公开(公告)号：US3728385A

公开(公告)日：1973-04-17

申请号：US3728385D

申请日：1969-11-28

申请人： COLGATE PALMOLIVE CO

发明人： WIXON H ,  SUNDBY B ,  KENNEY E

IPC分类号： B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C11D1/10 ,  C11D1/88 ,  C11D3/00 ,  C07C101/12

CPC分类号： B01J37/02 ,  B01J37/00 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C07C2601/20 ,  C11D1/10 ,  C11D1/88 ,  C11D3/001

摘要： Novel oxides of aminocarboxylates or aminocarboxylic acids are of the formula:

WHEREIN R1 is an aliphatic hydrocarbon radical of four to 20 carbon atoms, R2 is a hydrocarbon radical of one to four carbon atoms or is R3COOX, R3 is a divalent aliphatic or aromatic hydrocarbon radical of one to nine carbon atoms, which may be the same as or different from another R3 radical which may be prsent in the compound, X is hydrogen, alkali metal, alkaline earth metal, other suitable salt-forming metal, ammonium, alkylamine or alkanolamine, which may be the same as or different from any other X in the formula, with it being understood that in the case of divalent or trivalent X''s it may be joined to a plurality of the shown organic moieties through the carboxylic oxygen(s) thereof. The novel compounds are possessed of surface activity and are substantive to fibrous materials, e.g., cotton and wool. They may be used as detergents or components of detergent compositions and serve as softeners for fibrous materials.

摘要翻译： 氨基羧酸盐或氨基羧酸的新型氧化物具有下式：

公开(公告)号：US3725473A

公开(公告)日：1973-04-03

申请号：US3725473D

申请日：1969-11-28

申请人： COLGATE PALMOLIVE CO

发明人： WIXON H ,  SUNDBY B ,  KENNEY E

IPC分类号： B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C11D1/10 ,  C11D1/88 ,  C11D3/00 ,  C07C101/20

CPC分类号： B01J37/02 ,  B01J37/00 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C07C2601/20 ,  C11D1/10 ,  C11D1/88 ,  C11D3/001

摘要： Novel N-(hydroxyhydrocarbyl) iminodicarboxylates or the corresponding carboxylic acids are of the formula:

WHEREIN R1 is an aliphatic hydrocarbon radical of 4 to 20 carbon atoms, R2 and R3 are divalent aliphatic or aromatic hydrocarbon radicals of 1 to 9 carbon atoms and X and Y are either hydrogen or salt-forming elements or radicals. In preferred embodiments of the invention, R1 is a saturated radical of 12 to 20 carbon atoms, R2 and R3 are identical alkylene radicals of 1 to 2 carbon atoms, and X and Y are the same monovalent metals, or lower alkanolamines e.g., sodium, triethanolamine. The novel compounds are surface active and substantive to fibrous materials such as cotton, wool and synthetics. They are useful as detergents or as components of detergent compositions. Preferred compounds function very effectively as softening agents, either alone or in conjunction with other detergent composition materials. Additionally, they may be used as starting materials for the manufacture of corresponding N-oxides, which also may be employed as detergents and textile softeners.

公开(公告)号：US3803036A

公开(公告)日：1974-04-09

申请号：US20539671

申请日：1971-12-06

申请人： COLGATE PALMOLIVE CO

发明人： SUNDBY B ,  WIXON H

IPC分类号： C07C215/12 ,  C07C309/17 ,  C11D1/12 ,  C11D1/46 ,  C11D3/00 ,  D06L1/12 ,  D06M13/224 ,  D06M13/372 ,  D06M13/38

CPC分类号： A61K8/44 ,  A61Q5/02 ,  C11D1/123 ,  C11D1/46 ,  C11D3/001 ,  Y10S516/04

摘要： A detergent composition having inherent softening properties consisting essentially of a builder salt and a detergent selected from the group consisting of water-soluble sulfosuccinates of polyhydroxy tertiary amines having the structural formula:

WHEREIN R1 is a monovalent hydrocarbon radical of 8 to 24, preferably 10 to 20 carbon atoms; R2 is an alkyl or alkylol radical containing 1 to 6 carbon atoms, and R3 is an alkylol radical containing 1 to 6 carbon atoms, and salts thereof. The reaction mixture consists of sulfonated mono-, di-, and/or triesters, depending on the number of reactive hydroxyl groups in the alcoholamine and the amount of dicarboxylic acid utilized. Since the aforedefined sulfonated esters and salts thereof uniquely possess both detergency and softening properties, they may constitute the sole detergent ingredient in the composition, although the presence of other detergents is not precluded.

摘要翻译： 具有固有软化性质的洗涤剂组合物，其基本上由助洗剂盐和洗涤剂组成，所述助洗剂盐和洗涤剂选自二羧酸的水溶性酯和具有结构式：OHR 2 R 1 CH-CH 2 N-R 3的多羟基叔胺，其中R 1是 8-24个碳原子，优选10-20个碳原子的单价烃基; R2是含有1至6个碳原子的烷基或烷醇基，R3是含有1至6个碳原子的烷醇基，及其盐。 反应混合物由单 - ，二 - 和/或三酯组成，取决于醇胺中反应性羟基的数量和所用二羧酸的量。 由于上述酯和其盐独特地具有洗涤性和软化性，所以它们可以构成组合物中唯一的洗涤剂成分，尽管不排除其它洗涤剂的存在。

公开(公告)号：US3755435A

公开(公告)日：1973-08-28

申请号：US3755435D

申请日：1969-11-28

申请人： COLGATE PALMOLIVE CO

发明人： SUNDBY B ,  KENNEY E ,  WIXON H

IPC分类号： B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C11D1/10 ,  C11D1/88 ,  C11D3/00 ,  C07C101/06

CPC分类号： B01J37/02 ,  B01J37/00 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C07C2601/20 ,  C11D1/10 ,  C11D1/88 ,  C11D3/001

摘要： N-(2-HYDROXY-HIGHER HYDROCARBYL)-N-LOWER HYDROCARBYL-AMINOCARBOXYLATES OR THE CORRESPONDING AMINOCARBOXYLIC ACIDS ARE OF THE FORMULA

R1-CH(-OH)-CH2-N(-R2)-R3-COO-X

WHEREIN R1 IS AN ALIPHATIC HYDROCARBON RADICAL OF 10 TO 20 CARBON ATOMS, R2 IS A HYDROCARBON RADICAL OF 1 TO 4 CARBON ATOMS, R3 IS A DIVALENT ALIPHATIC OR AROMATIC HYDROCARBON RADICAL OF 1 TO 9 CARBON ATOMS, AND X IS EITHER HYDROGEN OR A SALT-FORMING ELEMENT OR RADICAL. IN PREFERRED ENBODIMENTS OF THE INVENTION, R1 IS AN ACYCLIC SATURATED RADICAL OF 12 TO 16 CARBON ATOMS, R2 IS METHYL, R3 IS OF 1 TO 2 CARBON ATOMS, AND X IS A MONOVALENT METAL OR AN ALKANOLAMINE, SUCH AS SODIUM OR TRIETHANOLAMINE. THE NOVEL COMOUNDS ARE SURFACE ACTIVE AND MANY EXHIBIT EXCELLENT SUBSTANTIVITIES TO FIBROUS MATERIALS, ESPECIALLY COTTON. THEY ARE USEFUL AS DETERGENTS OR AS CONSTITUENTS OF DETERGENT PREPARATIONS. PREFERRED COMPOUNDS FUNCTION VERY EFFECTIVELY AS SOFTENING AGENTS, WHICH MAY BE EMPLOYED IN THE FINAL RINSING OF LAUNDRY OR TEXTILES, IF USED ALONE OR IN CONJUNCTION WITH OTHER DETERGENT COMPOSITION MATERIALS, IN THE WASH WATER. THE PRESENT N-(2HYDROXY-HIGHER HYDROCARBYL)-N-LOWER HYDROCARBYL-AMINOCARBOXYLATES MAY ALSO BE CONVERTED TO THE CORRESPONDING N-OXIDES, WHICH ARE ALSO EFFECTIVE DETERGENTS, AND MANY OF WHICH MAY BE EMPLOYED AS EXCELLENT SOFTENING AGENTS FOR LAUNDRY AND TEXTILES.

公开(公告)号：US3726797A

公开(公告)日：1973-04-10

申请号：US3726797D

申请日：1969-11-28

申请人： COLGATE PALMOLIVE CO

发明人： SUNDBY B ,  KENNEY E ,  WIXON H

IPC分类号： B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C11D1/10 ,  C11D1/88 ,  C11D3/00 ,  C11D1/18 ,  C11D3/04 ,  D06M13/38

CPC分类号： B01J37/02 ,  B01J37/00 ,  B01J37/03 ,  B01J37/18 ,  C07C291/04 ,  C07C2601/20 ,  C11D1/10 ,  C11D1/88 ,  C11D3/001

摘要： BUILT SYNTHETIC ORGANIC DETERGENT COMPOSITIONS COMPRISE N-(2-HYDROXY HYDROCARBYL) IMINOCARBOXYLATES OR THE CORRESPONDING CARBOXYLIC ACIDS OF THE FORMULA: R1-CH(-OH)-CH2-N(-R2-COO-X)-R3-COO-Y WHEREIN R1 IS AN ALIPHATIC HYDROCARBON RADICAL OF 4 TO 20 CARBON ATOMS, R2 AND R3 ARE DIVALENT ALIPHATIC OR AROMATIC HYDROCARBON RADICALS OF 1 TO 9 CARBON ATOMS AND X AND Y ARE EITHER HYDROGEN OR SALT-FORMING ELEMENTS OR RADICALS. IN PREFERRED EMBODIMENTS OF THE INVENTION, R1 IS A SATURATED RADICAL OF 12 TO 20 CARBON ATOMS, R2 AND R3 ARE INENTICAL ALKYLENE RADICALS OF 1 TO 2 CARBON ATOMS, AND X AND Y ARE THE SAME MONOVALENT METALS, OR LOWER ALKANOLAMINES, E.G., SODIUM, TRIETHANOLAMINE. IN ADDITION TO THE IMINODICARBOXYLATES, SUCH COMPOSITIONS COMPRISE AN INORGANIC BUILDERS SALT, SUCH AS SODIUM TRIPOLYPHOSPHATE OR POTASSIUM PHYROPHOSPHATE, AND ALSO MAY INCLUDE OTHER ADJUVANT MATERIALS, SUCH AS TRISODIUM NITRILOTRACETATE, ENZYMES, ANTI-REDEPOSITION AGENTS, BLACHES OR BLUMAGENTS, GERMICIDES, HYDROTROPES, AUXILIARY DETERGENTS AND SOFTENING AGENTS, ETC. USUALLY, THE IMINODICARBOXYLATE COMPRISES FROM 3 TO 30% OF THE COMPOSITION AND THE INORGANIC BUILDER SALT IS FROM 10 TO 70% THEREOF. THE PRODUCTS MADE MAY BE IN LIQUID OR SOLID FORM AND ARE PREFERABLY EMPLOYED AS LIQUIDS OR POWDERS. THEY MAY BE UTILIZED AS WASHING-SOFTENING AGENTS IN LAUNDERING OR MAY BE EMPLOYED IN PRE-SOAKING OR AFTER-SOAKING OF LAUNDRY, TO IMPROVE THE SOFTENING OF THE WASHED MATERIAL. THE IMINODICARBOXYLATE CAN BE USED WITHOUR INORGANIC BUILDER SALT, IN WHICH CASE IS NORMALLY FUNCTIONS PRIMARILY AS A SOFTENING AGENT AND IS PREFERABLY UTILIZED IN THE RINSE WATER, AFTER COMPLETION OF WASHING, ALTHOUGH IT MAY ALSO BE USED ALONE IN A PRE-SOAKING OR WASHING OPERATIONS.