公开(公告)号：US09434160B2

公开(公告)日：2016-09-06

申请号：US14468682

申请日：2014-08-26

Applicant: CANON FINETECH INC.

Inventor： Yuusuke Sumikawa ,  Shintaro Suzuki

IPC: G01D11/00 ,  B41J2/14 ,  B41J2/155 ,  B41J2/16 ,  B41J2/21

CPC classification number: B41J2/14016 ,  B41J2/1433 ,  B41J2/155 ,  B41J2/1601 ,  B41J2/2107 ,  B41J2002/14403

Abstract: An ink jet recording head, includes a nozzle array of nozzle flow paths; ink ejection orifices communicating with the nozzle flow paths; heaters in the nozzle flow paths; and ink with which the head is filled. The ink contains a coloring material, an acetylene glycol-based surfactant, and water, the surfactant containing one or more kinds of an acetylene glycol or an ethylene oxide adduct thereof, an average addition number of moles of ethylene oxide of the whole surfactant being 3 to 7. The ink has a viscosity of 1.5 mPa·s to 3.0 mPa·s. The head is a line type head having an opening area of each ink ejection orifice of 100 μm2 to 350 μm2, a total number of nozzles of 1,200 or more, and a length of the nozzle array of 2 inches or more, and the head is driven at a frequency of 1 kHz to 10 kHz.

Abstract translation: 一种喷墨记录头，包括喷嘴流道的喷嘴阵列; 喷墨口与喷嘴流路连通; 喷嘴流路中的加热器; 和头部填充的墨水。 油墨含有着色材料，乙炔二醇类表面活性剂和水，表面活性剂含有一种或多种乙炔二醇或其环氧乙烷加合物，整个表面活性剂的环氧乙烷的平均加成摩尔数为3 油墨的粘度为1.5mPa·s〜3.0mPa·s。 头部是具有每个喷墨孔的开口面积为100μm2〜350μm2，喷嘴总数为1200以上，喷嘴列的长度为2英寸以上的线型头，头为 以1kHz至10kHz的频率驱动。

公开(公告)号：US20150070437A1

公开(公告)日：2015-03-12

申请号：US14477057

申请日：2014-09-04

Applicant: CANON FINETECH INC.

Inventor： Yuusuke Sumikawa ,  Masato Kawakami ,  Ryuta Aoto ,  Eriko Himura ,  Kanako Aratani ,  Takahiro Tsutsui ,  Shintaro Suzuki

IPC: C08K5/3415 ,  C09D125/14 ,  C09D11/38 ,  B41J2/175 ,  C09D11/322

CPC classification number: C08K5/3415 ,  B41J2/1404 ,  B41J2/155 ,  B41J2/175 ,  B41J2002/14379 ,  B41J2002/14403 ,  C09D11/322 ,  C09D11/38 ,  C09D125/14

Abstract: An ink jet recording ink including a coloring material; water; and three kinds of water-soluble compounds. The content of the water is 70 mass % or more with respect to the total amount of the ink. Each water-soluble compound has a molecular weight of 80 or more and is a liquid compound having a vapor pressure at 20° C. of 5 Pa or less or a solid compound, and at least one kind of the water-soluble compounds is a solid compound. In case that the water-soluble compounds are mixed at a ratio at which the water-soluble compounds are incorporated into the ink to provide a mixture, a 40% aqueous solution of the mixture has a water activity value of 0.88-0.91 and a viscosity of 3.3 mPa·s or less. The total content of the water-soluble compounds in the ink is 20-25 mass % with respect to the total amount of the ink.

Abstract translation: 包括着色材料的喷墨记录油墨; 水; 和三种水溶性化合物。 水的含量相对于油墨的总量为70质量％以上。 每种水溶性化合物的分子量为80以上，为20Pa以下的蒸气压为5Pa以下的液体化合物或固体化合物，至少一种水溶性化合物为 固体化合物。 在水溶性化合物以将水溶性化合物引入墨水中以提供混合物的比例混合的情况下，混合物的40％水溶液的水活度值为0.88-0.91，粘度 为3.3mPa·s以下。 油墨中的水溶性化合物的总含量相对于油墨的总量为20〜25质量％。

公开(公告)号：US09278527B2

公开(公告)日：2016-03-08

申请号：US14474547

申请日：2014-09-02

Applicant: CANON FINETECH INC.

Inventor： Kanako Aratani ,  Ryuta Aoto ,  Yuusuke Sumikawa ,  Takahiro Tsutsui ,  Shintaro Suzuki ,  Masato Kawakami

IPC: B41J29/38 ,  B41J2/15 ,  B41J2/14 ,  B41J2/175 ,  C08K5/3415 ,  C09D11/322 ,  C09D11/38 ,  C09D125/14 ,  C09D11/033 ,  C09D11/30 ,  B41J2/165

CPC classification number: B41J2/1433 ,  B41J2/16508 ,  B41J2/1652 ,  B41J2/16538 ,  B41J2/17513 ,  B41J2/17563 ,  B41J2202/00 ,  C08K5/3415 ,  C09D11/033 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C09D11/38 ,  C09D125/14

Abstract: An ink jet recording ink including a pigment; water; and water-soluble compounds. The pigment comprises a resin-dispersed pigment dispersed with a (meth)acrylate-based random copolymer having an acid value of 100-160 mgKOH/g. The water-soluble compounds include at least ethylene urea and a water-soluble compound having a hydrophilicity-hydrophobicity coefficient defined by the following equation (A) of 0.37 or less The total content of the water-soluble compounds is 22-50 mass % with respect to the total amount of the ink The content of the ethylene urea is 11.0 mass % or more with respect to the total amount of the ink, and the proportion of the amount of the ethylene urea in the total amount of the water-soluble compounds is 50% by mass or less, Hydrophilicity-hydrophobicity coefficient=((water activity value of 20% aqueous solution)−(molar fraction of water in 20% aqueous solution))/(1−(molar fraction of water in 20% aqueous solution))  Equation (A).

Abstract translation: 一种包括颜料的喷墨记录油墨; 水; 和水溶性化合物。 颜料包含分散有酸值为100-160mgKOH / g的（甲基）丙烯酸酯类无规共聚物的树脂分散颜料。 水溶性化合物至少包括亚乙基脲和具有下述式（A）定义的亲水性 - 疏水性系数为0.37以下的水溶性化合物。水溶性化合物的总含量为22〜50质量％， 相对于油墨的总量，乙烯脲的含量相对于油墨的总量为11.0质量％以上，并且乙烯的量在水溶性化合物的总量中的比例 为50质量％以下，亲水性 - 疏水性系数=（（20％水溶液的水分活度值） - （20％水溶液中的水的摩尔分数））/（1-（20％水溶液中的水的摩尔分数） 解））等式（A）。

公开(公告)号：US09056996B2

公开(公告)日：2015-06-16

申请号：US14475982

申请日：2014-09-03

Applicant: CANON FINETECH INC.

Inventor： Eriko Himura ,  Takahiro Tsutsui ,  Yuusuke Sumikawa

IPC: B41J2/17 ,  C09D11/328 ,  B41J2/175 ,  C09D11/38 ,  C09D11/40

CPC classification number: C09D11/328 ,  B41J2/17563 ,  C09D11/38 ,  C09D11/40

Abstract: An ink-jet recording ink set includes: an ink (I) containing a dye D1, a compound C1 represented by the following formula and having a U+V of S1, and water; and an ink (II) containing a dye D2, a compound C2 represented by the following formula and having a U+V of S2, and water in which in case that a surface tension γL1 (mN/m) of an evaluation liquid L1 obtained by adding, to a 5 mass % aqueous solution of the dye D1, a compound C3 in an amount corresponding to 1 mass % of the aqueous solution, and a surface tension γL2 (mN/m) of an evaluation liquid L2 obtained by adding, to a 5 mass % aqueous solution of the dye D2, the compound C3 in an amount corresponding to 1 mass % of the aqueous solution satisfy a relationship of γL1−γL2≧10 (mN/m), the S1 and the S2 satisfy a relationship of 2≦S2−S1≦7.

Abstract translation: 喷墨记录油墨组包括：含有染料D1的油墨（I），由下式表示的化合物C1和具有S +的U + V和水; 和含有染料D2的油墨（II），由下式表示的化合物C2和具有S +的U + V的水和在得到的评价液体L1的表面张力γL1（mN / m）的情况下） 通过向染料D1的5质量％水溶液中加入相当于水溶液的1质量％的化合物C3和通过将水性溶液中添加的评价液L2的表面张力γL2（mN / m） 相对于染料D2的5质量％水溶液，对应于水溶液的1质量％的量的化合物C3满足γL1-γL2≥10（mN / m）的关系，S1和S2满足关系 2＆nlE; S2-S1＆nlE; 7。

公开(公告)号：US20150070449A1

公开(公告)日：2015-03-12

申请号：US14475982

申请日：2014-09-03

Applicant: CANON FINETECH INC.

Inventor： Eriko Himura ,  Takahiro Tsutsui ,  Yuusuke Sumikawa

IPC: C09D11/328 ,  B41J2/175

CPC classification number: C09D11/328 ,  B41J2/17563 ,  C09D11/38 ,  C09D11/40

Abstract: An ink-jet recording ink set includes: an ink (I) containing a dye D1, a compound C1 represented by the following formula and having a U+V of S1, and water; and an ink (II) containing a dye D2, a compound C2 represented by the following formula and having a U+V of S2, and water in which in case that a surface tension γL1 (mN/m) of an evaluation liquid L1 obtained by adding, to a 5 mass % aqueous solution of the dye D1, a compound C3 in an amount corresponding to 1 mass % of the aqueous solution, and a surface tension γL2 (mN/m) of an evaluation liquid L2 obtained by adding, to a 5 mass % aqueous solution of the dye D2, the compound C3 in an amount corresponding to 1 mass % of the aqueous solution satisfy a relationship of γL1−γL2≧10 (mN/m), the S1 and the S2 satisfy a relationship of 2≦S2−S1≦7.

Abstract translation: 喷墨记录油墨组包括：含有染料D1的油墨（I），由下式表示的化合物C1和具有S +的U + V和水; 和含有染料D2的油墨（II），由下式表示的化合物C2和具有S +的U + V的水和在得到的评价液体L1的表面张力γL1（mN / m）的情况下） 通过向染料D1的5质量％水溶液中加入相当于水溶液的1质量％的化合物C3和通过将水性溶液中添加的评价液L2的表面张力γL2（mN / m） 相对于染料D2的5质量％水溶液，对应于水溶液的1质量％的量的化合物C3满足γL1-γL2≥10（mN / m）的关系，S1和S2满足关系 2＆nlE; S2-S1＆nlE; 7。

公开(公告)号：US20150070436A1

公开(公告)日：2015-03-12

申请号：US14474547

申请日：2014-09-02

Applicant: CANON FINETECH INC.

Inventor： Kanako Aratani ,  Ryuta Aoto ,  Yuusuke Sumikawa ,  Takahiro Tsutsui ,  Shintaro Suzuki ,  Masato Kawakami

IPC: B41J2/14 ,  C09D125/14 ,  C09D11/322 ,  C09D11/38 ,  B41J2/175 ,  C08K5/3415

CPC classification number: B41J2/1433 ,  B41J2/16508 ,  B41J2/1652 ,  B41J2/16538 ,  B41J2/17513 ,  B41J2/17563 ,  B41J2202/00 ,  C08K5/3415 ,  C09D11/033 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C09D11/38 ,  C09D125/14

Abstract: An ink jet recording ink including a pigment; water; and water-soluble compounds. The pigment comprises a resin-dispersed pigment dispersed with a (meth)acrylate-based random copolymer having an acid value of 100-160 mgKOH/g. The water-soluble compounds include at least ethylene urea and a water-soluble compound having a hydrophilicity-hydrophobicity coefficient defined by the following equation (A) of 0.37 or less The total content of the water-soluble compounds is 22-50 mass % with respect to the total amount of the ink The content of the ethylene urea is 11.0 mass % or more with respect to the total amount of the ink, and the proportion of the amount of the ethylene urea in the total amount of the water-soluble compounds is 50% by mass or less, Hydrophilicity-hydrophobicity coefficient=((water activity value of 20% aqueous solution)−(molar fraction of water in 20% aqueous solution))/(1−(molar fraction of water in 20% aqueous solution))   Equation (A).

Abstract translation: 一种包含颜料的喷墨记录油墨; 水; 和水溶性化合物。 颜料包含分散有酸值为100-160mgKOH / g的（甲基）丙烯酸酯类无规共聚物的树脂分散颜料。 水溶性化合物至少包括亚乙基脲和具有下述式（A）定义的亲水性 - 疏水性系数为0.37以下的水溶性化合物。水溶性化合物的总含量为22〜50质量％， 相对于油墨的总量，乙烯脲的含量相对于油墨的总量为11.0质量％以上，并且乙烯的量在水溶性化合物的总量中的比例 为50质量％以下，亲水性 - 疏水性系数=（（20％水溶液的水分活度值） - （20％水溶液中水的摩尔分数））/（1-（20％水溶液中的水的摩尔分数） 解））等式（A）。