应产物分离,从氨氧化得到的氢氰酸的纯化 例如通过蒸馏或吸附从氢氰酸中回收基本上纯的氢氰酸。

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