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公开(公告)号：US5965480A
公开(公告)日：1999-10-12
申请号：US35005
申请日：1998-03-05
IPC分类号： B01J27/138 , B01J23/66 , B01J27/10 , B01J27/232 , C07B61/00 , C07D301/10 , C07D303/04 , B01J23/48 , B01J23/50
CPC分类号： C07D301/10 , B01J23/66 , B01J27/10 , B01J27/232
摘要： Direct oxidation of propylene to propylene oxide is accomplished using alkaline earth metal compound-supported silver catalysts containing an inorganic chloride promoter and a potassium promoter derived from a potassium salt containing a nitrogen oxyanion or precursor thereof.
摘要翻译： 丙烯到环氧丙烷的直接氧化是使用含有无机氯催化剂的碱土金属化合物负载的银催化剂和源自含有氮氧阴离子或其前体的钾盐的钾促进剂来实现的。
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公开(公告)号：US5780657A
公开(公告)日：1998-07-14
申请号：US880905
申请日：1997-06-23
IPC分类号： B01J27/138 , B01J23/66 , B01J27/10 , B01J27/232 , C07B61/00 , C07D301/10 , C07D303/04
CPC分类号： C07D301/10 , B01J23/66 , B01J27/10 , B01J27/232
摘要： Direct oxidation of propylene to propylene oxide is accomplished using alkaline earth metal compound-supported silver catalysts containing an inorganic chloride promoter and a potassium promoter derived from a potassium salt containing a nitrogen oxyanion or precursor thereof.
摘要翻译： 丙烯到环氧丙烷的直接氧化是使用含有无机氯催化剂的碱土金属化合物负载的银催化剂和源自含有氮氧阴离子或其前体的钾盐的钾促进剂来实现的。
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公开(公告)号：US06960671B2
公开(公告)日：2005-11-01
申请号：US10251405
申请日：2002-09-20
IPC分类号： B01J29/89 , B01J35/02 , C01B37/00 , C07D301/12 , C07D301/10 , C07D301/06 , C07D301/08
CPC分类号： B01J29/89 , B01J35/023 , C01B37/005 , C07D301/12
摘要： Large crystals of titanium silicalite or intergrowths of intergrown smaller crystals, having a mean particle size greater than 2 μm, have been found catalytically effective at commercially reasonable rates for the epoxidation of olefins in the presence of hydrogen peroxide. Crystals synthesized with a silica source having a low sodium content exhibit high levels of production and selectivity. The crystals have a low attrition rate and are easily filterable from a product stream.
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4.发明授权Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein 失效将丙烯直接氧化成环氧丙烷和大粒径钛硅沸石催化剂用于其中的方法公开(公告)号：US07399726B2
公开(公告)日：2008-07-15
申请号：US11087776
申请日：2005-03-23
IPC分类号： B01J29/06 , B01J29/89 , B01J29/068
CPC分类号： B01J29/89 , B01J35/023 , C01B37/005 , C07D301/12
摘要： Large crystals of titanium silicalite or intergrowths of intergrown smaller crystals, having a mean particle size greater than 2 μm, have been found catalytically effective at commercially reasonable rates for the epoxidation of olefins in the presence of hydrogen peroxide. Crystals synthesized with a silica source having a low sodium content exhibit high levels of production and selectivity. The crystals have a low attrition rate and are easily filterable from a product stream.
摘要翻译： 已经发现，在双氧水存在下，以商业上合理的速率对烯烃的环氧化催化有效的大晶体的钛硅沸石或共生的较小结晶的共生长的平均粒径大于2μm。 用具有低钠含量的二氧化硅源合成的晶体表现出高水平的生产和选择性。 该晶体具有低的磨耗率，并且易于从产品流中过滤。
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公开(公告)号：US06281369B1
公开(公告)日：2001-08-28
申请号：US09731565
申请日：2000-12-07
IPC分类号： C07D30106
CPC分类号： C07D301/06 , C07D301/08
摘要： The stability of a noble metal/titanium zeolite catalyst is improved by elevated temperature calcination with an oxygen containing gas; the catalyst is useful in epoxidation involving the reaction of olefin, oxygen and hydrogen.
摘要翻译： 贵金属/钛沸石催化剂的稳定性通过用含氧气体进行高温煅烧而提高; 该催化剂可用于涉及烯烃，氧和氢的反应的环氧化。
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公开(公告)号：US06555493B2
公开(公告)日：2003-04-29
申请号：US09873715
申请日：2001-06-04
IPC分类号： B01J2100
CPC分类号： C07D301/06 , C07D301/08
摘要： The stability of a noble metal/titanium zeolite catalyst is improved by elevated temperature calcination with an oxygen containing gas; the catalyst is useful in epoxidation involving the reaction of olefin, oxygen and hydrogen.
摘要翻译： 贵金属/钛沸石催化剂的稳定性通过用含氧气体进行高温煅烧而提高; 该催化剂可用于涉及烯烃，氧和氢的反应的环氧化。
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7.发明授权Epoxidation process using supported silver catalysts treated with carbon dioxide 失效使用用二氧化碳处理的负载银催化剂的环氧化方法
公开(公告)号：US5856534A
公开(公告)日：1999-01-05
申请号：US993466
申请日：1997-12-18
IPC分类号： B01J23/68 , C07B61/00 , C07D301/10 , C07D303/04
CPC分类号： C07D301/10
摘要： The catalytic performance of a supported silver catalyst in a propylene epoxidation process is improved by first contacting the catalyst at an elevated temperature with a treatment stream comprised of carbon dioxide. The carbon dioxide-treated catalyst is thereafter contacted with a feedstream containing propylene, molecular oxygen, but essentially no carbon dioxide under conditions effective to form propylene oxide.
摘要翻译： 通过首先使催化剂在升高的温度下与由二氧化碳组成的处理流接触来改善负载的银催化剂在丙烯环氧化方法中的催化性能。 然后，二氧化碳处理的催化剂在有效形成环氧丙烷的条件下与含有丙烯，分子氧，但基本上不含二氧化碳的进料流接触。
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8.发明授权Epoxidation process using supported silver catalysts pretreated with organic chloride 失效用有机氯化物预处理的负载银催化剂的环氧化方法
公开(公告)号：US5770746A
公开(公告)日：1998-06-23
申请号：US880896
申请日：1997-06-23
IPC分类号： B01J27/132 , C07D301/10
CPC分类号： C07D301/10
摘要： A propylene epoxidation process wherein a supported silver catalyst is utilized may be operated at high efficiency even in the absence of any organic chloride in the feedstream, provided the catalyst is first contacted at an elevated temperature with a treatment stream comprised of an organic chloride and molecular oxygen.
摘要翻译： 使用负载的银催化剂的丙烯环氧化方法即使在进料流中不存在任何有机氯化物也可以以高效率运行，条件是催化剂首先在升高的温度下与含有机氯化物和分子 氧。
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公开(公告)号：US07182932B2
公开(公告)日：2007-02-27
申请号：US10769359
申请日：2004-01-30
申请人： Wilson H. Onimus , Bernard Cooker , Edrick Morales
发明人： Wilson H. Onimus , Bernard Cooker , Edrick Morales
IPC分类号： B01J29/89 , C07D301/04 , C07D301/12
CPC分类号： C07D301/06 , B01J29/405 , B01J29/44 , B01J37/0045 , B01J37/0203 , B01J37/18 , C07D301/12 , Y02P20/52
摘要： A TS-1 catalyst suitable for the production of oxirane compounds is prepared by subjecting conventionally formed TS-1 to a size reduction treatment such as milling such that the average particle size weighted by volume of the TS-1 is reduced to less than 10 microns in diameter and the size reduced TS-1 is spray dried.
摘要翻译： 通过对常规形成的TS-1进行诸如研磨之类的尺寸减小处理使得将TS-1的体积加权的平均粒径减小到小于10微米的方法制备适用于生产环氧乙烷化合物的TS-1催化剂 直径和尺寸减小TS-1被喷雾干燥。
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公开(公告)号：US06972337B1
公开(公告)日：2005-12-06
申请号：US10918605
申请日：2004-08-12
申请人： Wilson H. Onimus , Bernard Cooker
发明人： Wilson H. Onimus , Bernard Cooker
IPC分类号： B01J29/44 , B01J29/48 , B01J29/89 , C07D301/06 , C07D301/12
CPC分类号： B01J29/48 , B01J29/44 , B01J29/89 , B01J2229/186 , B01J2229/30 , B01J2229/40 , C07D301/12
摘要： Titanium or vanadium zeolites are heated at a temperature greater than 400° C., then contacted with water prior to use in olefin epoxidation with hydrogen peroxide.
摘要翻译： 钛或钒沸石在大于400℃的温度下加热，然后在用过氧化氢进行烯烃环氧化之前与水接触。
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