公开(公告)号：US5091350A

公开(公告)日：1992-02-25

申请号：US605939

申请日：1990-10-29

申请人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

发明人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

IPC分类号： B01J23/96 ,  B01J31/40 ,  C01G55/00 ,  C07C45/50 ,  C07C45/80 ,  C07C45/85 ,  C22B3/38 ,  C22B7/00 ,  B01J38/68 ,  C22B11/04

CPC分类号： C22B11/048 ,  B01J31/2404 ,  B01J31/4046 ,  C01G55/001 ,  C07C45/50 ,  C07C45/80 ,  C07C45/85 ,  C22B3/0051 ,  C22B7/009 ,  B01J2231/321 ,  B01J23/464 ,  B01J2531/822 ,  Y02P10/214 ,  Y02P10/234 ,  Y02P20/584

摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.

摘要翻译： 一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。 还阐述了在络合剂和增溶剂存在下制备醛的方法。 增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个 碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。

公开(公告)号：US4731485A

公开(公告)日：1988-03-15

申请号：US9734

申请日：1987-02-02

申请人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

发明人： Boy Cornils ,  Werner Konkol ,  Helmut Bahrmann ,  Hanswilhelm Bach ,  Ernest Wiebus ,  Wolfgang Lipps

IPC分类号： C07C45/50

CPC分类号： C07C45/50

摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.

摘要翻译： 一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。 还阐述了在络合剂和增溶剂存在下制备醛的方法。 增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个 碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。

公开(公告)号：US4801754A

公开(公告)日：1989-01-31

申请号：US125595

申请日：1987-11-25

申请人： Hanswilhelm Bach ,  Boy Cornils ,  Wilhelm Gick ,  Gehard Diekhaus ,  Werner Konkol ,  Ernest Wiebus

发明人： Hanswilhelm Bach ,  Boy Cornils ,  Wilhelm Gick ,  Gehard Diekhaus ,  Werner Konkol ,  Ernest Wiebus

IPC分类号： B01J31/24 ,  B01J31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00

CPC分类号： C07C45/50

摘要： In a hydroformylation process for the preparation of aldehydes by reacting aliphatic olefins of 2 to 12 carbon atoms with carbon monoxide and hydrogen at temperatures of 20.degree. to 150.degree. C. and pressures of 0.1 to 20 mPa in the liquid phase and in the presence of an aqueous solution containing 50 to 800 wt. ppm of rhodium and 25 to 30 wt. % of phosphines, in each case based on the aqueous solution as a catalyst system and in addition the transformation products of the phosphines, the improvement comprising draining off a portion of the aqueous solution of the catalyst system together with the reaction product and replacing the same by fresh aqueous solution of the catalyst system whereby the original catalyst selectivity for formation of n-aldehydes is maintained.

摘要翻译： 在通过使2至12个碳原子的脂族烯烃与一氧化碳和氢气在20至150℃的温度和0.1至20mPa的压力下在液相中以及在 含有50〜800重量％ ppm的铑和25〜30wt。 膦的百分比，在每种情况下基于作为催化剂体系的水溶液，此外，膦的转化产物，改进包括将一部分催化剂体系的水溶液与反应产物一起排出并将其替换 通过新鲜的催化剂体系水溶液，由此维持形成正醛的初始催化剂选择性。