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公开(公告)号：US06964728B2
公开(公告)日：2005-11-15
申请号：US10147621
申请日：2002-05-16
CPC分类号： B01D3/34 , Y10S203/11 , Y10S203/14
摘要： Bisphenol-A-bis(neopentylglycolphosphate) products of enhanced properties and processes for preparing them are described. One of the processes includes (a) mixing and reacting neopentyl glycol and bisphenol-A-bis(dichlorophosphate) in an inert polar organic solvent which (1) if mixed by itself with an equal volume of water at 25° C., will form a separate phase, (2) the solvent by itself will dissolve at least about 10 wt % of bisphenol-A-bis(neopentylglycolphosphate) at a temperature in the range of 25 to 50° C., and optionally but preferably (3) the solvent by itself can be completely vaporized at a temperature below about 180° C.; (b) washing bisphenol-A-bis(neopentylglycolphosphate) product formed in a) while dissolved in inert organic solvent having such characteristics at least once with an aqueous alkaline washing solution; and (c) optionally but preferably, recovering bisphenol-A-bis(neopentylglycolphosphate) product from organic solvent having such characteristics. The reaction of (a) can be conducted in an inert non-polar solvent if that solvent is replaced by an inert polar organic solvent satisfying (1) and (2), and preferably (3). A solvent satisfying (1), (2), and (3) is used when (c) is conducted by distilling or vaporizing off the solvent to recover the bisphenol-A-bis(neopentylglycolphosphate) product as such. The product has a low acid number or a high thermal stability, and usually both.
摘要翻译： 描述了增强性能的双酚A双（新戊二醇磷酸酯）产物及其制备方法。 其中一个方法包括（a）在惰性极性有机溶剂中将新戊二醇和双酚-A-双（二氯磷酸盐）混合和反应，（1）如果在25℃下与等体积的水自身混合，将形成 单独的相，（2）溶剂本身将在25至50℃的温度范围内溶解至少约10重量％的双酚A-双（新戊基乙二醇酯磷酸酯），并且任选但优选（3） 溶剂本身可以在低于约180℃的温度下完全蒸发; （b）洗涤a）中形成的双酚-A-双（新戊基乙二醇磷酸酯）产物，同时用碱性洗涤液溶解至少一次具有这种特性的惰性有机溶剂; 和（c）任选地但优选地，从具有这种特性的有机溶剂中回收双酚A-双（新戊基乙二醇磷酸酯）产物。 （a）的反应可以在惰性非极性溶剂中进行，如果该溶剂被满足（1）和（2），优选（3）的惰性极性有机溶剂代替。 （c）通过蒸馏除去溶剂进行蒸发以回收双酚A-双（新戊基乙二醇酯磷酸酯）产物时，使用满足（1），（2）和（3）的溶剂。 该产品具有低酸值或高热稳定性，通常两者都是。
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公开(公告)号：US20080318829A1
公开(公告)日：2008-12-25
申请号：US11911792
申请日：2006-04-13
IPC分类号： C11D10/02 , C07C17/00 , C07C17/383
CPC分类号： C07C17/156 , C07C17/38 , C07C17/383 , C07C19/075 , C07C19/045
摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.
摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。
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公开(公告)号：US06620441B1
公开(公告)日：2003-09-16
申请号：US09894598
申请日：2001-06-28
IPC分类号： A01N5900
CPC分类号： A61L2/18 , A01N59/00 , C02F1/76 , Y10S514/97 , Y10S514/973 , A01N59/02 , A01N25/22 , A01N2300/00
摘要： In producing aqueous microbiocidal solutions by oxidation of a water-soluble alkali metal bromide, an intolerable loss of active halogen species has been found to occur during a 10-day period immediately after the product solution has been formed. Surprisingly, this loss has been found to result from an alcohol impurity in the alkali metal bromide used in the process. By eliminating or at least sharply reducing the amount of alcohol impurity in the reaction mixture, products are formed which do not undergo the intolerable loss of active halogen content during the 10-day period.
摘要翻译： 在通过水溶性碱金属溴化物的氧化生产含水的杀微生物剂溶液中，已经发现在形成产物溶液后的10天期间，不能容忍的活性卤素物质的损失发生。 令人惊奇的是，这种损失已被发现是由于该方法中使用的碱金属溴化物中的醇杂质引起的。 通过消除或至少急剧减少反应混合物中的醇杂质的量，形成在10天期间不会发生不能容忍的活性卤素含量损失的产物。
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公开(公告)号：US08193398B2
公开(公告)日：2012-06-05
申请号：US11911792
申请日：2006-04-13
CPC分类号： C07C17/156 , C07C17/38 , C07C17/383 , C07C19/075 , C07C19/045
摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.
摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。
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公开(公告)号：US5773672A
公开(公告)日：1998-06-30
申请号：US867144
申请日：1997-06-20
CPC分类号： C07C17/08
摘要： 1-Bromopropane is produced from hydrogen bromide, propene and a catalytically effective amount of an ozonide catalyst and/or one or more active catalytic species formed in situ therefrom. In addition to being highly efficient and highly suitable for use on an industrial scale, the process has the additional advantages of being environmentally friendly, operationally safe, and conservationally beneficial.
摘要翻译： 1-溴丙烷由溴化氢，丙烯和催化有效量的臭氧化物催化剂和/或由其原位形成的一种或多种活性催化物质制备。 除了高效率，高度适用于工业规模以外，该工艺还具有环保，操作安全，保护性好等优点。
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