Production of hydroxymethyl vinyl oxazoline
    1.
    发明授权
    Production of hydroxymethyl vinyl oxazoline 失效
    羟乙基乙烯基氧杂环丁烷的生产

    公开(公告)号:US3678065A

    公开(公告)日:1972-07-18

    申请号:US3678065D

    申请日:1970-12-09

    Inventor: FRUMP JOHN A

    CPC classification number: C07D263/14

    Abstract: A process for the production of hydroxymethyl vinyl oxazolines corresponding to the formula:

    WHERE R is methyl, ethyl, or hydroxymethyl and R'' is hydrogen or methyl, comprising reacting an alkanolamine, in which to the carbon atom adjacent to the amino group there are bonded three hydroxyalkyl groups, or two hydroxyalkyl groups and an alkyl group, with an ester of acrylic acid or methacrylic acid in the presence of a catalyst and a polymerization inhibitor, thereby forming an amide, and heating said amide rapidly and briefly to within about 165*-210* C in the presence of additional polymerization inhibitor, thereby forming said hydroxymethyl vinyl oxazoline.

    Abstract translation: 一种制备相应于下式的羟甲基乙烯基恶唑啉的方法:

    Oxazoline emulsifier in polymerization of styrene and butadiene
    10.
    发明授权
    Oxazoline emulsifier in polymerization of styrene and butadiene 失效
    苯乙烯和丁二烯聚合中的恶唑啉乳化剂

    公开(公告)号:US3886128A

    公开(公告)日:1975-05-27

    申请号:US40675573

    申请日:1973-10-15

    Inventor: FRUMP JOHN A

    CPC classification number: C08F236/10 C08F212/08 C08F236/06 C08F2/30

    Abstract: In a process for production of styrene-butadiene copolymer by reacting styrene and butadiene in an emulsion system in the presence of a secondary emulsifying agent, the step of using as said secondary emulsifying agent an oxazoline corresponding to the formula

    WHEREIN R is alkyl of from three to 17 carbon atoms, and R1 and R2 are methyl, ethyl or hydroxymethyl and can be the same or different.

    Abstract translation: 在二次乳化剂存在下,通过在乳液体系中使苯乙烯和丁二烯反应生产苯乙烯 - 丁二烯共聚物的方法,使用对应于式WHEREIN R的恶唑啉作为所述二级乳化剂的步骤为三 至17个碳原子,并且R 1和R 2是甲基,乙基或羟甲基,可以相同或不同。

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