公开(公告)号：US4629553A

公开(公告)日：1986-12-16

申请号：US760834

申请日：1985-07-31

申请人： Carl W. Hudson ,  Gerald E. Markley

发明人： Carl W. Hudson ,  Gerald E. Markley

IPC分类号： C10G65/04

CPC分类号： C10G65/04

摘要： A process wherein in a hydrofining zone, a sulfur- or nitrogen-containing distillate feed, or feed containing both sulfur and nitrogen, is hydrofined at hydrofining conditions sufficient to convert the sulfur and nitrogen to hydrogen sulfide, and ammonia, respectively, the hydrogen sulfide and ammonia are separated from the hydrofined product, and the hydrofined product contacted in a subsequent zone with hydrogen, or a hydrogen-containing gas over a catalyst which contains elemental iron and one or more alkali- or alkaline-earth metals at reaction conditions sufficient to reduce or restore the color of the hydrofined product. Operation in this manner permits hydrofining of the feed at higher severities, for longer periods, than heretofore possible because the adverse quality of the product reaction mixture normally caused by deterioration of the hydrofiner product at such conditions is remediated by treatment of the hydrofined product over the iron catalyst.

摘要翻译： 一种方法，其中在加氢精制区中含硫或含氮的馏出物进料或含有硫和氮的进料在加氢精炼条件下进行加氢精制，该条件足以将硫和氮分别转化为硫化氢和氨，硫化氢 并且氨与加氢精制产物分离，并且加氢精制产物在随后的区域中与氢或含氢气体在含有元素铁和一种或多种碱金属或碱土金属的催化剂上接触，反应条件足以 减少或恢复加氢精制产品的颜色。 以这种方式进行的操作允许进料以比以前更高的严格程度进行加氢精制，因为通常在这种条件下通常由氢化产物的劣化引起的产物反应混合物的不良质量通过在 铁催化剂。

公开(公告)号：US4440628A

公开(公告)日：1984-04-03

申请号：US482511

申请日：1983-04-06

申请人： William E. Winter ,  Gerald E. Markley

发明人： William E. Winter ,  Gerald E. Markley

IPC分类号： B01J23/656 ,  C10G59/02 ,  C10G35/06

CPC分类号： C10G59/02 ,  B01J23/6567

摘要： A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the rearward most reforming zones is constituted of a high rhenium, platinum rhenium catalyst, viz., a catalyst comprising supported platinum and a relatively high concentration of rhenium relative to the platinum, and preferably the catalyst in the forwardmost reforming zone, or reactor of the series, is constituted of platinum, or platinum and a relatively low concentration of rhenium relative to the platinum. At least 30 percent, preferably from 40 percent to about 90 percent, of the rearward most reactors of the unit, or even 100 percent, based on the total weight of the catalyst in all of the reactors of the unit, contain a high rhenium, platinum rhenium catalyst, the weight ratio of rhenium:platinum being at least about 1.5:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, and the reaction continued for a period of at least 700 hours, preferably from about 700 hours to about 2750 hours, while conducting the reaction at temperatures ranging from about 850.degree. F. to about 950.degree. F. (E.I.T.), at pressures ranging from about 150 psig to about 350 psig, and at gas rates ranging from about 2500 SCF/B to about 4500 SCF/B.

摘要翻译： 一种方法，其中在一系列重整区或反应器中，每个重整区或反应器各自含有床或催化剂床，后最重整区中的催化剂由高铼，铂铼催化剂，即催化剂 包括相对于铂的负载的铂和相对高浓度的铼，并且优选地，该系列的最前面的重整区或反应器中的催化剂由铂或铂和相对于铂的相对低浓度的铼构成。 基于该单元的所有反应器中的催化剂的总重量，该单元的最后反应器的至少30％，优选40％至约90％，甚至100％，含有高铼， 铂铼催化剂，铼：铂的重量比为至少约1.5:1。 催化剂床与烃或石脑油进料和氢气接触，反应持续至少700小时，优选约700小时至约2750小时，同时在约850℃的温度下进行反应 在约150psig至约350psig的压力和约2500SCF / B至约4500SCF / B的气体速率下的温度为约950°F（EIT）。

公开(公告)号：US4415441A

公开(公告)日：1983-11-15

申请号：US417218

申请日：1982-09-13

申请人： Gerald E. Markley ,  William E. Winter

发明人： Gerald E. Markley ,  William E. Winter

IPC分类号： C10G35/22 ,  C10G35/08

CPC分类号： C10G35/22 ,  Y10S585/951

摘要： A process for reforming, with hydrogen, a naphtha in a reforming reactor provided with a rhenium promoted platinum catalyst over which the naphtha is contacted and reacted at reforming conditions to produce a C.sub.5.sup.+ liquid product of improved octane. The catalyst is contacted, on initiation of the reforming reaction, with a maximum of about 75 percent of the rate of hydrogen required for maintaining the optimum C.sub.5.sup.+ liquid yield over the length of the operating cycle. The hydrogen rate is increased not later than the time of line-out of the C.sub.5.sup.+ liquid yield to that required to maintain said optimum C.sub.5.sup.+ liquid yield.

摘要翻译： 在具有铼促进的铂催化剂的重整反应器中用氢气重整石脑油的方法，在该催化剂上使石脑油在重整条件下接触并反应以产生改进的辛烷的C5 +液体产物。 在重整反应开始时，催化剂与在操作循环长度上保持最佳C5 +液体产率所需的最大氢气速率的75％接触。 氢气速率不迟于C5 +液体产量的排出时间增加到维持所述最佳C5 +液体产率所需的时间。

公开(公告)号：US4973396A

公开(公告)日：1990-11-27

申请号：US378335

申请日：1989-07-10

申请人： Gerald E. Markley

发明人： Gerald E. Markley

IPC分类号： C10G65/12

CPC分类号： C10G65/12

摘要： Hydrotreating at relatively low pressure and elevated temperature followed by a selective distillation results in lighter fractions substantially free of sulfur and nitrogen. Over half of the total liquid product is suitable for sweet hydroprocessing over a noble metal catalyst.

摘要翻译： 在相对较低的压力和升高的温度下进行加氢处理，然后进行选择性蒸馏，得到基本上不含硫和氮的较轻馏分。 总液体产物的一半以上适用于贵金属催化剂上的甜加氢处理。

公开(公告)号：US4610779A

公开(公告)日：1986-09-09

申请号：US658375

申请日：1984-10-05

申请人： Gerald E. Markley ,  James C. Spry, Jr.

发明人： Gerald E. Markley ,  James C. Spry, Jr.

IPC分类号： B01J29/90 ,  C10G45/54 ,  C10G65/08 ,  C10G45/00 ,  C07C5/10

CPC分类号： B01J29/90 ,  C10G45/54 ,  C10G65/08

摘要： A process for the hydrogenation of aromatic hydrocarbons contained in hydrocarbonaceous oil feed comprising at least about 15 wppm organic nitrogen compounds is provided in which the feed is contacted with hydrogen in a substantially sulfur-free environment in the presence of a catalyst comprising a Group VIII noble metal component, such as palladium, a Y-type crystalline aluminosilicate zeolite and a support such as alumina. When the hydrogenation activity of the catalyst decreases, the partially deactivated catalyst is stripped with hydrogen periodically to increase the hydrogenation activity of the catalyst.

摘要翻译： 提供了包含至少约15wppm有机氮化合物的烃油进料中所含芳烃的氢化方法，其中在含有VIII族贵金属的催化剂的存在下，在基本无硫的环境中，进料与氢接触 金属成分如钯，Y型结晶硅铝酸盐沸石和载体如氧化铝。 当催化剂的氢化活性降低时，部分失活的催化剂定期用氢气汽提，以提高催化剂的氢化活性。

公开(公告)号：US4990242A

公开(公告)日：1991-02-05

申请号：US366067

申请日：1989-06-14

申请人： Stephen Louie ,  Gerald E. Markley

发明人： Stephen Louie ,  Gerald E. Markley

IPC分类号： C10G65/16

CPC分类号： C10G65/16

摘要： An enhanced process to reduce the sulfur content in petroleum distillate products through fractionation of a feedstock followed by segregated hydrotreating. Improved performance and more controlled desulfurization is achieved.

摘要翻译： 通过分馏原料，然后分离加氢处理来降低石油馏分产物中硫含量的增强方法。 实现了改进的性能和更多的控制脱硫。

公开(公告)号：US4440627A

公开(公告)日：1984-04-03

申请号：US482510

申请日：1983-04-06

申请人： Gerald E. Markley

发明人： Gerald E. Markley

IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/06

CPC分类号： C10G35/09 ,  B01J23/6567

摘要： A process wherein, in a series of reforming zones, employing one or a series of reactors, each of which contains a bed, or beds of catalyst, the catalyst in the rearward most reforming zones is constituted of supported platinum and a relatively high concentration of rhenium, and the catalyst in the forward most reforming zone is constituted of platinum, or platinum and a relatively low concentration of a promoter metal, especially rhenium. In the rearward reaction zones, at least 40 percent, and preferably from 40 percent to about 90 percent, based on the total weight of catalyst in the reactor, or reactors of the unit, is constituted of a rhenium promoted platinum catalyst, the weight ratio of rhenium:platinum of which at least about 1.5:1, and preferably 2:1, or greater. The beds of catalyst are contacted at start-of-run temperatures ranging from about 875.degree. F. to about 935.degree. F. with a hydrocarbon or naphtha feed, and hydrogen, at reforming conditions to produce a hydrocarbon, or naphtha product of improved octane, and the product is withdrawn.

摘要翻译： 一种方法，其中在一系列重整区中，使用一个或一系列反应器，每个反应器包含一个床或催化剂床，后部最重整区域中的催化剂由负载的铂和相对高浓度的 铼，并且前向重整区域中的催化剂由铂或铂构成，并且相对低浓度的助催化剂金属，特别是铼构成。 在后向反应区中，基于反应器中的催化剂的总重量或该单元的反应器，至少40％，优选40％至约90％由铼促进的铂催化剂构成，重量比 的铼：其中至少约1.5:1，优选2:1或更大的铂。 催化剂床在起始运行温度范围为约875°F至约935°F的烃或石脑油进料和氢气，在重整条件下生产烃或改进的辛烷值的石脑油产物 ，并撤回产品。

公开(公告)号：US06224749B1

公开(公告)日：2001-05-01

申请号：US09073415

申请日：1998-05-06

申请人： Ramesh Gupta ,  Henry Jung ,  Edward S. Ellis ,  Gerald E. Markley

发明人： Ramesh Gupta ,  Henry Jung ,  Edward S. Ellis ,  Gerald E. Markley

IPC分类号： C10G6502

CPC分类号： C10G65/00 ,  B01J8/04 ,  B01J8/0488 ,  B01J2208/00283

摘要： A three stage hydroprocessing process includes two liquid and one vapor reaction stages, both of which produce an effluent comprising liquid and vapor. Both vapor effluents comprise vaporized hydrocarbonaceous material. Fresh hydrogen is used for the hydroprocessing in both liquid stages. The second stage liquid effluent comprises the product liquid. The first stage liquid effluent is the feed for the second stage. The first stage vapor effluent is hydroprocessed in the vapor stage and then cooled to condense and recover at least a portion of the processed vapor as additional product liquid.

摘要翻译： 三级加氢处理方法包括两个液体和一个蒸气反应阶段，二者都产生包含液体和蒸汽的流出物。 两种蒸汽流出物都包含蒸发的含烃材料。 新鲜氢气用于两个液体阶段的加氢处理。 第二级液体流出物包括产物液体。 第一阶段液体流出物是第二阶段的进料。 第一级蒸汽流出物在蒸气阶段加氢处理，然后冷却以冷凝并回收至少一部分经处理的蒸气作为另外的产物液体。

公开(公告)号：US6036844A

公开(公告)日：2000-03-14

申请号：US73413

申请日：1998-05-06

申请人： Ramesh Gupta ,  Henry Jung ,  Edward S. Ellis ,  Gerald E. Markley

发明人： Ramesh Gupta ,  Henry Jung ,  Edward S. Ellis ,  Gerald E. Markley

IPC分类号： C10G51/02 ,  C10G35/00 ,  C10G35/10 ,  C10G45/00 ,  C10G55/02 ,  C10G57/00 ,  C10G65/00 ,  C10G65/02 ,  C10G69/02

CPC分类号： C10G65/00 ,  C10G65/02

摘要： A three stage hydroprocessing process includes two liquid and one vapor reaction stages, with a hydrogen containing vapor effluent produced in both liquid stages. The second liquid stage vapor effluent comprises part of the first liquid stage feed and the first liquid stage vapor effluent is the feed for the vapor stage. At least a portion of the hydrogen for the first liquid stage and vapor stage reactions is respectively provided by the hydrogen in the second and first liquid stage vapor effluents.

摘要翻译： 三级加氢处理方法包括两个液相和一个蒸气反应阶段，在两个液相中产生含氢气的蒸气流出物。 第二液相蒸气流出物包括第一液相进料的一部分，第一液段蒸气流出物是用于蒸气阶段的进料。 用于第一液段和蒸气阶段反应的氢的至少一部分分别由第二和第一液相蒸气流出物中的氢提供。

公开(公告)号：US5707511A

公开(公告)日：1998-01-13

申请号：US362073

申请日：1994-12-22

申请人： Gerald E. Markley ,  George C. Hadjiloizou

发明人： Gerald E. Markley ,  George C. Hadjiloizou

IPC分类号： C10G45/02

CPC分类号： C10G45/02

摘要： A process for simultaneously removing heteroatoms, such as sulfur, from a virgin distillate stream and a light catalytic cyclic stream in two reaction zones in a hydrotreating process unit. One reaction zone will be a low temperature reaction zone and the other will be the high temperature zone. In the low temperature reaction zone, the cracked stream is reacted with a hydrotreating catalyst at a predetermined temperature and in high temperature reaction zone, the virgin distillate stream is reacted with a catalyst which is less reactive than that of the first reaction zone. When catalyst in the high reaction zone is replaced with fresh catalyst the temperature is lowered so that it now becomes the low temperature zone in which the cracked stream is redirected. Correspondingly, the virgin stream is redirected to the other reaction zone whose temperature is now raised and which becomes the high temperature zone and which now contains a catalyst less active than the low temperature reaction zone which now contains the fresher more active catalyst. This cyclic operation is repeated each time fresh catalyst is substituted for spent catalyst.

摘要翻译： 在加氢处理单元中的两个反应区中同时从原始馏出物流中除去杂原子如硫的方法和轻质催化的环状物流。 一个反应区是低温反应区，另一个是高温区。 在低温反应区中，裂化物流与加氢处理催化剂在预定温度和高温反应区中反应，原始馏出物流与反应性低于第一反应区的催化剂反应。 当高反应区中的催化剂被新鲜的催化剂代替时，温度降低，使其现在成为破裂流被重定向的低温区。 相应地，原始物流被重定向到温度现在升高的另一个反应区，并且其成为高温区，现在含有比现在含有更新鲜的活性催化剂的低温反应区活性较低的催化剂。 每当新鲜催化剂代替废催化剂时，重复该循环操作。