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    Formable film
    3.
    发明授权
    Formable film 有权

    公开(公告)号：US10066122B2

    公开(公告)日：2018-09-04

    申请号：US14698422

    申请日：2015-04-28

    Applicant: Benecke-Kaliko AG ,  Bayer MaterialScience AG

    Inventor： Dirk Iben ,  Heino Koch ,  Stefan Reusch ,  Heinz Dietmar Gewiss ,  Martin Melchiors ,  Uwe Klippert ,  Marc Claudius Schrinner

    IPC: C09D175/06 ,  C09D175/04 ,  C08G18/08 ,  C08G18/66 ,  C08J7/04 ,  C08G18/78 ,  C08G18/79

    Abstract: A deformable film has a decorative surface featuring a completely matt appearance. For this purpose, the deformable film has a decorative surface provided with at least one coating comprising the following constituents: (a) an aqueous dispersion of a hydroxy-functional prepolymer, obtainable by conversion of at least one of the following components: (i) a component having hydroxyl groups, (ii) a polyester polyol having hydroxyl groups, (iii) a polyisocyanate having isocyanate groups, (iv) a compound having at least two groups reactive toward isocyanate groups and at least one group capable of anion formation, (v) water, where components (i) to (iii) and the ratio of components (i) to (iii) are selected such that an excess of hydroxyl groups is present relative to the isocyanate groups, and (b) nanoparticles having a number-average particle size of 1 to 1000 nm and (c) a crosslinker having at least two groups reactive toward hydroxyl groups.

    Method for treating a substance mixture comprising an aromatic amine, in particular a substance mixture of raw aniline
    6.
    发明授权
    Method for treating a substance mixture comprising an aromatic amine, in particular a substance mixture of raw aniline 有权

    公开(公告)号：US09682917B2

    公开(公告)日：2017-06-20

    申请号：US14397914

    申请日：2013-04-29

    Applicant: Bayer MaterialScience AG

    Inventor： Michael Merkel ,  Thomas Knauf ,  Cliff Andre Peters ,  Thorsten Schmidt

    IPC: C07C209/84

    CPC classification number: C07C209/84 ,  C07C211/46 ,  C07C211/50

    Abstract: The present invention relates to a method for treating a substance mixture comprising an aromatic amine, wherein the aromatic amine is aniline or 2,4-diaminotoluene, preferably aniline. The substance mixture comprises an aromatic amine and compounds having a higher boiling point than the aromatic amine. The method for treating the substance mixture requires I) separating the first substance mixture by means of distillation in a first distillation unit (110, 1130), to at least partially remove some of the aromatic amine in the process, and to obtain a first bottom product which is removed from the first distillation unit (110, 1130). After removal from the first distillation unit (110, 1130), the bottom product is diluted with a condensed top product from a distillation unit that is different from the first distillation unit and/or with a composition that comprises methanol.

    Aqueous blocked polyurethane-urea dispersion
    9.
    发明授权
    Aqueous blocked polyurethane-urea dispersion 有权
    水性封闭聚氨酯 - 尿素分散体

    公开(公告)号：US09404020B2

    公开(公告)日：2016-08-02

    申请号：US14400680

    申请日：2013-05-22

    Applicant: Bayer MaterialScience AG

    Inventor： Hans-Georg Grablowitz ,  Thomas Feller ,  Thomas Michaelis ,  Tanja Hebestreit ,  Ingo Gipperich

    IPC: C08G18/00 ,  C09D175/04 ,  C09D175/12 ,  C08G18/80 ,  C08G18/08 ,  C08G18/32

    CPC classification number: C09D175/12 ,  C08G18/0823 ,  C08G18/3262 ,  C08G18/8083 ,  C09D175/04

    Abstract: The present invention relates to an aqueous blocked polyurethaneurea dispersion which is obtainable by reacting at least one polyisocyanate, one blocking agent for isocyanate groups, one polyamine having at least one carboxyl and/or carboxylate group, and water. Additionally provided by the invention are a coating composition comprising the aqueous blocked polyurethaneurea dispersion, the use of the aqueous blocked polyurethaneurea dispersion or of the coating composition for producing a coating, a coating obtainable using the aqueous blocked polyurethaneurea dispersion or the coating composition, and a method for producing the aqueous blocked polyurethaneurea dispersion.

    Abstract translation: 本发明涉及一种水性封闭的聚氨酯脲分散体，其通过使至少一种多异氰酸酯，一种异氰酸酯基团封闭剂，一个具有至少一个羧基和/或羧酸酯基团的多胺与水反应而获得。 本发明另外提供了一种涂料组合物，其包含水性封端聚氨酯脲分散体，使用水性封端聚氨酯脲分散体或用于制备涂料的涂料组合物，使用水分封闭的聚氨酯脲分散体或涂料组合物可获得的涂料，以及 水性封端聚氨酯脲分散液的制造方法。

    Process for hydrogenating aromatic di- and polyamines
    10.
    发明授权
    Process for hydrogenating aromatic di- and polyamines 有权
    氢化芳族二胺和多胺的方法

    公开(公告)号：US09403754B2

    公开(公告)日：2016-08-02

    申请号：US14614013

    申请日：2015-02-04

    Applicant: Bayer MaterialScience AG

    Inventor： Thomas E. Müller ,  Christoph Gürtler ,  Reinhard Halpaap ,  Christoph Thiebes ,  Ewa Gebauer-Henke ,  Isabel U. Castro Cevallos ,  Walter Leitner

    IPC: C07C209/72 ,  B01J23/46

    CPC classification number: C07C209/72 ,  B01J23/464 ,  C07C2601/14 ,  Y02P20/582 ,  C07C211/36

    Abstract: A catalytic process for hydrogenating aromatic di- and polyamines with the aid of a selected catalyst system is provided, which comprises a mixture of a first heterogeneous catalyst and a second heterogeneous catalyst and a nitro compound (nitrate and/or nitrite salt). The first and second heterogeneous catalyst each independently comprise a metal selected from the group consisting of Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and/or Pt and the metal selected for the second heterogeneous catalyst is different from the metal selected for the first heterogeneous catalyst. Hydrogenation of aromatic rings having two or more amino groups bound to the aromatic ring produces cycloaliphatic di- and polyamines, which are useful chemical intermediates, e.g., for further reaction with epoxides or isocyanates. The amino groups may also be converted to isocyanates via reaction with phosgene. The resulting cycloaliphatic di- and polyisocyanates may also be used as monomers for making polymers.

    Abstract translation: 提供了借助于选择的催化剂体系来氢化芳族二胺和多胺的催化方法，其包括第一非均相催化剂和第二非均相催化剂和硝基化合物（硝酸盐和/或亚硝酸盐）的混合物。 第一和第二非均相催化剂各自独立地包含选自Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd和/或Pt中的金属，并且所选择的金属 对于第二种非均相催化剂，不同于为第一种非均相催化剂选择的金属。 具有与芳环结合的两个或多个氨基的芳环的氢化产生脂环族二胺和多胺，它们是有用的化学中间体，例如用于与环氧化物或异氰酸酯的进一步反应。 氨基也可以通过与光气反应转化为异氰酸酯。 所得到的脂环族二异氰酸酯和多异氰酸酯也可以用作制备聚合物的单体。

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