Oxidation of cyclic mono-olefins to {60 ,{107 -dialdeydes
    2.
    发明授权
    Oxidation of cyclic mono-olefins to {60 ,{107 -dialdeydes 失效
    将环状单烯烃氧化为{60,{10-二烯

    公开(公告)号:US3923903A

    公开(公告)日:1975-12-02

    申请号:US41985273

    申请日:1973-11-28

    Applicant: BAYER AG

    CPC classification number: C07C45/34 C07C47/12

    Abstract: A process for the production of an Alpha - omega -dialdehyde, comprising reacting a cyclic mono-olefin in the gaseous phase with oxygen at an elevated temperature. Preferably cyclopentene or cyclohexene respectively give glutardialdehyde and adipic dialdehyde by passage through a tubular reactor with air at 0.05 to 100 atmospheres and 200* to 500*C.

    Abstract translation: 一种制备α-ω-二醛的方法,包括使气相中的环状单烯烃与氧在升高的温度下反应。 优选环戊烯或环己烯分别通过具有0.05-100个大气压和200-500℃的空气的管式反应器产生戊二醛和己二醛。

    Catalytic process for preparing 3-halogen- and 3,5-dihalogen-phenols
    3.
    发明授权
    Catalytic process for preparing 3-halogen- and 3,5-dihalogen-phenols 失效
    用于制备3-卤代和3,5-二氢苯酚的催化方法

    公开(公告)号:US3912782A

    公开(公告)日:1975-10-14

    申请号:US41985373

    申请日:1973-11-28

    Applicant: BAYER AG

    CPC classification number: B01J27/04 B01J37/20

    Abstract: 3-HALOGEN- AND 3,5-DIHALOGEN-PHENOLS ARE PREPARED FROM HIGHERHALOGENATED COMPOUNDS HAVING THE FORMULA

    WHEREIN X represents halogen, R1, R2, R3 and R4 independently of one another represent hydrogen, halogen an alkyl, aralkyl, aryl, alkoxy, aryloxy, alkyl mercapto or dialkylaminomethyl radical, IN ADDITION TO WHICH AT LEAST ONE OF THE RADICALS R1, R2 or R4 represents a halogen atom, whilst the radical R3 can also represent a hydroxy group and, in the case of 3,5dihalogenphenols, exclusively represents a halogen atom, R represents OH, in addition to which R together with R1 can represent the radical - O- CH2 - O -CH2, the phenol oxygen atom standing for R, in which case X, R2, R3 and R4 independently of one another represent hydrogen, halogen or an alkyl radical and at least one of the radicals X or R3 and at least one of the radicals R2 or R4 represents a halogen atom.

    Process and catalyst for preparing of 3-halogen-and 3,5-dihalogen-phenols
    5.
    发明授权
    Process and catalyst for preparing of 3-halogen-and 3,5-dihalogen-phenols 失效
    制备3-恶唑烷酮和3,5-二氢苯酚的方法和催化剂

    公开(公告)号:US3912783A

    公开(公告)日:1975-10-14

    申请号:US41985573

    申请日:1973-11-28

    Applicant: BAYER AG

    CPC classification number: B01J37/20 B01J27/04

    Abstract: 3-Halogen- and 3,5-dihalogen-phenols are prepared from higherhalogenated compounds having the formula

    WHEREIN: X represents halogen, R1, R2, R3 and R4 independently of one another represent hydrogen, halogen, an alkyl, aralkyl, aryl, alkoxy aryloxy, alkylmercapto or dialkylaminomethyl radical, in addition to which at least one of the radicals R1, R2 or R4 represents a halogen atom while the radical R3 can also represent a hydroxy group and, in the case of 3,5dihalogenphenols, exclusively represents a halogen atom, R represents OH, in addition to which R together with R1 can represent the radical - O - CH2 - O - CH2 -, the phenol oxygen atom standing for R, in which case, X, R2, R3 and R4 independently of one another represent hydrogen, halogen or an alkyl radical and at least one of the radicals X or R3 and at least one of the radicals R2 or R4 represents a halogen atom, by reacting same with hydrogen at elevated temperature in the presence of noble metals of Group VIII of the Periodic System and catalysts containing sulphur and/or sulphur compounds.

    Cellulose-containing textiles colored with reactive dyestuffs
    7.
    发明授权
    Cellulose-containing textiles colored with reactive dyestuffs 失效
    含有纤维素的纺织品与反应性染料混合

    公开(公告)号:US3519642A

    公开(公告)日:1970-07-07

    申请号:US3519642D

    申请日:1968-07-30

    Applicant: BAYER AG

    Abstract: The invention comprises dyestuffs of the formula where F is an organic dyestuff radical, R is alkylene or cycloalkylene, R2 is alkylene, R1 is -S-or where X is hydrogen, an araliphatic or cycloaliphatic substituent or an aliphatic radical which may form part of a heterocyclic nitrogen-containing 5 or 6 membered ring, Y is a substituent which, upon treatment with alkaline substances and/or heat, may be split off as a negative ion leaving R2 with a positive charge, and n is a whole number. Organic dyestuffs specified are those of the azo, anthraquinone, triphenylmethane, oxazine or azaporphin series, and values specified for Y are the sulphuric acid ester, phosphoric acid ester and sulphonyloxy groups and halogen atoms. The dyestuffs are made by reacting a dyestuff sulphonic acid chloride or carboxylic acid chloride with an amine containing the group -R-R1-R2-Y, by esterifying dyestuffs of the above general formula but wherein the group Y is hydroxyl, or by synthesising the dyestuffs from dyestuff intermediates already containing the group -R-R1-R2-Y, for example by diazotisation and coupling in the case of azo dyestuffs. The dyestuffs dye and print textile materials of natural or regenerated cellulose in conjunction with an alkali and heat treatment, and wool and silk from a weakly alkaline or neutral medium to give a variety of shades. Reference has been directed by the Comptroller to Specifications 835,819 and 868,741.

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