公开(公告)号：US20160244555A1

公开(公告)日：2016-08-25

申请号：US15025980

申请日：2014-10-16

Applicant: BIOCHEMTEX S.P.A.

Inventor： Marco BERNARDI ,  Daniela TODARO ,  Chiara DORATI

IPC: C08G63/183 ,  B01J21/18 ,  B01J21/04 ,  C01B3/32 ,  B01J23/42 ,  B01J23/46 ,  B01J23/755

CPC classification number: C08G63/183 ,  B01J21/04 ,  B01J21/18 ,  B01J23/42 ,  B01J23/462 ,  B01J23/755 ,  C01B3/323 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/06 ,  C01B2203/065 ,  C01B2203/1217 ,  C07C29/00 ,  C07C29/132 ,  C07C29/60 ,  Y02P20/145 ,  Y02P20/52 ,  C07C31/18 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225

Abstract: It is disclosed a process for producing a low boiling mixture comprising ethylene glycol and propylene glycol from a liquid sugar stream derived from a ligno-cellulosic biomass feedstock. The liquid sugar stream is catalytically converted in the presence of hydrogen to a mixture, which is separated into at least a high boiling mixture, comprising glycerol, and the low boiling mixture. The high boiling mixture is converted to hydrogen by reforming and the reforming hydrogen is used in the catalytical steps. Preferably, all the hydrogen used in the conversion process is generated by aqueous phase reforming of the high boiling polyols mixture.

Abstract translation: 公开了一种从源自木质纤维素生物质原料的液体糖流中生产包含乙二醇和丙二醇的低沸点混合物的方法。 将液体糖流在氢存在下催化转化成混合物，将其分离成至少包含甘油的高沸点混合物和低沸点混合物。 通过重整将高沸点混合物转化为氢，并且在催化步骤中使用重整氢。 优选地，转化过程中使用的所有氢通过高沸点多元醇混合物的水相重整产生。

公开(公告)号：US20170058078A1

公开(公告)日：2017-03-02

申请号：US14915661

申请日：2014-09-02

Applicant: Ivana Tanzi ,  BIOCHEMTEX S.P.A.

Inventor： Beatriz RIVAS TORRES ,  Dario GIORDANO ,  Guido GHISOLFI ,  Marco BERNARDI ,  Daniela TODARO ,  Irene BOZZANO ,  Tommaso CRIPPA

IPC: C08G63/183

CPC classification number: C08G63/183 ,  C08G63/16

Abstract: The present specification discloses a composition comprising a plurality of diols which is useful for the production of polyester bottles, wherein the diols are mainly obtained from the conversion of a ligno-cellulosic biomass feedstock stream. The composition comprises ethylene glycol and at least one diol selected from the group of diols having a formula of CH(OH)2, wherein n is the total number of carbons and is an integer in the range from 3 to 20, z is an integer in the range from 0 to 2n, and C1 and C2 are each attached to one of the OH groups of the formula (e.g. 1,2-Propylene glycol, 1,2-Butanediol and 1,2-Pentanediol) and wherein the composition is substantially free of diols which absorb light at a wavelength of 275 nm, so that the percent light transmission of the composition at a wavelength of 275 nm is greater than 40%.

Abstract translation: 本说明书公开了一种组合物，其包含可用于生产聚酯瓶的多个二醇，其中二醇主要由木质纤维素生物质原料流的转化获得。 组合物包含乙二醇和选自具有式CH（OH）2的二醇的至少一种二醇，其中n是碳的总数，并且是3-20的整数，z是整数 在0至2n的范围内，并且C1和C2各自连接到下式的OH基之一（例如1,2-丙二醇，1,2-丁二醇和1,2-戊二醇），其中组合物为 基本上不含吸收波长275nm的光的二醇，使得组合物在275nm波长处的透光百分比大于40％。

公开(公告)号：US20160368842A1

公开(公告)日：2016-12-22

申请号：US15120756

申请日：2015-02-13

Applicant: BIOCHEMTEX S.P.A.

Inventor： Marco BERNARDI ,  Irene BOZZANO ,  Daniela TODARO

IPC: C07C29/132 ,  C07C29/60

CPC classification number: C07C29/132 ,  C07C29/60 ,  C07C31/205 ,  C07C31/202

Abstract: It is disclosed a continuous process for producing a polyols stream comprising ethylene glycol and propylene glycol, wherein a liquid sugar stream comprising water and at least a monomeric sugar is introduced into a first reaction zone and subjected to a first reaction, which is a hydrogenation reaction of the at least a monomeric sugar, at a first catalytic conditions and in the presence of a first hydrogen gas to produce an hydrogenated mixture comprising at least a sugar alcohol. At least a portion of the hydrogenated mixture and at least a portion of the first hydrogen gas are then transferred to a second reaction zone and subjected to a second reaction, which is a hydrogenolysis reaction of the at least a sugar alcohol, at second catalytic conditions to produce a hydrogenolysis mixture comprising at least a polyol. The second reaction occurs in the presence of a second hydrogen gas, wherein the second hydrogen gas comprises the portion of the first hydrogen gas which has been transferred to the second reaction. The first reaction is conducted at a first reaction pressure which is greater than or equal to the second reaction pressure, and the hydrogen gas is then released at the end of the conversion process of the second reaction zone at a discharge pressure which is less than the pressure of the first reaction. In this way, the transferring of at least a portion of the hydrogenated mixture and at least a portion of the first hydrogen gas from the first reaction zone to the second reaction zone may be done without the use of any pumping system, specifically of a pumping system which is capable of pumping a pressurized liquid/gas mixture.

Abstract translation: 公开了一种用于生产包含乙二醇和丙二醇的多元醇流的连续方法，其中将包含水和至少单体糖的液态糖料流引入第一反应区并进行第一反应，其为氢化反应 的至少一种单体糖，在第一催化条件下和在第一氢气存在下，产生至少包含糖醇的氢化混合物。 然后将至少一部分氢化混合物和至少一部分第一氢气转移到第二反应区，并在第二催化条件下进行第二反应，其是至少糖醇的氢解反应 以产生至少包含多元醇的氢解混合物。 第二反应在第二氢气存在下进行，其中第二氢气包括已转移到第二反应的第一氢气的部分。 第一反应在大于或等于第二反应压力的第一反应压力下进行，然后在第二反应区的转化过程结束时，在小于第二反应压力的排出压力下释放氢气 第一反应的压力。 以这种方式，可以在不使用任何泵送系统（特别是泵送）的情况下将至少一部分氢化混合物和至少一部分第一氢气从第一反应区转移到第二反应区 系统，其能够泵送加压的液体/气体混合物。

公开(公告)号：US20160362353A1

公开(公告)日：2016-12-15

申请号：US15121085

申请日：2015-02-13

Applicant: BIOCHEMTEX S.P.A

Inventor： Marco BERNARDI ,  Patrizia FERRANDO ,  Srinivasan RAGHAVENDRAN ,  Andrea BONANNI ,  Alessandra FRATTINI ,  Dario GIORDANO

IPC: C07C29/132 ,  D21C3/02 ,  D21C3/04 ,  C07C29/60 ,  D21C3/10 ,  D21C3/12 ,  D21C3/14 ,  D21C11/00 ,  D21C3/06 ,  D21C3/08

CPC classification number: C07C29/132 ,  C07C29/60 ,  D21C3/02 ,  D21C3/04 ,  D21C3/06 ,  D21C3/08 ,  D21C3/10 ,  D21C3/12 ,  D21C3/14 ,  D21C11/00 ,  Y02P20/125 ,  C07C31/202 ,  C07C31/205

Abstract: It is disclosed an integrated process for producing at least a cellulosic pulp comprising cellulose in the form of fibers and a polyols stream from a ligno-cellulosic feedstock comprising cellulose, hemicellulose and lignin. The process comprises the steps of:a) Treating the ligno-cellulosic feedstock to produce the cellulosic pulp and at least a liquid sugar stream comprising water and monomeric sugars derived from the hemicellulose of the ligno-cellulosic feedstock;b) Catalytically converting the monomeric sugars of the liquid sugar stream to a polyols mixture, comprising primary polyols and secondary polyols;c) Separating at least a portion of the polyols mixture into at least the polyols stream and a residual stream, wherein the polyols stream comprises the majority by weight of the primary polyols and the residual stream comprises the majority by weight of the secondary polyols;d) Recovering a first thermal energy from the residual stream in a first recovery unit.

Abstract translation: d）在第一回收单元中从残余流中回收第一热能。