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    Processes for production and purification of normal propyl bromide
    1.
    发明授权
    Processes for production and purification of normal propyl bromide 有权
    生产和纯化正丙基溴的方法

    公开(公告)号：US08193398B2

    公开(公告)日：2012-06-05

    申请号：US11911792

    申请日：2006-04-13

    申请人： William B. Harrod ,  Bonnie G. McKinnie ,  Alireza M. Dadgar ,  Tyson J. Hall

    发明人： William B. Harrod ,  Bonnie G. McKinnie ,  Alireza M. Dadgar ,  Tyson J. Hall

    IPC分类号： C07C17/00 ,  C11D17/00

    CPC分类号： C07C17/156 ,  C07C17/38 ,  C07C17/383 ,  C07C19/075 ,  C07C19/045

    摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.

    摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。

    Processes For Production and Purification of Normal Propyl Bromide
    2.
    发明申请
    Processes For Production and Purification of Normal Propyl Bromide 有权
    正丙酰溴的生产和纯化方法

    公开(公告)号：US20080318829A1

    公开(公告)日：2008-12-25

    申请号：US11911792

    申请日：2006-04-13

    申请人： William B. Harrod ,  Bonnie G. McKinnie ,  Alireza M. Dadgar ,  Tyson J. Hall

    发明人： William B. Harrod ,  Bonnie G. McKinnie ,  Alireza M. Dadgar ,  Tyson J. Hall

    IPC分类号： C11D10/02 ,  C07C17/00 ,  C07C17/383

    CPC分类号： C07C17/156 ,  C07C17/38 ,  C07C17/383 ,  C07C19/075 ,  C07C19/045

    摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.

    摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。

    Production of 1-bromopropane
    3.
    发明授权
    Production of 1-bromopropane 失效
    生产1-溴丙烷

    公开(公告)号：US5773672A

    公开(公告)日：1998-06-30

    申请号：US867144

    申请日：1997-06-20

    申请人： William B. Harrod ,  Alireza M. Dadgar ,  Phillip R. Beaver

    发明人： William B. Harrod ,  Alireza M. Dadgar ,  Phillip R. Beaver

    IPC分类号： C07C17/08 ,  C07C17/00

    CPC分类号： C07C17/08

    摘要： 1-Bromopropane is produced from hydrogen bromide, propene and a catalytically effective amount of an ozonide catalyst and/or one or more active catalytic species formed in situ therefrom. In addition to being highly efficient and highly suitable for use on an industrial scale, the process has the additional advantages of being environmentally friendly, operationally safe, and conservationally beneficial.

    摘要翻译： 1-溴丙烷由溴化氢，丙烯和催化有效量的臭氧化物催化剂和/或由其原位形成的一种或多种活性催化物质制备。 除了高效率，高度适用于工业规模以外，该工艺还具有环保，操作安全，保护性好等优点。

    Removal of Bromine From Gaseous Hydrogen Bromide
    5.
    发明申请
    Removal of Bromine From Gaseous Hydrogen Bromide 审中-公开
    从气态溴化氢中除去溴

    公开(公告)号：US20130287675A1

    公开(公告)日：2013-10-31

    申请号：US13997964

    申请日：2011-12-28

    申请人： William B. Harrod ,  John M. Harden ,  Gary L. Sharp ,  Robert E. Williams

    发明人： William B. Harrod ,  John M. Harden ,  Gary L. Sharp ,  Robert E. Williams

    IPC分类号： C01B7/09

    CPC分类号： C01B7/093 ,  B01D53/68 ,  B01D2257/2022 ,  C07C17/12 ,  C07C25/02 ,  C07C25/18

    摘要： A new, highly selective way of removing bromine contamination from a gaseous stream comprised of hydrogen bromide and bromine is described. Such process technology involves non-catalyzed free radical (benzylic) bromination of an alkylene-bridged aromatic hydrocarbon and/or certain alkyl-substituted aromatic hydrocarbons and recovering the purified gaseous HBr. Because of the high selectivity of the bromination on the aliphatic bridges or side-chains, virtually no ring bromination occurs, and this enables recovery of the bromine values in the form of HBr. Thus preferably, the bromine is recovered as HBr from the scrubbing liquid by subjecting the scrubbing liquid to thermal or catalytic dehyrobromination. In plant operations, the gaseous HBr purified in the process can then be introduced into a compressor to produce either liquid or gaseous HBr for storage under pressure. Alternatively, the purified gaseous HBr can be fed directly into one or more reactions in which HBr is used as a reactant.

    摘要翻译： 描述了从由溴化氢和溴组成的气流中除去溴污染物的新的高度选择性的方法。 这种方法技术涉及亚烷基桥连芳烃和/或某些烷基取代芳烃的非催化自由基（苄基）溴化，并回收纯化的气态HBr。 由于溴化对脂族桥或侧链的高选择性，实际上不发生环溴化，因此能够以HBr的形式回收溴值。 因此，优选地，通过对洗涤液进行热或催化脱氢化，从洗涤液中将溴作为HBr回收。 在工厂操作中，在该过程中纯化的气态HBr然后可以被引入压缩机以产生液体或气体HBr以在压力下储存。 或者，纯化的气态HBr可以直接进料到一个或多个反应中，其中使用HBr作为反应物。

    Purification of arylene polyphosphate esters
    8.
    发明授权
    Purification of arylene polyphosphate esters 失效
    亚磷酸多聚磷酸酯的纯化

    公开(公告)号：US06399685B1

    公开(公告)日：2002-06-04

    申请号：US09734053

    申请日：2000-12-11

    申请人： W. Dirk Klobucar ,  William B. Harrod ,  Billie B. Dadgar ,  Joseph D. McLean ,  Gary D. Heidebrecht ,  Hao V. Phan ,  Thomas R. Nicholas ,  Jeffrey L. Broeker

    发明人： W. Dirk Klobucar ,  William B. Harrod ,  Billie B. Dadgar ,  Joseph D. McLean ,  Gary D. Heidebrecht ,  Hao V. Phan ,  Thomas R. Nicholas ,  Jeffrey L. Broeker

    IPC分类号： C08K552

    CPC分类号： C07F9/025 ,  C07F9/12

    摘要： Emulsion formation is minimized or prevented and hydrolytic product degradation is suppressed during purification of impure bisphenol-A bis(diphenylphosphate). This is accomplished by forming a hydrocarbon solution of bisphenol-A bis(diphenylphosphate) plus impurities in a solvent comprising at least one aromatic hydrocarbon and at least one paraffinic hydrocarbon. Optionally, but preferably, this solution is washed with water or an aqueous buffer solution. Next, the hydrocarbon solution is washed one or more times with an aqueous alkaline washing solution that has a specific gravity that differs from the specific gravity of the hydrocarbon solution by at least about 0.05 gram per cubic centimeter. After each washing the mixture settles into a purified organic phase and a separate aqueous phase, and these phases are separated from each other. After completing the one or more alkaline washings and separations, the resultant purified organic phase is washed one or more times with water to remove alkaline components from the hydrocarbon solution, and after each such washing the washed mixture is settled into a less alkaline purified organic phase and a separate aqueous phase. These phases are separated, and preferably the purified product is recovered from the organic phase.

    摘要翻译： 在纯化双酚A双（二苯基磷酸酯）的纯化期间，乳液形成被最小化或防止并且抑制了水解产物降解。 这通过在包含至少一种芳族烃和至少一种链烷烃的溶剂中形成双酚-A双（二苯基磷酸酯）加杂质的烃溶液来实现。 任选地，但优选地，该溶液用水或缓冲液水溶液洗涤。 接下来，将烃溶液用比表面积与烃溶液的比重不同的碱性水溶液洗涤一次或多次至少约0.05克/立方厘米。 每次洗涤后，混合物沉降到纯化的有机相和单独的水相中，并且这些相彼此分离。 在完成一次或多次碱性洗涤和分离之后，将所得纯化的有机相用水洗涤一次或多次以从烃溶液中除去碱性组分，并且在每次这样洗涤后，将洗涤的混合物沉降到较不碱性的纯化的有机相 和单独的水相。 分离这些相，优选从有机相中回收纯化的产物。

    Bisphenol-A bis(diphenyl phosphate)-based flame retardant
    10.
    发明授权
    Bisphenol-A bis(diphenyl phosphate)-based flame retardant 失效
    双酚A双（二苯基磷酸酯）系阻燃剂

    公开(公告)号：US06319432B1

    公开(公告)日：2001-11-20

    申请号：US09330688

    申请日：1999-06-11

    申请人： William B. Harrod ,  W. Dirk Klobucar

    发明人： William B. Harrod ,  W. Dirk Klobucar

    IPC分类号： C09K2112

    CPC分类号： C08K5/523 ,  C07F9/12

    摘要： Disclosed is a flame retardant comprising bisphenol A bis(diphenyl phosphate) and its dimer, the former having an HPLC determined 78 to 87 area % and an 85 to less than 90 normalized area %, the normalized area % being based on the total HPLC area % of the bisphenol A bis(diphenyl phosphate) and the dimer. The flame retardant also has a low isopropenylphenyl diphenyl phosphate and a low triphenylphosphate content.

    摘要翻译： 公开了一种包含双酚A双（磷酸二苯酯）及其二聚物的阻燃剂，前者具有HPLC测定为78至87面积％和85至小于90标准化面积％，归一化面积％基于总HPLC面积 ％的双酚A双（磷酸二苯酯）和二聚体。 阻燃剂也具有低的异丙烯基苯基二苯基磷酸酯和低的三苯基磷酸盐含量。