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公开(公告)号:US5543280A
公开(公告)日:1996-08-06
申请号:US557734
申请日:1995-11-13
申请人: Beate Weber , J org Hagemann , G unter Helling , Markus Geiger
发明人: Beate Weber , J org Hagemann , G unter Helling , Markus Geiger
CPC分类号: G03C7/396 , C07C69/54 , C07C69/96 , G03C7/39216 , G03C7/3022 , G03C7/30535
摘要: A color photographic material which contains in at least one blue sensitive layer containing a yellow coupler a compound of the formula (I) ##STR1## in which R.sub.1 means --(X).sub.m --R.sub.4,m means 0 or 1,X means --CO--, --CO--NR.sub.5 -- or --CO--O--,R.sub.4 means H, alkyl, aryl or alkenyl,R.sub.2 means H or alkyl,R.sub.3 means H or alkyl,R.sub.5 means H, alkyl, cycloalkyl or aryl,n means 1 to 20, providing that m is 1 in at least 10% of the R.sub.1 groups, is distinguished by improved color stability.
摘要翻译: 在含有黄色成色剂的至少一个蓝色感光层中含有式(I)化合物的彩色感光材料表示-CO-,-CO-NR5-或-CO-O-,R4表示H, 烷基,芳基或烯基,R 2表示H或烷基,R 3表示H或烷基,R 5表示H,烷基,环烷基或芳基,n表示1至20,条件是在至少10%的R 1基团中m为1, 区别在于颜色稳定性的提高。
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公开(公告)号:US5731138A
公开(公告)日:1998-03-24
申请号:US592692
申请日:1996-01-26
申请人: Gunter Helling , Beate Weber , Markus Geiger
发明人: Gunter Helling , Beate Weber , Markus Geiger
IPC分类号: G03C7/00 , G03C7/30 , G03C7/38 , G03C7/388 , G03C7/392 , G03C7/396 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号: G03C7/39296 , G03C7/3008 , G03C7/3825 , G03C7/3882 , G03C7/396
摘要: A color photographic material which contains in at least one layer a stabilizer of the formula (I) ##STR1## in which R.sub.1 means H, alkyl, aryl or acyl; R.sub.2 means --OR.sub.1, --COOH, alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl or sulphonyl; R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another mean H, halogen or a residue as R.sub.2 or two adjacent residues --OR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 may together complete a 5- to 8-membered ring, and a polymer insoluble in water as pH 5 and soluble at pH 11 with an acid value of 30 to 300 and a Tg of.ltoreq.40.degree. C. of the formula (II) ##STR2## in which R.sub.7 mutually independently mean hydrogen, C.sub.1 -C.sub.4 alkyl or CH.sub.2 --COOH, R.sub.8 means alkyl, aryl or aralkyl a means 80 to 95 mol. % and b means 5 to 20 mol. %, is distinguished by improved stability of the image dyes.
摘要翻译: 一种彩色照相材料,其在至少一层中含有式(I)r酰基的稳定剂; R2表示-OR1,-COOH,烷基,芳基,二烷基氨基,酰氨基,磺酰氨基,酰基或磺酰基; R 3,R 4,R 5和R 6彼此独立地表示H,卤素或作为R 2或两个相邻残基-OR 1,R 2,R 3,R 4,R 5和R 6的残基可以一起完成5-至8-元环, 不溶于水的聚合物,其pH值为5,在pH值为11,酸值为30至300,Tg为40℃,式(Ⅱ)其中R7相互独立地表示氢 ,C 1 -C 4烷基或CH 2 -COOH,R 8表示烷基,芳基或芳烷基,是指80至95摩尔。 %和b表示5〜20mol。 %,通过改善图像染料的稳定性来区分。
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公开(公告)号:US5508157A
公开(公告)日:1996-04-16
申请号:US453665
申请日:1995-05-30
申请人: Beate Weber , Markus Geiger , Gunter Helling , Jorg Hagemann
发明人: Beate Weber , Markus Geiger , Gunter Helling , Jorg Hagemann
CPC分类号: G03C7/3885 , G03C7/3008 , G03C7/39208 , G03C7/39236
摘要: A color photographic silver halide material in which at least one coupler is dissolved or dispersed in a coupler solvent corresponding to the following formula: ##STR1## in which R.sub.1 is alkyl, alkenyl, cycloalkyl or cycloalkenyl,R.sub.2 and R.sub.3 are alkylene or alkenylene,X is CO, NHCO or SO.sub.2,n is 0 or 1 andl, m are numbers of 1 to 5,is distinguished by steep gradation and improved maximum density.
摘要翻译: 一种彩色照相卤化银材料,其中至少一种成色剂溶解或分散在对应于下式的成色剂溶剂中:其中R 1是烷基,烯基,环烷基或环烯基,R 2和R 3是亚烷基或 亚烯基,X是CO,NHCO或SO2,n是0或1,l,m是1到5的数,以陡峭的等级和改进的最大密度来区分。
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公开(公告)号:US5441861A
公开(公告)日:1995-08-15
申请号:US112192
申请日:1993-08-26
申请人: Beate Weber , Gunter Helling , Klaus Walz , Markus Geiger , Kaspar Wingender , Jorg Hagemann
发明人: Beate Weber , Gunter Helling , Klaus Walz , Markus Geiger , Kaspar Wingender , Jorg Hagemann
CPC分类号: G03C7/3882 , G03C7/39216
摘要: A color photographic material with at least one silver halide emulsion layer which contains a color coupler distributed in a polymeric oil former and at least one compound of the formula (I) ##STR1## in which R means alkyl, cycloalkyl, alkenyl, aryl, acyl, alkylsulphonyl or arylsulphonyl,R.sub.1 means a chemical bond or a divalent bridging member,R.sub.2 and R.sub.3 mean alkyl, alkoxy, alkenyl, cycloalkyl, aryl or aryloxy or two residues R.sub.2 or R.sub.3 the remaining atoms of a benzene ring condensed with the phenyl residue andm and n mean 0 to 3, wherein all alkyl, alkoxy, cycloalkyl, alkenyl, aryl, aryloxy and acyl residues may be further substituted,is characterized by improved color stability.
摘要翻译: 一种具有至少一个卤化银乳剂层的彩色照相材料,其含有分布在聚合物油形成剂中的至少一种式(I)化合物(I),其中R表示烷基,环烷基,链烯基, 芳基,酰基,烷基磺酰基或芳基磺酰基,R1表示化学键或二价桥连构件,R2和R3表示烷基,烷氧基,烯基,环烷基,芳基或芳氧基或两个残基R2或R3,苯环的剩余原子与 苯基残基,m和n表示0至3,其中所有烷基,烷氧基,环烷基,烯基,芳基,芳氧基和酰基残基可以进一步被取代,其特征在于改进的颜色稳定性。
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公开(公告)号:US06890707B2
公开(公告)日:2005-05-10
申请号:US10612809
申请日:2003-07-02
申请人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号: G03C5/08 , G03C1/035 , G03C1/09 , G03C5/04 , G03C7/00 , G03C7/30 , G03C7/34 , G03C7/392 , G03C1/08 , G03C7/25 , G03C7/32
CPC分类号: G03C7/346 , G03C1/09 , G03C5/04 , G03C7/30 , G03C7/3022 , G03C7/39204 , G03C2001/03517 , G03C2001/093 , G03C2200/19
摘要: A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, contain 20 to 500 nmol of iridium per mol of silver halide and the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished in that it is equally ideally suitable for analogue and scanning exposure and exhibits very good latent image stability.
摘要翻译: 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 含有至少一种黄色成色剂的层,其特征在于,红色敏感层的卤化银晶体的氯化物含量为至少95摩尔%,每摩尔卤化银含有20-500nmol的铱,青色成色剂为 其中R 1表示氢原子或烷基的式R 2是指烷基,芳基或杂芳基,R 3表示 烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,亚磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基 基团或氢原子,Z表示氢原子或取代基 在显色发展的条件下,其特征在于它同样理想地适用于模拟和扫描曝光,并且表现出非常好的潜像稳定性。
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公开(公告)号:US06783924B2
公开(公告)日:2004-08-31
申请号:US10612560
申请日:2003-07-02
申请人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号: G03C108
CPC分类号: G03C1/18 , G03C1/127 , G03C5/04 , G03C7/30 , G03C7/3006 , G03C7/346 , G03C7/3926 , G03C7/39276 , G03C2200/19
摘要: A color photographic silver halide material comprising a substrate, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, the cyan coupler corresponding to formula wherein R1 represents a hydrogen atom or an alkyl group, R2 represents an alkyl, aryl or hetaryl group R3 represents an alkyl or aryl group, R4 represents an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulphonyloxy, sulphamoylamino, sulphonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z represents a hydrogen atom or a group which may be split off under the conditions of chromogenic development and the red-sensitive layer contains at least one compound of formula wherein R5 represents H, CH3 or OCH3, R6 represents H, OH, CH3, OCH3, NHCO—R7, COOR7, SO2NH2, NHCONH2 or NHCONH—CH3 and R7 represents C1 to C4 alkyl, is distinguished by very good stability in storage simultaneously with very good latent image stability.
摘要翻译: 一种彩色照相卤化银材料,其包含基材,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红色成色剂的至少一种感绿卤化银乳剂层和至少一种蓝色敏感性 含有至少一种黄色成色剂的卤化银乳剂层,其特征在于,所述红色感光层的卤化银晶体的氯化物含量为至少95摩尔%,对应于其中的青色成色剂R 1表示氢原子或 烷基,R 2表示烷基,芳基或杂芳基R 3表示烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰氨基,脲基 ,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基或氢原子,Z表示氢原子或可以在条件o f显色发育和红敏层含有至少一种糠醛的化合物,R 5表示H,CH 3或OCH 3,R 6表示H,OH,CH 3,OCH 3,NHCO-R 7,COOR 7, SO 2 NH 2,NHCONH 2或NHCONH-CH 3和R 7表示C 1至C 4烷基,其特征在于非常好的保存稳定性,同时具有非常好的潜像稳定性。
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公开(公告)号:US5441855A
公开(公告)日:1995-08-15
申请号:US257165
申请日:1994-06-09
申请人: Beate Weber , Jorg Hagemann , Gunter Helling , Markus Geiger
发明人: Beate Weber , Jorg Hagemann , Gunter Helling , Markus Geiger
CPC分类号: G03C7/39216 , C07C39/17 , C08G61/02 , G03C7/396 , G03C2001/03517 , G03C2200/07 , G03C2200/11 , G03C7/3013 , G03C7/36
摘要: A color photographic material which contains in at least one blue-sensitive layer a yellow coupler and a compound of the formula (I) ##STR1## in which R.sub.1 means hydrogen or alkyl,R.sub.2 means hydrogen or alkyl,R.sub.3 means hydrogen or alkyl,1 means 1 to 20X ##STR2## or cycloalkene, R.sub.4 means hydrogen or alkyl,R.sub.5 means hydrogen or alkyl andn means 1 to 6,shows improved light-stability of the yellow dye obtained from said yellow coupler by exposure and processing.
摘要翻译: 在至少一个蓝色敏感层中含有黄色成色剂和式(I)化合物的彩色照相材料,其中R 1表示氢或烷基,R 2表示氢或烷基,R 3表示氢或 烷基,1表示1至20个X或环烯烃,R 4表示氢或烷基,R 5表示氢或烷基,n表示1至6,通过曝光和加工显示由所述黄色成色剂获得的黄色染料的改善的光稳定性 。
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公开(公告)号:US06806042B2
公开(公告)日:2004-10-19
申请号:US10612132
申请日:2003-07-02
申请人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号: G03C108
CPC分类号: G03C7/346 , G03C5/04 , G03C7/30 , G03C7/3022 , G03C7/3882 , G03C7/3885 , G03C2001/03517 , G03C2200/19
摘要: A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the red-sensitive layer contains at least one oil former, the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, and the ratio by weight of oil former to cyan coupler is less than 1:1, is distinguished by excellent colour reproduction.
摘要翻译: 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 该层包含至少一个黄色成色剂,其特征在于该红色敏感层含有至少一种成油剂,青色成色剂是式(1)表示氢原子或烷基,R 2表示烷基 ,芳基或杂芳基,R 3表示烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,亚磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基, ,芳硫基,烷基氨基或芳基氨基或氢原子,Z表示氢原子或在显色条件下可消除的基团,成油剂与青色成色剂的重量比小于1:1,由ex 细胞色彩再现。
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公开(公告)号:US5441862A
公开(公告)日:1995-08-15
申请号:US329886
申请日:1994-10-27
申请人: Beate Weber , Gunter Helling , Markus Geiger
发明人: Beate Weber , Gunter Helling , Markus Geiger
CPC分类号: G03C7/3885
摘要: A color photographic recording material with at least one silver halide emulsion layer and a color coupler associated with that layer, which contains in the silver halide emulsion layer or in an adjacent non-photosensitive binder layer a combination of a color coupler and a compound corresponding to general formula (I) or (II): ##STR1## in which R.sub.4 is the residue of a polymer produced by polycondensation andR.sub.1 to R.sub.3, m and n are as defined in the specification, ##STR2## in which R.sub.4 is as defined above and L.sub.1, L.sub.2, X, R.sub.5 to R.sub.11, p, q and r are as defined in the specification,is distinguished by improved stability of the image dyes produced from yellow couplers.
摘要翻译: 一种彩色照相记录材料,其具有至少一个卤化银乳剂层和与该层相关联的着色剂,其在卤化银乳剂层中或在相邻的非感光性粘合剂层中包含颜色成色剂和对应于 通式(I)或(II):其中R 4是通过缩聚反应制备的聚合物的残基,并且R 1至R 3,m和n如说明书中所定义, 其中R4如上所定义,L1,L2,X,R5至R11,p,q和r如说明书中所定义,其特征在于由黄色成色剂产生的图像染料的改进的稳定性。
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公开(公告)号:US6096492A
公开(公告)日:2000-08-01
申请号:US185774
申请日:1998-11-04
申请人: Beate Weber , Markus Geiger , Jorg Hagemann
发明人: Beate Weber , Markus Geiger , Jorg Hagemann
CPC分类号: G03C7/396 , G03C7/39208 , G03C7/3825
摘要: A colour photographic material which contains an OH-functional polylactone in at least one layer is distinguished by improved maximum densities.
摘要翻译: 在至少一层中含有OH-官能聚内酯的彩色照相材料的特征在于改进的最大密度。
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