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公开(公告)号：US08193398B2
公开(公告)日：2012-06-05
申请号：US11911792
申请日：2006-04-13
CPC分类号： C07C17/156 , C07C17/38 , C07C17/383 , C07C19/075 , C07C19/045
摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.
摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。
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公开(公告)号：US08133467B2
公开(公告)日：2012-03-13
申请号：US12523785
申请日：2008-02-05
摘要： Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an aqueous HBr rich stream and, optionally, a feed brine dilute in CaCI2. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, and, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution.
摘要翻译： 提供了用于从富含HBr水溶液和任选的在CaCl 2中稀释的进料盐水中共同生产Br2和含有至少约5重量％CaCl 2的浓缩水溶液（基于浓缩水溶液的重量）的方法。 这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用Cl 2氧化塔内的溴化物部分以产生Br 2，从塔中回收Br 2，从塔中除去溴化物贫化的塔底物， HCl，向溴化物贫乏的塔底物中加入Ca ++源，以将塔底中的基本上所有的HCl转化为CaCl 2，并根据需要从经处理的塔底产物中除去水以产生浓缩的水溶液。
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公开(公告)号：US20100015034A1
公开(公告)日：2010-01-21
申请号：US12523959
申请日：2008-02-13
IPC分类号： C01B7/09
CPC分类号： C01B7/096 , B01J21/066 , B01J27/08
摘要： Processes are provided for catalytic oxidation of bromide to bromine by use of oxygen at temperatures of at least about 315° C. in the presence of a cerium-containing compound, such as a cerium bromide catalyst, wherein the produced stream comprising Br2 and H2O is directly cooled with water. The bromide and the oxygen may be heated directly with steam.
摘要翻译： 在含铈化合物如溴化铈催化剂存在下，通过使用氧气至少约315℃的温度将溴化物催化氧化成溴的方法，其中包含Br 2和H 2 O的产物流是 用水直接冷却。 溴和氧可以用蒸汽直接加热。
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4.发明申请METHODS FOR CONVERSION OF METHANE TO USEFUL HYDROCARBONS AND CATALYSTS FOR USE THEREIN 审中-公开将甲烷转化为有用的烃类和催化剂用于其的方法公开(公告)号：US20090247804A1
公开(公告)日：2009-10-01
申请号：US12442226
申请日：2007-09-14
CPC分类号： B01J31/143 , B01J27/125 , B01J27/135 , B01J31/121 , B01J2231/46 , C10G50/00
摘要： Methods are provided for converting methane to useful hydrocarbons. In the methods provided, a fluid comprising methane and hydrogen is combined with a catalyst composition derived from at least an aluminum compound, such as an aluminum halide, an aluminum alkyl, or a aluminum hydrate, and a second component such as a transition metal halide, a transition metal hydride, or a zero-valent metal, to produce heavier hydrocarbons.
摘要翻译： 提供了将甲烷转化成有用的烃的方法。 在所提供的方法中，将包含甲烷和氢气的流体与衍生自至少铝化合物如卤化铝，烷基铝或水合铝的催化剂组合物和第二组分如过渡金属卤化物 ，过渡金属氢化物或零价金属，以生产较重的烃。
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5.发明授权公开(公告)号：US08133468B2
公开(公告)日：2012-03-13
申请号：US12594877
申请日：2008-02-05
摘要： Processes are provided for conjointly producing Br2, a concentrated aqueous solution containing CaCI2, and Cl2 from an aqueous HBr-rich stream and a feed brine dilute in CaCI2 that comprises NaCI. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 from a Cl2 source, at least a portion of which is produced according to this invention, to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution, producing Cl2 and caustics from residual chlorides such as NaCI, and using at least a portion of the thus produced Cl2 in the Cl2 source.
摘要翻译： 提供了从富含HBr水溶液的水中共同生成Br2，含有CaCl 2和Cl 2的浓缩水溶液和在包含NaCl的CaCl 2中稀释的进料盐水的方法。 这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用来自Cl 2源的Cl 2氧化塔内的溴化物部分，其至少一部分根据本发明生产以产生Br2，回收 Br2，从塔中除去溴化物贫乏的塔底物，这样的含有HCl的塔底物，向溴化物贫乏的塔底物中加入Ca ++源，根据需要将底部的基本上所有的HCl转化为CaCl 2，从而从 处理的底部产物以产生浓缩的水溶液，从残余氯化物如NaCl中产生Cl 2和苛性碱，并使用Cl2源中由此产生的Cl 2的至少一部分。
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6.发明申请METHODS FOR CONVERSION OF METHANE TO USEFUL HYDROCARBONS, CATALYSTS FOR USE THEREIN, AND REGENERATION OF THE CATALYSTS 审中-公开用于甲烷转化为有用的烃类的方法，其使用的催化剂和催化剂的再生公开(公告)号：US20100087308A1
公开(公告)日：2010-04-08
申请号：US12442223
申请日：2007-09-14
IPC分类号： B01J38/00
CPC分类号： B01J31/4015 , B01J27/32 , B01J31/121 , B01J31/143 , B01J31/4076 , B01J2231/46 , B01J2531/0216
摘要： Methods are provided for regenerating catalyst compositions useful in processes for converting methane to useful hydrocarbons. The methods comprise applying voltage across the catalyst compositions.
摘要翻译： 提供了用于再生用于将甲烷转化为有用的烃的方法中的催化剂组合物的方法。 所述方法包括在催化剂组合物上施加电压。
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公开(公告)号：US20100047155A1
公开(公告)日：2010-02-25
申请号：US12523785
申请日：2008-02-05
申请人： Joe D. Sauer , George W. Cook , Tyson J. Hall , George A. Newbill
发明人： Joe D. Sauer , George W. Cook , Tyson J. Hall , George A. Newbill
摘要： Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an aqueous HBr rich stream and, optionally, a feed brine dilute in CaCI2. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, and, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution.
摘要翻译： 提供了用于从富含HBr水溶液和任选的在CaCl 2中稀释的进料盐水中共同生产Br2和含有至少约5重量％CaCl 2的浓缩水溶液（基于浓缩水溶液的重量）的方法。 这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用Cl 2氧化塔内的溴化物部分以产生Br 2，从塔中回收Br 2，从塔中除去溴化物贫化的塔底物， HCl，向溴化物贫乏的塔底物中加入Ca ++源，以将塔底中的基本上所有的HCl转化为CaCl 2，并根据需要从经处理的塔底产物中除去水以产生浓缩的水溶液。
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公开(公告)号：US20100030005A1
公开(公告)日：2010-02-04
申请号：US12528241
申请日：2008-02-13
IPC分类号： C07C2/00
摘要： Processes for producing C2+ hydrocarbons are provided. Such processes use Br2, HBr, and/or heat that are produced by such processes, thus providing commercially efficient processes. The process can comprise (a) producing HBr and methyl bromide using a bromine source and a gas stream comprising methane; (b) heating the methyl bromide in the presence of a catalyst to produce additional HBr and C2+ hydrocarbons; (c) combining at least some of the HBr and an oxygen source in the presence of a cerium-containing compound at least about 315° C. to produce Br2; and (d) using at least some of the produced Br2 from (c) as at least a portion of the bromine source in (a). Additionally, the additional HBr from (b) can be used in (c) and/or heat can be recovered from (c) and used to provide at least some of the heating in (a), (b), or both.
摘要翻译： 提供了生产C2 +烃的方法。 这种方法使用通过这些方法生产的Br 2，HBr和/或热，从而提供商业上有效的方法。 该方法可以包括（a）使用溴源和包含甲烷的气流产生HBr和甲基溴; （b）在催化剂存在下加热甲基溴以产生额外的HBr和C2 +烃; （c）在至少约315℃的含铈化合物的存在下将至少一些HBr和氧源合并以产生Br 2; 和（d）使用来自（c）的所产生的Br 2中的至少一些作为（a）中的溴源的至少一部分。 另外，来自（b）的另外的HBr可以用于（c）中，和/或可以从（c）回收热量，并用于在（a），（b）或两者中提供至少一些加热。
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9.发明申请公开(公告)号：US20100143238A1
公开(公告)日：2010-06-10
申请号：US12594877
申请日：2008-02-05
申请人： Joe D. Sauer , George W. Cook , Tyson J. Hall , George A. Newbill
发明人： Joe D. Sauer , George W. Cook , Tyson J. Hall , George A. Newbill
摘要： Processes are provided for conjointly producing Br2, a concentrated aqueous solution containing CaCI2, and Cl2 from an aqueous HBr-rich stream and a feed brine dilute in CaCI2 that comprises NaCI. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 from a Cl2 source, at least a portion of which is produced according to this invention, to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution, producing Cl2 and caustics from residual chlorides such as NaCI, and using at least a portion of the thus produced Cl2 in the Cl2 source.
摘要翻译： 提供了从富含HBr水溶液的水中共同生成Br2，含有CaCl 2和Cl 2的浓缩水溶液和在包含NaCl的CaCl 2中稀释的进料盐水的方法。 这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用来自Cl 2源的Cl 2氧化塔内的溴化物部分，其至少一部分根据本发明生产以产生Br2，回收 Br2，从塔中除去溴化物贫乏的塔底物，这样的含有HCl的塔底物，向溴化物贫乏的塔底物中加入Ca ++源，根据需要将底部的基本上所有的HCl转化为CaCl 2，从而从 处理的底部产物以产生浓缩的水溶液，从残余氯化物如NaCl中产生Cl 2和苛性碱，并使用Cl2源中由此产生的Cl 2的至少一部分。
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公开(公告)号：US20080318829A1
公开(公告)日：2008-12-25
申请号：US11911792
申请日：2006-04-13
IPC分类号： C11D10/02 , C07C17/00 , C07C17/383
CPC分类号： C07C17/156 , C07C17/38 , C07C17/383 , C07C19/075 , C07C19/045
摘要： A process for oxygen-initiated hydrobromination of propene to form a crude reaction mixture of 95 GC area % n-propyl bromide. The process includes feeding an oxygen-containing gas, propene and hydrogen bromide into a liquid phase mixture comprised of n-propyl bromide and hydrogen bromide. At least the oxygen-containing gas and the propene of the feed are fed subsurface to the liquid phase mixture and either (a) the oxygen-containing gas and the propene do not come together in the absence of hydrogen bromide or (b) the oxygen-containing gas and the propene come together only in a propene:oxygen molar ratio in the range of 145:1 to 180:1. Purification processes provide a propyl bromide product containing at least 99.7 GC area % n-propyl bromide. Also provided is a novel composition of enhanced thermal stability which comprises a mixture of n-propyl bromide and isopropyl bromide. The mixture has an n-propyl bromide content of at least 99.7 GC area %, and an isopropyl bromide content of no more than 0.05 GC area %. The mixture, if subjected to storage in a closed chemically inert container at 60° C. for at least 480 hours, has an APHA color of 10 or less while the mixture is devoid of any added stabilizer component.
摘要翻译： 丙烯的氧引发氢溴化方法，形成95 GC面积％正丙基溴的粗反应混合物。 该方法包括将含氧气体，丙烯和溴化氢进料到由正丙基溴和溴化氢组成的液相混合物中。 至少将含氧气体和进料的丙烯进料到液相混合物的下面，并且（a）在不存在溴化氢的情况下，（a）含氧气体和丙烯不会聚在一起，或（b）氧气 的含有气体和丙烯仅在丙烯：氧摩尔比在145:1至180:1的范围内聚合在一起。 纯化方法提供含有至少99.7 GC面积％正丙基溴的丙基溴产物。 还提供了包含正丙基溴和异丙基溴的混合物的增强热稳定性的新型组合物。 该混合物的正丙基溴含量至少为99.7 GC面积％，异丙基溴含量不超过0.05 GC面积％。 混合物如果在封闭的化学惰性容器中在60℃下储存至少480小时，则其APHA颜色为10或更小，而混合物没有任何添加的稳定剂组分。
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