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1.再颁专利Deactivating and removing aluminum and titanium contaminant from Ziegler-Natta polymerization mixtures 失效从齐格勒 - 纳塔聚合混合物中去除和去除铝和钛的污染物
公开(公告)号：USRE29004E
公开(公告)日：1976-10-12
申请号：US640248
申请日：1975-12-12
IPC分类号： C08F6/02
CPC分类号： C08F6/02
摘要： A polymerization reaction product comprising a solution of a poly(1-alkene) and a hydrocarbon polymerization solvent is purified of Ziegler-Natta aluminum and titanium containing catalyst residue by treating with flux-calcined diatomite to deactivate and insolubilize the aluminum and titanium and filtering out the insolubilized aluminum and titanium.
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公开(公告)号：US4181794A
公开(公告)日：1980-01-01
申请号：US937353
申请日：1978-08-28
申请人： Jin K. Kim , Clarence R. Murphy , Edward W. Smith
发明人： Jin K. Kim , Clarence R. Murphy , Edward W. Smith
摘要： A process for preparing olefin polymer fibrils is disclosed. A high molecular weight ethylene polymer is dissolved in methylene chloride in a first zone that is heated to develop a superatmospheric pressure. The polymer solution is fed to a second zone which is maintained at atmospheric pressure. The polymer solution is discharged into vigorously stirred isopropanol to form fibrils. Polymer solvent is distilled from the resulting slurry. The fibrils are refined in the isopropanol slurry. The polymer solvent and the isopropanol are recycled to the process.
摘要翻译： 公开了一种制备烯烃聚合物原纤维的方法。 将高分子量乙烯聚合物溶解在加热至超大气压的第一区中的二氯甲烷中。 将聚合物溶液进料至保持在大气压下的第二区域。 将聚合物溶液排入剧烈搅拌的异丙醇中以形成原纤维。 从所得浆液中蒸馏出聚合物溶剂。 原纤维在异丙醇浆液中精炼。 将聚合物溶剂和异丙醇再循环到该方法中。
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公开(公告)号：US4196305A
公开(公告)日：1980-04-01
申请号：US932727
申请日：1978-08-10
申请人： Clarence R. Murphy , S. Paul Thackaberry , Robert E. Boehme, deceased , by Helen J. Boehme, legal representative
发明人： Clarence R. Murphy , S. Paul Thackaberry , Robert E. Boehme, deceased , by Helen J. Boehme, legal representative
CPC分类号： C02F1/285
摘要： A process is disclosed for removing phenols from dilute aqueous solutions thereof. The method consists of contacting the aqueous phenol solution with a mass of olefin polymer fibrils which absorb the phenol from the aqueous solution. Water treated by the method does not give a characteristic phenol color when tested with ferric chloride.
摘要翻译： 公开了从其稀的水溶液中除去酚类的方法。 该方法包括使苯酚水溶液与从水溶液中吸收苯酚的大量烯烃聚合物原纤维接触。 当用氯化铁测试时，通过该方法处理的水不会产生特征酚颜色。
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公开(公告)号：US4320210A
公开(公告)日：1982-03-16
申请号：US215905
申请日：1980-12-12
申请人： Jin K. Kim , Clarence R. Murphy , Edward W. Smith
发明人： Jin K. Kim , Clarence R. Murphy , Edward W. Smith
摘要： Improved ethylene polymer fibrils are provided which are characterized in having:(a) a melt temperature of at least about 137.degree. C.,(b) a molecular weight of at least 250,000,(c) at least about 1.2 weight % of polyvinyl alcohol sorbed thereon, and(d) a zero-span breaking length of at least about 25,000.Water-laid sheets prepared from the fibrils have the following minimum factored values:Mullen Burst: 30 psiElmendorf Tear Strength: 300 grams/sheetTensile Strength: 15 lbs/inchElongation at Break: 40%
摘要翻译： 提供了改进的乙烯聚合物原纤维，其特征在于具有：（a）至少约137℃的熔融温度，（b）至少250,000的分子量，（c）至少约1.2重量％的聚乙烯醇 吸附在其上，（d）零跨度断裂长度至少约为25,000。 从原纤维制备的水性片材具有以下最小因子值：马伦爆裂：30 psi Elmendorf撕裂
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公开(公告)号：US4212848A
公开(公告)日：1980-07-15
申请号：US817325
申请日：1977-07-20
CPC分类号： B01F7/169 , B01F1/0011 , B01F1/0022 , B01F1/0033 , D01D1/02 , D01D5/40 , B01F2215/0049 , Y10S422/901
摘要： The invention is directed to an apparatus useful for dissolving high molecular weight olefin polymers in a hot hydrocarbon solvent. The apparatus includes:(a) A plurality of interconnected fluid chambers, each of which has a fluid inlet and a fluid outlet,(b) Screens covering the inlet and the outlet of each fluid chamber; the screen covering the outlet having a smaller mesh than the screen covering the inlet,(c) Stirring means in each fluid chamber adapted to sweep retained polymer particles free of the screen covering the outlet of said chamber,(d) Means for pumping fluid through the fluid chambers, and(e) Means for supplying heat to fluid passing through the apparatus.
摘要翻译： 本发明涉及一种用于将高分子量烯烃聚合物溶解在热烃溶剂中的装置。 该装置包括：（a）多个相互连接的流体室，每个流体室具有流体入口和流体出口，（b）覆盖每个流体室的入口和出口的筛网; 覆盖出口的筛网比覆盖入口的筛网小，（c）每个流体室中的搅拌装置，其适于扫掠覆盖所述室的出口的筛网的残留聚合物颗粒，（d）用于泵送流体的装置 流体室，和（e）用于向穿过设备的流体供应热量的装置。
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公开(公告)号：US4237081A
公开(公告)日：1980-12-02
申请号：US892799
申请日：1978-04-03
申请人： Clarence R. Murphy , Robert E. Boehme, deceased , by Helen J. Boehme, legal representative , by Joseph P. Phelp, executor
发明人： Clarence R. Murphy , Robert E. Boehme, deceased , by Helen J. Boehme, legal representative , by Joseph P. Phelp, executor
摘要： Apparatus useful in the manufacture of thermoplastic Olefin polymer fibrils are prepared by a process carried out in a disc mill. A hot olefin polymer solution is fed into the working cavity defined by the discs. In passing through the working cavity, the hot polymer solution is broken up into a plurality of uniaxially-oriented liquid streams which follow tortuous liquid paths through the working cavity whereby each of the streams is attenuated to orient the solute polymer molecules in said streams. A coolant liquid is fed into the working cavity and cools the attenuated polymer streams to a temperature sufficiently low so that substantially all of the solute polymer is precipitated in the form of uniaxially-oriented polymer fibrils. The product recovered from the modified disc mill consists of a mixture of uniaxially-oriented polymer fibrils, polymer solvent, and coolant liquid. The fibrils are recovered and refined in subsequent downstream operations.
摘要翻译： 用于制造热塑性烯烃聚合物原纤维的装置通过在圆盘磨机中进行的方法制备。 将热烯烃聚合物溶液进料到由盘限定的工作空腔中。 在通过工作空腔之后，热聚合物溶液被分解成多个单向取向的液体流，其沿着曲折的液体路径穿过工作空腔，由此每个流被减弱以使所述流中的溶质聚合物分子定向。 将冷却剂液体进料到工作空腔中并将减弱的聚合物流冷却到足够低的温度，使得基本上所有的溶质聚合物以单轴取向的聚合物原纤维的形式沉淀。 从改性盘磨机回收的产物由单轴取向聚合物原纤维，聚合物溶剂和冷却剂液体的混合物组成。 在随后的下游操作中回收和精制原纤维。
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公开(公告)号：US4274917A
公开(公告)日：1981-06-23
申请号：US16060
申请日：1979-02-28
申请人： Clarence R. Murphy , S. Paul Thackabeery , Robert E. Boehme, deceased , by Helen J. Boehme, sole beneficiary
发明人： Clarence R. Murphy , S. Paul Thackabeery , Robert E. Boehme, deceased , by Helen J. Boehme, sole beneficiary
摘要： Paper having improved properties, particularly tear strength, is prepared from a furnish containing at least 90 weight % of cellulose fibers and up to 10 weight % of olefin polymer fibrils. The fibrils are prepared by a differential temperature process of the type described in U.S. Pat. No. 4,013,751, are refined in isopropanol, and are treated with an aqueous solution of polyvinyl alcohol to sorb at least 1.0 weight % of polyvinyl alcohol on the fibrils. The fibrils are prepared from an olefin polymer having a weight average molecular weight of at least one (1) million.
摘要翻译： 具有改善性能，特别是撕裂强度的纸由含有至少90重量％的纤维素纤维和至多10重量％的烯烃聚合物原纤的配料制备。 原纤维通过美国专利No. 在异丙醇中精炼，并用聚乙烯醇水溶液处理以吸附原纤上至少1.0重量％的聚乙烯醇。 原纤维由重均分子量为至少一（1）百万的烯烃聚合物制备。
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公开(公告)号：US4197062A
公开(公告)日：1980-04-08
申请号：US924124
申请日：1978-07-13
CPC分类号： D01D5/40
摘要： Centrifugal spinning apparatus is provided for the manufacture of fibrils from hot viscous hydrocarbon solutions of olefin polymers having an intrinsic viscosity of at least 3.5. The apparatus consists of an impeller which rotates at high speed in a cylindrical cavity having a discharge port. The impeller has a plurality of blades whose narrow dimensions lie substantially in the plane of the impeller's rotation and whose tips come in close proximity to the inner peripheral surface of the cylindrical cavity. The blades are arranged in at least two substantially-identical sets. Within each set, the blades are offset substantially equidistant from one another, both in the rotational plane of the impeller and in the plane transverse thereto. Two inlet ports are provided in the peripheral surface of the cylindrical cavity to feed liquids to the cylindrical cavity, each of which port is narrow in a plane transverse to the plane of the impeller's rotation and extends over substantially the entire peripheral surface. The inlet ports are positioned near the discharge port of the cylindrical cavity and upstream thereof viewed with respect to the impeller's rotation, so that the bulk of the liquids entering the cavity from the inlet ports are swept away from the discharge port by the impeller's rotation.
摘要翻译： 离心纺丝设备用于从特性粘度至少为3.5的烯烃聚合物的热粘性烃溶液制造原纤维。 该装置由在具有排出口的圆柱形空腔中高速旋转的叶轮组成。 叶轮具有多个叶片，其狭窄尺寸基本上位于叶轮转动的平面中，并且其尖端紧邻圆柱形腔的内周表面。 叶片布置在至少两个基本相同的组中。 在每组中，叶片在叶轮的旋转平面中和横向于其的平面中彼此基本等距离地偏移。 两个入口端口设置在圆柱形空腔的圆周表面中，以将液体供应到圆柱形腔体，每个孔口在与叶轮旋转平面相交的平面中窄，并在基本上整个圆周表面上延伸。 入口端口位于圆柱形腔的排出口附近并且相对于叶轮旋转的上游位置，使得通过叶轮的旋转，从入口进入空腔的大部分液体被排出排出口。
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公开(公告)号：US4125584A
公开(公告)日：1978-11-14
申请号：US812031
申请日：1977-07-01
CPC分类号： D01D5/40 , Y10S264/47
摘要： Centrifugal spinning apparatus is provided for the manufacture of fibrils from hot viscous hydrocarbon solutions of olefin polymers having an intrinsic viscosity of at least 3.5. The apparatus consists of an impeller which rotates at high speed in a cylindrical cavity having a discharge port. The impeller has a plurality of blades whose narrow dimensions lie substantially in the plane of the impeller's rotation and whose tips come in close proximity to the inner peripheral surface of the cylindrical cavity. The blades are arranged in at least two substantially-identical sets. Within each set, the blades are offset substantially equidistant from one another, both in the rotational plane of the impeller and in the plane transverse thereto. Two inlet ports are provided in the peripheral surface of the cylindrical cavity to feed liquids to the cylindrical cavity, each of which port is narrow in a plane transverse to the plane of the impeller's rotation and extends over substantially the entire peripheral surface. The inlet ports are positioned near the discharge port of the cylindrical cavity and upstream thereof viewed with respect to the impeller's rotation, so that the bulk of the liquids entering the cavity from the inlet ports are swept away from the discharge port by the impeller's rotation.
摘要翻译： {PG，1离心纺丝设备用于从特性粘度至少为3.5的烯烃聚合物的热粘性烃溶液制造原纤维。 该装置由在具有排出口的圆柱形空腔中高速旋转的叶轮组成。 叶轮具有多个叶片，其狭窄尺寸基本上位于叶轮的平面（3s旋转中，并且其尖端靠近圆柱形腔的内周表面）。 叶片布置在至少两个基本相同的组中。 在每组中，叶片在叶轮的旋转平面中和横向于其的平面中彼此基本等距离地偏移。 两个入口端口设置在圆柱形空腔的圆周表面中，以将液体供给到圆柱形腔体，每个孔口在垂直于叶轮平面的平面（3s旋转中并且在基本上整个圆周表面上延伸）的窄边。 入口端口位于圆柱形腔的排出口附近，并且相对于叶轮（3s的旋转）观察其上游，使得从入口端口进入空腔的大部分液体从排出口被扫除 叶轮{3 s旋转。
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