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    Rare earth-doped, stabilized cadmium halide glasses
    1.
    发明授权
    Rare earth-doped, stabilized cadmium halide glasses 失效
    稀土掺杂，稳定的镉卤化物玻璃

    公开(公告)号：US5346865A

    公开(公告)日：1994-09-13

    申请号：US86048

    申请日：1993-07-06

    申请人： Bruce G. Aitken ,  Frank A. Annunziata ,  Roger F. Bartholomew ,  Mark A. Newhouse ,  Mark L. Powley ,  Andrea L. Sadd

    发明人： Bruce G. Aitken ,  Frank A. Annunziata ,  Roger F. Bartholomew ,  Mark A. Newhouse ,  Mark L. Powley ,  Andrea L. Sadd

    IPC分类号： C03C3/32 ,  C03C4/00 ,  C03C4/10 ,  H01S3/16 ,  H01S3/17

    CPC分类号： C03C4/10 ,  C03C3/32 ,  C03C3/325 ,  C03C4/0071 ,  H01S3/17 ,  H01S3/1603 ,  Y10S501/904

    摘要： This invention is directed to the production of transparent glasses exhibiting transmission far into the infrared regime of the radiation spectrum. The glasses consist essentially, in mole percent, of 42-55% CdF.sub.2 and/or CdCl.sub.2, 30-40% NaF and/or NaCl, 2-20% total of BaF.sub.2 and/or BaCl.sub.2 +KF and/or KCl, consisting of 0-15% BaF.sub.2 and/or BaCl.sub.2 and 0-7% KF and/or KCl, 1-12% total of at least one stabilizing metal halide selected from the group LiX, BeX.sub.2, MgX.sub.2, MnX.sub.2, PbX.sub.2, TlX, COX.sub.2, and ZnX.sub.2, and 0,005-0.5% REX.sub.3, wherein Re is at least one rare earth metal selected from the lanthanide series of rare earth metals and X is at least one halide selected from the group consisting of fluoride, chloride, and bromide. The preferred glasses contain at least 2% each of BaF.sub.2 and/or BaCl.sub.2 and KF and/or KCl.

    摘要翻译： 本发明涉及透明玻璃的生产，该透明玻璃显示出远离辐射光谱的红外区域的传播。 玻璃基本上以摩尔百分数计含42-55％的CdF2和/或CdCl2，30-40％的NaF和/或NaCl，2-20％的BaF 2和/或BaCl 2 + KF和/或KCl，由 0-15％BaF 2和/或BaCl 2和0-7％KF和/或KCl，1-12％的至少一种选自LiX，BeX2，MgX2，MnX2，PbX2，TlX，COX2， 和ZnX2和0.005-0.5％的REX3，其中Re是选自镧系稀土金属中的至少一种稀土金属，X是选自氟化物，氯化物和溴化物中的至少一种卤化物。 优选的玻璃含有至少2％的BaF 2和/或BaCl 2和KF和/或KCl。

    Hermetically sealed glass package and method of fabrication
    3.
    发明授权
    Hermetically sealed glass package and method of fabrication 有权
    密封玻璃包装及其制造方法

    公开(公告)号：US08148179B2

    公开(公告)日：2012-04-03

    申请号：US12725648

    申请日：2010-03-17

    申请人： Bruce G. Aitken ,  Paul S. Danielson ,  James E. Dickinson, Jr. ,  Stephan L. Logunov ,  Robert Morena ,  Mark L. Powley ,  Kamjula P. Reddy ,  Joseph F. Schroeder, III ,  Alexander Streltsov

    发明人： Bruce G. Aitken ,  Paul S. Danielson ,  James E. Dickinson, Jr. ,  Stephan L. Logunov ,  Robert Morena ,  Mark L. Powley ,  Kamjula P. Reddy ,  Joseph F. Schroeder, III ,  Alexander Streltsov

    IPC分类号： H01L21/00

    CPC分类号： C03B23/245 ,  C03C3/091 ,  C03C3/093 ,  C03C3/108 ,  C03C8/04 ,  C03C8/10 ,  C03C8/24 ,  C03C27/06 ,  H01L51/524 ,  H01L51/5246

    摘要： A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. In one embodiment, the hermetically sealed glass package is manufactured by providing a first substrate plate and a second substrate plate. The second substrate contains at least one transition or rare earth metal such as iron, copper, vanadium, manganese, cobalt, nickel, chromium, neodymium and/or cerium. A sensitive thin-film device that needs protection is deposited onto the first substrate plate. A laser is then used to heat the doped second substrate plate in a manner that causes a portion of it to swell and form a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the thin film device. The second substrate plate is doped with at least one transition metal such that when the laser interacts with it there is an absorption of light from the laser in the second substrate plate, which leads to the formation of the hermetic seal while avoiding thermal damage to the thin-film device. Another embodiment of the hermetically sealed glass package and a method for manufacturing that hermetically sealed glass package are also described herein.

    摘要翻译： 这里使用OLED显示器作为示例来描述气密密封的玻璃封装和制造密封玻璃封装的方法。 在一个实施例中，通过提供第一基板和第二基板制造密封的玻璃封装。 第二基板包含至少一种过渡金属或稀土金属，例如铁，铜，钒，锰，钴，镍，铬，钕和/或铈。 需要保护的敏感薄膜器件沉积到第一衬底板上。 然后使用激光器以使其一部分膨胀并形成将第一衬底板连接到第二衬底板的气密密封件并且还保护薄膜器件的方式来加热掺杂的第二衬底板。 第二衬底板掺杂有至少一种过渡金属，使得当激光与其相互作用时，吸收来自第二衬底板中的激光的光，这导致气密密封的形成，同时避免对 薄膜装置。 本文还描述了密封玻璃封装的另一个实施例以及密封玻璃封装的制造方法。

    HERMETICALLY SEALED GLASS PACKAGE AND METHOD OF FABRICATION
    5.
    发明申请
    HERMETICALLY SEALED GLASS PACKAGE AND METHOD OF FABRICATION 有权
    密封玻璃包装和制造方法

    公开(公告)号：US20100186449A1

    公开(公告)日：2010-07-29

    申请号：US12725648

    申请日：2010-03-17

    申请人： Bruce G. Aitken ,  Paul S. Danielson ,  James E. Dickinson, JR. ,  Stephan L. Longunov ,  Robert Morena ,  Mark L. Powley ,  Kamjula P. Reddy ,  Joseph F. Schroeder, III ,  Alexander Streltsov

    发明人： Bruce G. Aitken ,  Paul S. Danielson ,  James E. Dickinson, JR. ,  Stephan L. Longunov ,  Robert Morena ,  Mark L. Powley ,  Kamjula P. Reddy ,  Joseph F. Schroeder, III ,  Alexander Streltsov

    IPC分类号： C03B29/00

    CPC分类号： C03B23/245 ,  C03C3/091 ,  C03C3/093 ,  C03C3/108 ,  C03C8/04 ,  C03C8/10 ,  C03C8/24 ,  C03C27/06 ,  H01L51/524 ,  H01L51/5246

    摘要： A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. In one embodiment, the hermetically sealed glass package is manufactured by providing a first substrate plate and a second substrate plate. The second substrate contains at least one transition or rare earth metal such as iron, copper, vanadium, manganese, cobalt, nickel, chromium, neodymium and/or cerium. A sensitive thin-film device that needs protection is deposited onto the first substrate plate. A laser is then used to heat the doped second substrate plate in a manner that causes a portion of it to swell and form a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the thin film device. The second substrate plate is doped with at least one transition metal such that when the laser interacts with it there is an absorption of light from the laser in the second substrate plate, which leads to the formation of the hermetic seal while avoiding thermal damage to the thin-film device. Another embodiment of the hermetically sealed glass package and a method for manufacturing that hermetically sealed glass package are also described herein.

    摘要翻译： 这里使用OLED显示器作为示例来描述气密密封的玻璃封装和制造密封玻璃封装的方法。 在一个实施例中，通过提供第一基板和第二基板制造密封的玻璃封装。 第二基板包含至少一种过渡金属或稀土金属，例如铁，铜，钒，锰，钴，镍，铬，钕和/或铈。 需要保护的敏感薄膜器件沉积到第一衬底板上。 然后使用激光器以使其一部分膨胀并形成将第一衬底板连接到第二衬底板的气密密封件并且还保护薄膜器件的方式来加热掺杂的第二衬底板。 第二衬底板掺杂有至少一种过渡金属，使得当激光与其相互作用时，吸收来自第二衬底板中的激光的光，这导致气密密封的形成，同时避免对 薄膜装置。 本文还描述了密封玻璃封装的另一个实施例以及密封玻璃封装的制造方法。

    Gallium sulfide glasses
    6.
    发明授权
    Gallium sulfide glasses 失效

    公开(公告)号：US5392376A

    公开(公告)日：1995-02-21

    申请号：US225767

    申请日：1994-04-11

    申请人： Bruce G. Aitken ,  Mark A. Newhouse

    发明人： Bruce G. Aitken ,  Mark A. Newhouse

    IPC分类号： G02B6/12 ,  C03C3/32 ,  C03C4/10 ,  C03C13/04 ,  C03C3/23

    CPC分类号： C03C3/323 ,  C03C13/043 ,  C03C13/044 ,  C03C3/321 ,  C03C4/10 ,  Y10S501/904 ,  Y10T428/2929

    摘要： This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga.sub.2 S.sub.3, 0-35% RS.sub.x, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln.sub.2 S.sub.3, wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga.sub.2 S.sub.3, 0-10% R.sub.2 S.sub.3, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, and indium, 55-94.5% GeS.sub.2, 0.5-25% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, potassium, silver, sodium, strontium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-10% total selenide, 0-25% total chloride and/or fluoride, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value when doped with Pr demonstrate exceptionally high values of .tau..

    Ga- and/or In-containing AsGe sulfide glasses
    7.
    发明授权
    Ga- and/or In-containing AsGe sulfide glasses 失效
    含Ga和/或In含量的AsGe硫化物玻璃

    公开(公告)号：US5389584A

    公开(公告)日：1995-02-14

    申请号：US225766

    申请日：1994-04-11

    申请人： Bruce G. Aitken ,  Mark A. Newhouse

    发明人： Bruce G. Aitken ,  Mark A. Newhouse

    IPC分类号： C03C3/32 ,  C03C4/10

    CPC分类号： C03C3/321 ,  C03C3/323 ,  C03C4/10 ,  C03C4/12 ,  Y10S501/904

    摘要： This invention is directed to the production of transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, said glasses consisting essentially, expressed in terms of mole percent on the sulfide basis, of 55-95% GeS.sub.2, 2-40% As.sub.2 S.sub.3, 0.01-20% R.sub.2 S.sub.3, wherein R is at least one trivalent network forming cation selected from the group consisting of gallium and indium, 0-10% MS.sub.x, wherein M is at least one modifying cation selected from the group consisting of aluminum, barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-20% total of at least one halide selected from the group consisting of chloride and fluoride, 0-5% total selenide, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value. The difference between the temperature of the onset of crystallization and the transition temperature of the glasses is at least 150.degree. C. and commonly will be greater than 200.degree. C.

    摘要翻译： 本发明涉及生产透过远离电磁辐射光谱的红外区域的透射性优异的透明玻璃，所述玻璃基本上以硫化物摩尔百分数表示55-95％GeS2，2-40 ％As 2 S 3，0.01-20％R 2 S 3，其中R是选自由镓和铟组成的组中的至少一种三价网络形成的阳离子，0-10％的MS x，其中M是至少一种选自铝的修饰阳离子 ，钡，镉，钙，铅，锂，汞，钾，银，钠，锶，铊，锡，钇和镧系稀土金属，0-20％的至少一种选自 由氯化物和氟化物组成的组，0-5％的硒化物，其中硫和/或硒含量可以在化学计量值的85-125％之间变化。 结晶开始的温度与玻璃的转变温度之间的差异至少为150℃，通常将大于200℃。

    Gallium sulfide glasses
    8.
    再颁专利
    Gallium sulfide glasses 失效
    硫化镓玻璃

    公开(公告)号：USRE36513E

    公开(公告)日：2000-01-18

    申请号：US775706

    申请日：1996-12-17

    申请人： Bruce G. Aitken ,  Mark A. Newhouse

    发明人： Bruce G. Aitken ,  Mark A. Newhouse

    IPC分类号： G02B6/12 ,  C03C3/32 ,  C03C4/10 ,  C03C13/04 ,  C03C3/23

    CPC分类号： C03C3/323 ,  C03C13/043 ,  C03C13/044 ,  C03C3/321 ,  C03C4/10 ,  Y10S501/904 ,  Y10T428/2929

    摘要： This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga.sub.2 S.sub.3, 0-35% RS.sub.x, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln.sub.2 S.sub.3, wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga.sub.2 S.sub.3, 0-10% R.sub.2 S.sub.3, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, and indium, 55-94.5% GeS.sub.2, 0.5-25% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, potassium, silver, sodium, strontium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-10% total selenide, 0-25% total chloride and/or fluoride, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value when doped with Pr demonstrate exceptionally high values of .tau..

    摘要翻译： 本发明广泛地涉及在电磁辐射光谱的红外区域中表现出优异透射性的透明玻璃，基本上以摩尔百分数表示的40-80％Ga 2 S 3，0-35％RS x的玻璃，其中R是 选自铝，锑，砷，锗和铟的至少一种网络形成阳离子，1-50％的Ln2S3，其中Ln是至少一种选自稀土金属阳离子和钇的阳离子， 1-45％的MS x，其中M是选自钡，镉，钙，铅，锂，汞，钾，银，钠，锶，铊和锡中的至少一种改性金属阳离子，以及0-10 总氯化物和/或氟化物。 基本上以摩尔百分比表示的5-30％Ga 2 S 3，0-10％R 2 S 3的玻璃组合物，其中R是选自铝，锑，砷和铟的至少一种形成网络的阳离子，55 -94.5％GeS2,0.5-25％MSx，其中M是选自钡，镉，钙，铅，锂，钾，银，钠，锶，锡，钇中的至少一种改性金属阳离子和 稀土金属镧系，0-10％总硒，0-25％总氯化物和/或氟化物，其中硫和/或硒含量可以在化学计量值的85-125％之间变化，当掺杂Pr 表现出非常高的tau值。