公开(公告)号：US09403754B2

公开(公告)日：2016-08-02

申请号：US14614013

申请日：2015-02-04

Applicant: Bayer MaterialScience AG

Inventor： Thomas E. Müller ,  Christoph Gürtler ,  Reinhard Halpaap ,  Christoph Thiebes ,  Ewa Gebauer-Henke ,  Isabel U. Castro Cevallos ,  Walter Leitner

IPC: C07C209/72 ,  B01J23/46

CPC classification number: C07C209/72 ,  B01J23/464 ,  C07C2601/14 ,  Y02P20/582 ,  C07C211/36

Abstract: A catalytic process for hydrogenating aromatic di- and polyamines with the aid of a selected catalyst system is provided, which comprises a mixture of a first heterogeneous catalyst and a second heterogeneous catalyst and a nitro compound (nitrate and/or nitrite salt). The first and second heterogeneous catalyst each independently comprise a metal selected from the group consisting of Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and/or Pt and the metal selected for the second heterogeneous catalyst is different from the metal selected for the first heterogeneous catalyst. Hydrogenation of aromatic rings having two or more amino groups bound to the aromatic ring produces cycloaliphatic di- and polyamines, which are useful chemical intermediates, e.g., for further reaction with epoxides or isocyanates. The amino groups may also be converted to isocyanates via reaction with phosgene. The resulting cycloaliphatic di- and polyisocyanates may also be used as monomers for making polymers.

Abstract translation: 提供了借助于选择的催化剂体系来氢化芳族二胺和多胺的催化方法，其包括第一非均相催化剂和第二非均相催化剂和硝基化合物（硝酸盐和/或亚硝酸盐）的混合物。 第一和第二非均相催化剂各自独立地包含选自Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd和/或Pt中的金属，并且所选择的金属 对于第二种非均相催化剂，不同于为第一种非均相催化剂选择的金属。 具有与芳环结合的两个或多个氨基的芳环的氢化产生脂环族二胺和多胺，它们是有用的化学中间体，例如用于与环氧化物或异氰酸酯的进一步反应。 氨基也可以通过与光气反应转化为异氰酸酯。 所得到的脂环族二异氰酸酯和多异氰酸酯也可以用作制备聚合物的单体。

公开(公告)号：US20150291726A1

公开(公告)日：2015-10-15

申请号：US14441279

申请日：2013-11-11

Applicant: BAYER MATERIALSCIENCE AG

Inventor： Thomas Ernst Mueller ,  Christoph Guertler ,  Susmit Basu ,  Walter Leitner

IPC: C08G18/75 ,  C08G18/71 ,  C08G18/32 ,  C08G18/22

CPC classification number: C08G18/758 ,  C08G18/003 ,  C08G18/222 ,  C08G18/225 ,  C08G18/227 ,  C08G18/3218 ,  C08G18/71 ,  C08G59/02 ,  C08G59/26 ,  C08G59/4028 ,  C08J3/09 ,  C08J2400/14 ,  C08L63/00

Abstract: The present invention relates to a method for the production of oxazolidinone compounds, comprising the step of slowly reacting an isocyanate compound with an epoxide compound in the presence of a Lewis acid catalyst. The invention further relates to an oxazolidinone compound, obtainable by a method according to the invention, with a colour as determined according to ASTM D1209-05 (2011) of ≦200 and a molar ratio of the oxazolidinone compound to isocyanurate by-product o/i of ≧85/15. Lastly, the invention relates to an oligomeric or polymeric oxazolidinone compound, obtainable by a method according to the invention using an isocyanate compound with two or more NCO groups per molecule and an epoxide compound with two or more epoxy groups per molecule, comprising at least two units derived from the isocyanate compound and at least two units derived from the epoxide compound, with a colour as determined according to ASTM D1209-05 (2011) of ≦200.

Abstract translation: 本发明涉及一种制备恶唑烷酮化合物的方法，包括在路易斯酸催化剂存在下使异氰酸酯化合物与环氧化合物缓慢反应的步骤。 本发明还涉及通过根据本发明的方法获得的具有根据ASTM D1209-05（2011）＆lt; NY; 200测定的颜色的恶唑烷酮化合物和恶唑烷酮化合物与异氰脲酸酯副产物o的摩尔比 /≧85/15。 最后，本发明涉及通过本发明的方法获得的低分子或聚合恶唑烷酮化合物，其使用每分子具有两个或多个NCO基团的异氰酸酯化合物和每分子具有两个或更多个环氧基团的环氧化合物，其包含至少两个 衍生自异氰酸酯化合物的单元和至少两种衍生自环氧化合物的单元，其颜色根据ASTM D1209-05（2011）＆lt; nEE200确定。

公开(公告)号：US09458281B2

公开(公告)日：2016-10-04

申请号：US14441279

申请日：2013-11-11

Applicant: Bayer MaterialScience AG

Inventor： Thomas Ernst Mueller ,  Christoph Guertler ,  Susmit Basu ,  Walter Leitner

IPC: C08G18/00 ,  C08G18/75 ,  C08G59/40 ,  C08G18/22 ,  C08G18/32 ,  C08G18/71 ,  C08G59/02 ,  C08J3/09 ,  C08L63/00

CPC classification number: C08G18/758 ,  C08G18/003 ,  C08G18/222 ,  C08G18/225 ,  C08G18/227 ,  C08G18/3218 ,  C08G18/71 ,  C08G59/02 ,  C08G59/26 ,  C08G59/4028 ,  C08J3/09 ,  C08J2400/14 ,  C08L63/00

Abstract: The present invention relates to a method for the production of oxazolidinone compounds, comprising the step of slowly reacting an isocyanate compound with an epoxide compound in the presence of a Lewis acid catalyst. The invention further relates to an oxazolidinone compound, obtainable by a method according to the invention, with a color as determined according to ASTM D1209-05 (2011) of ≦200 and a molar ratio of the oxazolidinone compound to isocyanurate by-product o/i of ≧85/15. Lastly, the invention relates to an oligomeric or polymeric oxazolidinone compound, obtainable by a method according to the invention using an isocyanate compound with two or more NCO groups per molecule and an epoxide compound with two or more epoxy groups per molecule, comprising at least two units derived from the isocyanate compound and at least two units derived from the epoxide compound, with a color as determined according to ASTM D1209-05 (2011) of ≦200.

Abstract translation: 本发明涉及一种制备恶唑烷酮化合物的方法，包括在路易斯酸催化剂存在下使异氰酸酯化合物与环氧化合物缓慢反应的步骤。 本发明还涉及通过根据本发明的方法获得的恶唑烷酮化合物，其颜色根据ASTM D1209-05（2011）确定为≤200，并且恶唑烷酮化合物与异氰脲酸酯副产物的摩尔比o / 我的≧85/15。 最后，本发明涉及通过本发明的方法获得的低分子或聚合恶唑烷酮化合物，其使用每分子具有两个或多个NCO基团的异氰酸酯化合物和每分子具有两个或更多个环氧基团的环氧化合物，其包含至少两个 衍生自异氰酸酯化合物的单元和至少两种衍生自环氧化合物的单元，其颜色根据ASTM D1209-05（2011）确定为≤200。

公开(公告)号：US09273183B2

公开(公告)日：2016-03-01

申请号：US14424171

申请日：2013-08-23

Applicant: Bayer MaterialScience AG

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Walter Leitner ,  Ilja Peckermann ,  Aurel Wolf

IPC: C08G64/30 ,  C08G65/26 ,  C08G64/34 ,  C08G18/48

CPC classification number: C08G64/305 ,  C08G18/4833 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2606 ,  C08G65/2663

Abstract: The invention relates to a method for producing polyether carbonate polyols by attaching alkylene oxides and carbon dioxide to one or more H-functional starters in the presence of a double-metal cyanide catalyst, characterized in that (alpha) a suspending agent which contains no H-functional groups and is selected from among one or more compounds from the group consisting of aliphatic lactones, aromatic lactones, lactides, cyclic carbonates comprising at least three optionally substituted methylene groups between the oxygen atoms of the carbonate group, aliphatic cyclic anhydrides, and aromatic cyclic anhydrides, is provided in a reactor; (ss) optionally, a moiety of alkylene oxide is added to the mixture from step (alpha) at temperatures of 90 to 150 DEG C., and the addition of the alkylene oxide compound is then interrupted; and (gamma) one or more H-functional starters are continuously metered into the reactor during the reaction.

Abstract translation: 本发明涉及一种通过在双金属氰化物催化剂存在下将环氧烷和二氧化碳连接到一个或多个H官能起始剂上制备聚醚碳酸酯多元醇的方法，其特征在于（α）不含H的悬浮剂 选自脂肪族内酯，芳族内酯，丙交酯，碳酸酯基的氧原子，脂肪族环状酸酐和芳香族中的至少3个以上的任意取代的亚甲基的环状碳酸酯的一种以上的化合物 环状酸酐，设置在反应器中; （β）任选地，在90至150℃的温度下，将来自步骤（α）的环氧烷的部分加入，然后中断环氧烷化合物的加入; 和（γ）一个或多个H功能起动器在反应期间连续地计量到反应器中。

公开(公告)号：US20150225503A1

公开(公告)日：2015-08-13

申请号：US14424171

申请日：2013-08-23

Applicant: Bayer MaterialScience AG

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Walter Leitner ,  Ilja Peckermann ,  Aurel Wolf

IPC: C08G64/30

CPC classification number: C08G64/305 ,  C08G18/4833 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2606 ,  C08G65/2663

Abstract: The invention relates to a method for producing polyether carbonate polyols by attaching alkylene oxides and carbon dioxide to one or more H-functional starters in the presence of a double-metal cyanide catalyst, characterized in that (alpha) a suspending agent which contains no H-functional groups and is selected from among one or more compounds from the group consisting of aliphatic lactones, aromatic lactones, lactides, cyclic carbonates comprising at least three optionally substituted methylene groups between the oxygen atoms of the carbonate group, aliphatic cyclic anhydrides, and aromatic cyclic anhydrides, is provided in a reactor; (ss) optionally, a moiety of alkylene oxide is added to the mixture from step (alpha) at temperatures of 90 to 150 DEG C, and the addition of the alkylene oxide compound is then interrupted; and (gamma) one or more H-functional starters are continuously metered into the reactor during the reaction.

Abstract translation: 本发明涉及一种通过在双金属氰化物催化剂存在下将环氧烷和二氧化碳连接到一个或多个H官能起始剂上制备聚醚碳酸酯多元醇的方法，其特征在于（α）不含H的悬浮剂 选自脂肪族内酯，芳族内酯，丙交酯，碳酸酯基的氧原子，脂肪族环状酸酐和芳香族中的至少3个以上的任意取代的亚甲基的环状碳酸酯的一种以上的化合物 环状酸酐，设置在反应器中; （β）任选地，在90至150℃的温度下，将来自步骤（α）的环氧烷的一部分加入到混合物中，然后中断环氧烷化合物的加入; 和（γ）一个或多个H功能起动器在反应期间连续地计量到反应器中。

公开(公告)号：US09278906B2

公开(公告)日：2016-03-08

申请号：US14614183

申请日：2015-02-04

Applicant: Bayer MaterialScience AG

Inventor： Thomas E. Müller ,  Christoph Gürtler ,  Reinhard Halpaap ,  Ewa Gebauer-Henke ,  Walter Leitner ,  Patrick Tomkins ,  Christoph Thiebes

IPC: C07C209/72

CPC classification number: C07C209/72 ,  C07C2601/14 ,  Y02P20/582 ,  C07C211/35

Abstract: A process for hydrogenating aromatic di- and polyamines is provided comprising the steps of reacting the aromatic amine with hydrogen in the presence of a catalytic system, wherein the catalytic system comprises a heterogeneous catalyst comprising a metal selected from the group consisting of Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and/or Pt and a support, and wherein the catalyst system further comprises an organic nitro compound. Hydrogenation of aromatic di- and polyamines having two or more amino groups bound to the aromatic ring produces cycloaliphatic di- and polyamines, which are useful chemical intermediates, e.g., for further reaction with epoxides or isocyanates. The amino groups may also be converted to isocyanates via reaction with phosgene. The resulting cycloaliphatic di- and polyisocyanates may also be used as monomers for making polymers.

Abstract translation: 提供了一种用于氢化芳族二胺和多胺的方法，其包括在催化体系存在下使芳族胺与氢反应的步骤，其中催化体系包含非均相催化剂，其包含选自Cr，Mo， W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd和/或Pt和载体，并且其中催化剂体系还包含有机硝基化合物。 具有与芳环结合的两个或多个氨基的芳族二胺和多胺的氢化产生脂环族二胺和多胺，它们是有用的化学中间体，例如用于与环氧化物或异氰酸酯进一步反应。 氨基也可以通过与光气反应转化为异氰酸酯。 所得到的脂环族二异氰酸酯和多异氰酸酯也可以用作制备聚合物的单体。