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1.发明授权Low ash gas generant and ignition compositions for vehicle occupant passive restraint systems 有权低灰分气体发生剂和车辆乘员被动约束系统的点火成分公开(公告)号：US06334961B1
公开(公告)日：2002-01-01
申请号：US09436344
申请日：1999-11-09
申请人： Brian K. Wheatley , Norman H. Lundstrom , Robert D. Lynch , R. Stephen Scheffee , James D. Martin
发明人： Brian K. Wheatley , Norman H. Lundstrom , Robert D. Lynch , R. Stephen Scheffee , James D. Martin
IPC分类号： C06B3112
摘要： Solid gas generant compositions produce low particulates (e.g., condensed ash) when ignited. The solid gas generant compositions most preferably include a nitramine, at least one oxidizer selected from nitrates of strontium or cerium, in admixture with or without potassium perchlorate, and a binder. Graphite may optionally be employed. The gas generant compositions are usefully employed in inflatable vehicle occupant passive restraint systems (e.g., air bag systems).
摘要翻译： 当点燃时，固体气体发生剂组合物产生低颗粒（例如浓缩灰分）。 固体气体发生剂组合物最优选包括硝酸铵，至少一种选自锶或铈的硝酸盐的氧化剂，与或不与高氯酸钾混合，以及粘合剂。 可以任选地使用石墨。 气体发生剂组合物有用地用于可充气车辆乘员被动约束系统（例如气囊系统）中。
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公开(公告)号：US6045726A
公开(公告)日：2000-04-04
申请号：US109156
申请日：1998-07-02
CPC分类号： C08K5/29 , C09K21/02 , C09K21/10 , Y10S428/921
摘要： A fire suppressant composition is provided which exhibits a low pressure and low flame temperature. The composition comprises ammonium nitrate and a guanidine salt or derivative which produces greater than 3 moles of inert gas per 100 grams of composition and alkali metal or alkaline earth salts for flame suppression. The composition may also include iron or iron oxide.
摘要翻译： 提供了具有低压和低火焰温度的防火剂组合物。 该组合物包含硝酸铵和每100克组合物产生大于3摩尔惰性气体的胍盐或衍生物，用于阻燃的碱金属或碱土金属盐。 组合物还可以包括铁或氧化铁。
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公开(公告)号：US6136113A
公开(公告)日：2000-10-24
申请号：US130455
申请日：1998-08-07
IPC分类号： B60R21/26 , B01J7/00 , C06B23/00 , C06B29/02 , C06B31/02 , C06B31/28 , C06B43/00 , C06B45/06 , C06D5/06 , C06B45/10 , C06B28/32
CPC分类号： C06D5/06 , C06B23/007
摘要： An improved thermally stable, storage stable gas generating composition characterized by both an increased burning rate and a decreased pressure exponent for producing a clean, nontoxic, substantially ash- and solids-free gas for inflating inflatable structures such as vehicle airbags is provided. Optimum combustion efficiencies and operating pressures are achieved in the improved gas generating composition by adding an effective amount of a copper or copper compound catalyst to a gas generating composition that is preferably a eutectic mixture or solid solution of ammonium nitrate, at least one highly oxygenated fuel, potassium or cesium perchlorate or nitrate and an optional binder.
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公开(公告)号：US06340401B1
公开(公告)日：2002-01-22
申请号：US09499030
申请日：2000-02-07
IPC分类号： D03D2300
CPC分类号： C06D5/06 , C06B23/007
摘要： An improved thermally stable, storage stable gas generating composition characterized by both an increased burning rate and a decreased pressure exponent for producing a clean, nontoxic, substantially ash- and solids-free gas for inflating inflatable structures such as vehicle airbags is provided. Optimum combustion efficiencies and operating pressures are achieved in the improved gas generating composition by adding an effective amount of a copper or copper compound catalyst to a gas generating composition that is preferably a eutectic mixture or solid solution of ammonium nitrate, at least one highly oxygenated fuel, potassium or cesium perchlorate or nitrate and an optional binder.
摘要翻译： 提供了一种改进的热稳定，储存稳定的气体产生组合物，其特征在于产生用于充气的充气结构例如车辆安全气囊的清洁，无毒，基本上无灰尘和无固体气体的燃烧速率和压力指数降低。 通过向气体发生组合物中加入有效量的铜或铜化合物催化剂，可以在改进的气体发生组合物中实现最佳的燃烧效率和操作压力，所述气体发生组合物优选为硝化铵的共晶混合物或固溶体，至少一种高度氧化的燃料 ，钾或铯高氯酸盐或硝酸盐和任选的粘合剂。
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5.发明授权Gas generant compositions exhibiting low autoignition temperatures and methods of generating gases therefrom 有权显示低自燃温度的气体发生剂组合物和从其中产生气体的方法公开(公告)号：US06673172B2
公开(公告)日：2004-01-06
申请号：US09849439
申请日：2001-05-07
IPC分类号： C06B4300
CPC分类号： C06C9/00 , C06B21/005 , C06B31/12 , C06D5/06
摘要： Gas generant compositions exhibit low autoignition temperatures. In preferred forms, the gas generant compositions include azobisformamidine dinitrate (AZODN) and a eutectic mixture (comelt) of silver nitrate and potassium nitrate. The comelt of silver nitrate and potassium nitrate is most preferably present in the formulations of the invention in an amount to achieve a low autoignition temperature of between about 140° C. (284° F.) to about 160° C. (320° F.). The compositions of the invention may include a variety of auxiliary components typically employed in conventional gas generant compositions for their intended purpose. For example, especially preferred formulations of the present invention will include a powdered metal or metal oxide as a combustion catalyst to speed the decomposition reaction and also as a combustion aid to facilitate the ignition of the primary propellant or gas generant.
摘要翻译： 气体发生剂组合物显示低自燃温度。 在优选形式中，气体发生剂组合物包括硝酸银和硝酸钾的偶氮二甲脒二硝酸盐（AZODN）和共晶混合物（熔点）。 硝酸银和硝酸钾的熔点最优选存在于本发明的制剂中，其用量达到约140℃（284°F）至约160℃的低自燃温度（320°F 。）。 本发明的组合物可以包括通常用于其预期目的的常规气体发生剂组合物中的各种辅助组分。 例如，本发明的特别优选的配方将包括作为燃烧催化剂的粉末金属或金属氧化物以加速分解反应，并且还可以作为燃烧助剂以促进初级推进剂或气体发生剂的点燃。
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公开(公告)号：US5734123A
公开(公告)日：1998-03-31
申请号：US538325
申请日：1995-10-03
申请人： Brian K. Wheatley , James D. Martin
发明人： Brian K. Wheatley , James D. Martin
摘要： A gas-generating composition for inflating inflation devices such as air bags, life rafts, slide chutes, and the like which comprises an oxidizer component, cellulose acetate and plasticizer. The cellulose acetate and plasticizer provides a binder system which does not produce hazardous compounds upon combustion. Molded articles can be formed by injection molding or extruding the composition.
摘要翻译： 一种用于充气膨胀装置的气体发生组合物，包括氧化剂组分，乙酸纤维素和增塑剂等气囊，救生筏，滑槽等。 醋酸纤维素和增塑剂提供了一种在燃烧时不会产生有害化合物的粘合剂体系。 可以通过注射成型或挤出组合物来形成模制品。
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7.发明授权Gas-generative composition consisting essentially of ammonium perchlorate plus a chlorine scavenger and an organic fuel 失效气体生成组合物基本上由高氯酸铵加氯清除剂和有机燃料组成
公开(公告)号：US5861571A
公开(公告)日：1999-01-19
申请号：US840472
申请日：1997-04-18
摘要： This invention relates to gas-generative compositions consisting essentially of ammonium perchlorate with a chlorine scavenger, such as strontium nitrate, barium nitrate, potassium nitrate, or lithium carbonate, the combination being present in an amount of about 30 to about 95% by weight, up to about 5% by weight of a binder, up to about 5% by weight of a burning rate catalyst, together with an organic fuel, such as guanidine nitrate. The fuel is in an amount complementary to the combined weight of ammonium perchlorate, burning rate catalyst, chlorine scavenger, and binder, at an oxidation ratio of 0.90 to 0.98. The invention also includes the method of inflating an inflatable device by generating gas employing the noted composition and a gas generator in which the gas-generative composition is that of the present invention.
摘要翻译： 本发明涉及基本上由高氯酸铵与氯清除剂如硝酸锶，硝酸钡，硝酸钾或碳酸锂组成的气体发生组合物，该组合物的存在量为约30至约95重量％ 最多约5重量％的粘合剂，至多约5重量％的燃烧速率催化剂，以及有机燃料如硝酸胍。 在0.90〜0.98的氧化比下，燃料与高氯酸铵，燃烧速率催化剂，氯清除剂和粘合剂的组合重量互补。 本发明还包括通过使用所述组合物产生气体来充气可膨胀装置的方法和其中气体发生组合物是本发明组合物的气体发生器。
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8.发明授权Pyrotechnic method of generating a particulate-free, non-toxic odorless and colorless gas 失效产生无颗粒，无毒无味无色气体的烟火方法
公开(公告)号：US5747730A
公开(公告)日：1998-05-05
申请号：US663009
申请日：1996-06-07
IPC分类号： B60R21/26 , A62B99/00 , B01J7/00 , B60R21/264 , B60R21/272 , C06B21/00 , C06B25/34 , C06B31/32 , C06B31/34 , C06D5/00 , C06D5/06 , F42C7/00 , B60R21/28
CPC分类号： B60R21/272 , B60R21/2644 , C06B21/005 , C06B31/32 , C06D5/06
摘要： An essentially particulate-free, non-toxic, odorless and colorless gas is generated in a pyrotechnic inflator device by using a eutectic solution of ammonium nitrate, guanidine nitrate and/or aminoguanidine nitrate, and minor amounts of polyvinyl alcohol and either potassium nitrate or potassium perchlorate. Ballistic modifiers such as triaminoguanidine nitrate (TAGN) or nitroguanidine (NQ) may be used as needed.
摘要翻译： 通过使用硝酸铵，硝酸胍和/或氨基胍硝酸盐的共晶溶液，以及少量的聚乙烯醇和硝酸钾或钾盐，在烟火充气装置中产生基本上无颗粒，无毒，无味和无色的气体 高氯酸盐 可以根据需要使用弹道改性剂，例如硝酸三氨基胍（TAGN）或硝基胍（NQ）。
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9.发明授权Preparation of eutectic mixtures of ammonium nitrate and amino guanidine nitrate 失效制备硝酸铵和氨基硝酸胍的共晶混合物
公开(公告)号：US6073438A
公开(公告)日：2000-06-13
申请号：US21315
申请日：1998-02-10
CPC分类号： C06B21/005 , C06B31/32 , C06D5/06
摘要： A eutectic solution of ammonium nitrate and either aminoguanidiine nitrate (AGN) or guanidine nitrate (AN) in the form of a present pellet is used to generate a particulate-free, non-toxic, odorless and colorless gas that is useful wherever an immediate source of such gas is required, such as the inflation of an occupant restraint air bag. The use of the material in the form of a eutectic totally eliminates pellet cracking. Moreover, the addition of a minor amount of potassium nitrate to the eutectic solution eliminates the ammonium nitrate phase change due to temperature cycling without adversely affecting the pressed pellets' freedom from cracking due to said temperature cycling.
摘要翻译： 使用硝酸铵和氨基胍二硝酸盐（AGN）或硝酸胍（AN）以本粒料形式的共晶溶液产生无颗粒，无毒，无臭和无色的气体，无论何时立即来源 需要这种气体，例如乘员约束气囊的充气。 以共晶体形式使用材料完全消除了颗粒开裂。 此外，向共晶溶液中加入少量的硝酸钾消除了由于温度循环引起的硝酸铵相变，而不会不利地影响压制颗粒由于所述温度循环而没有破裂。
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公开(公告)号：US5936195A
公开(公告)日：1999-08-10
申请号：US872320
申请日：1997-06-10
申请人： Brian K. Wheatley
发明人： Brian K. Wheatley
CPC分类号： C06B33/04 , C06D5/06 , Y10S149/114
摘要： A gas generating composition, particularly for inflating devices such as air bag inflators, includes an effective amount of an exploded aluminum powder to both increase the burning rate and lower the composition's pressure exponent.
摘要翻译： 气体发生组合物，特别是用于充气装置如气囊充气机的气体发生组合物包括有效量的分解铝粉，以增加燃烧速率并降低组合物的压力指数。
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