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公开(公告)号：US4440626A
公开(公告)日：1984-04-03
申请号：US482509
申请日：1983-04-06
IPC分类号： B01J23/656 , C10G35/09 , C10G35/06
CPC分类号： B01J23/6567 , C10G35/09
摘要： A process wherein, in a series of reforming zones, employing one or a series of reactors, each of which contains a bed, or beds of catalyst, the catalyst in the rearward most reforming zones is constituted of supported platinum and a relatively high concentration of rhenium, and the catalyst in the forward most reforming zone is constituted of platinum, or platinum and a relatively low concentration of a promoter metal, especially rhenium. In the rearward reaction zones, at least 40 percent, and preferably from 40 percent to about 90 percent, based on the total weight of catalyst in the reactor, or reactors of the unit, is constituted of a rhenium promoted platinum catalyst, the weight ratio of rhenium:plantinum of which at least about 1.5:1, a preferably 2:1, or greater. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, at reforming conditions to produce a hydrocarbon, or naphtha product of improved octane, and the product is withdrawn.
摘要翻译： 一种方法，其中在一系列重整区中，使用一个或一系列反应器，每个反应器包含一个床或催化剂床，后部最重整区域中的催化剂由负载的铂和相对高浓度的 铼，并且前向重整区域中的催化剂由铂或铂构成，并且相对低浓度的助催化剂金属，特别是铼构成。 在后向反应区中，基于反应器中的催化剂的总重量或该单元的反应器，至少40％，优选40％至约90％由铼促进的铂催化剂构成，重量比 的铼：植物，其至少约1.5:1，优选2:1或更大。 催化剂床与碳氢化合物或石脑油进料和氢气在重整条件下接触以产生烃或改进的辛烷的石脑油产物，并且产物被排出。
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公开(公告)号：US4415441A
公开(公告)日：1983-11-15
申请号：US417218
申请日：1982-09-13
CPC分类号： C10G35/22 , Y10S585/951
摘要： A process for reforming, with hydrogen, a naphtha in a reforming reactor provided with a rhenium promoted platinum catalyst over which the naphtha is contacted and reacted at reforming conditions to produce a C.sub.5.sup.+ liquid product of improved octane. The catalyst is contacted, on initiation of the reforming reaction, with a maximum of about 75 percent of the rate of hydrogen required for maintaining the optimum C.sub.5.sup.+ liquid yield over the length of the operating cycle. The hydrogen rate is increased not later than the time of line-out of the C.sub.5.sup.+ liquid yield to that required to maintain said optimum C.sub.5.sup.+ liquid yield.
摘要翻译： 在具有铼促进的铂催化剂的重整反应器中用氢气重整石脑油的方法，在该催化剂上使石脑油在重整条件下接触并反应以产生改进的辛烷的C5 +液体产物。 在重整反应开始时，催化剂与在操作循环长度上保持最佳C5 +液体产率所需的最大氢气速率的75％接触。 氢气速率不迟于C5 +液体产量的排出时间增加到维持所述最佳C5 +液体产率所需的时间。
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公开(公告)号：US4440628A
公开(公告)日：1984-04-03
申请号：US482511
申请日：1983-04-06
IPC分类号： B01J23/656 , C10G59/02 , C10G35/06
CPC分类号： C10G59/02 , B01J23/6567
摘要： A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the rearward most reforming zones is constituted of a high rhenium, platinum rhenium catalyst, viz., a catalyst comprising supported platinum and a relatively high concentration of rhenium relative to the platinum, and preferably the catalyst in the forwardmost reforming zone, or reactor of the series, is constituted of platinum, or platinum and a relatively low concentration of rhenium relative to the platinum. At least 30 percent, preferably from 40 percent to about 90 percent, of the rearward most reactors of the unit, or even 100 percent, based on the total weight of the catalyst in all of the reactors of the unit, contain a high rhenium, platinum rhenium catalyst, the weight ratio of rhenium:platinum being at least about 1.5:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, and the reaction continued for a period of at least 700 hours, preferably from about 700 hours to about 2750 hours, while conducting the reaction at temperatures ranging from about 850.degree. F. to about 950.degree. F. (E.I.T.), at pressures ranging from about 150 psig to about 350 psig, and at gas rates ranging from about 2500 SCF/B to about 4500 SCF/B.
摘要翻译： 一种方法，其中在一系列重整区或反应器中，每个重整区或反应器各自含有床或催化剂床，后最重整区中的催化剂由高铼，铂铼催化剂，即催化剂 包括相对于铂的负载的铂和相对高浓度的铼，并且优选地，该系列的最前面的重整区或反应器中的催化剂由铂或铂和相对于铂的相对低浓度的铼构成。 基于该单元的所有反应器中的催化剂的总重量，该单元的最后反应器的至少30％，优选40％至约90％，甚至100％，含有高铼， 铂铼催化剂，铼：铂的重量比为至少约1.5:1。 催化剂床与烃或石脑油进料和氢气接触，反应持续至少700小时，优选约700小时至约2750小时，同时在约850℃的温度下进行反应 在约150psig至约350psig的压力和约2500SCF / B至约4500SCF / B的气体速率下的温度为约950°F（EIT）。
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公开(公告)号：US5318695A
公开(公告)日：1994-06-07
申请号：US982933
申请日：1992-11-30
CPC分类号： C10G11/05
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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5.发明授权
公开(公告)号：US5051389A
公开(公告)日：1991-09-24
申请号：US542679
申请日：1990-06-25
IPC分类号： B01J21/18 , B01J23/28 , B01J23/652 , B01J23/882 , B01J37/02
CPC分类号： C10G49/04 , B01J21/18 , B01J23/28 , B01J23/6525 , B01J23/882 , B01J37/0238 , C10G45/50
摘要： A catalyst composition prepared by depositing a metal or metal compound onto a preformed carbon support and thereafter converting said metal or metal compounds to an oxide or sulfide having hydrogenation activity. The metal is selected from the group of metals consisting of Groups II-B, IV-B, IV-A, V-A, VI-A, VII-A and VIII-A metals of the Periodic Table of the Elements. The catalyst compositions are useful in hydroconversion and hydrotreating processes.
摘要翻译： 一种催化剂组合物，其通过将金属或金属化合物沉积到预先形成的碳载体上，然后将所述金属或金属化合物转化为具有氢化活性的氧化物或硫化物而制备。 金属选自由元素周期表的II-B族，IV-B族，IV-A族，V-A族，VI-A族，VII-A族和VIII-A族金属组成的金属。 催化剂组合物可用于加氢转化和加氢处理。
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公开(公告)号：US4368113A
公开(公告)日：1983-01-11
申请号：US297721
申请日：1981-08-31
摘要： A hydrocracking process is provided in which the heavy bottoms fraction recovered from the hydrocracked product is heat treated prior to being recycled to the hydrocracking zone. The resulting hydrocracked product has an increased amount of constituents boiling in the middle distillate range.
摘要翻译： 提供加氢裂化方法，其中从加氢裂化产物回收的重塔底馏分在再循环到加氢裂化区之前进行热处理。 所得到的加氢裂化产物在中间馏分范围内具有沸腾的成分的量增加。
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公开(公告)号：US4339354A
公开(公告)日：1982-07-13
申请号：US196191
申请日：1980-10-10
IPC分类号： C10G35/095 , B01J29/06 , B01J29/08 , C10G11/05 , C10G47/16
CPC分类号： B01J29/061
摘要： A catalyst, having a specified amount of rare earth metal content and a specified amount of alkali metal content, suitable for conversion of hydrocarbon oils to lower boiling products comprises a crystalline aluminosilicate zeolite, such as zeolite Y, an inorganic oxide matrix and, optionally discrete particles of alumina dispersed in the matrix. The zeolite prior to being composited with the matrix has a unit cell size above about 24.5 Angstroms. A cracking process utilizing the catalyst is also provided.
摘要翻译： 具有特定量的稀土金属含量和规定量的碱金属含量的催化剂适用于将烃油转化为低沸点产物包括结晶铝硅酸盐沸石，例如沸石Y，无机氧化物基质和任选的离散的 分散在基质中的氧化铝颗粒。 在与基质复合之前的沸石具有高于约24.5埃的晶胞尺寸。 还提供了利用催化剂的裂化方法。
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公开(公告)号：US4200520A
公开(公告)日：1980-04-29
申请号：US873106
申请日：1978-01-30
摘要： The octane number of a cracked naphtha can be significantly improved in a catalytic cracking unit, without significant decrease in naphtha yield, by maintaining certain critical concentrations of metals on the catalyst, suitably by blending or adding a heavy metals-containing component to the gas oil feed. Suitably, in a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking reactor (zone) at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regenerator (regeneration zone) by burning coke off the catalyst, and catalyst is circulated between the reactor and regenerator, sufficient of a metals-containing heavy feedstock is admixed, intermittantly or continuously, with the gas oil feed to deposit metals on said catalyst and raise the metals-content of said catalyst to a level of from about 1500 to about 6000 parts per million, preferably from about 2500 to about 4000 parts per million expressed as equivalent nickel, based on the weight of the catalyst, and said metals level is maintained on the catalyst throughout the operation by withdrawing high metals-containing catalyst and adding low metals-containing catalyst to the regenerator.
摘要翻译： 裂解石脑油的辛烷值可以通过在催化剂上保持某些临界浓度的金属而适当地通过将混合或加入含重金属的组分加入到瓦斯油中而在催化裂化装置中显着改善，而不显着降低石脑油的产率 饲料。 合适地，在裂化催化剂存在下，在高温下在裂化反应器（区域）中将瓦斯油原料裂解的催化裂化处理单元中，裂化催化剂通过燃烧焦炭再生在再生器（再生区）中 催化剂和催化剂在反应器和再生器之间循环，足够的含金属的重原料与瓦斯油进料间歇或连续地混合以沉积在所述催化剂上的金属，并将所述催化剂的金属含量提高到 水平为约1500至约6000份/百万份，优选约2500至约4000份/百万份表示为当量镍，基于催化剂的重量，并且所述金属水平在整个操作过程中保持在催化剂上，通过抽出高 含金属的催化剂和向再生器中加入含低金属的催化剂。
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公开(公告)号：US06565739B2
公开(公告)日：2003-05-20
申请号：US09811167
申请日：2001-03-16
申请人： William E. Winter
发明人： William E. Winter
IPC分类号： C10G5102
摘要： The invention relates to a two-stage catalytic cracking process for converting cycle oils to more valuable products. More particularly, the invention relates to a process that includes interstage hydroprocessing and a tailored catalyst mixture in a second catalytic cracking stage where the hydroprocessed cycle oil is re-cracked.
摘要翻译： 本发明涉及将循环油转化为更有价值的产物的两阶段催化裂化方法。 更具体地说，本发明涉及在加氢循环油再裂化的第二催化裂化阶段中包括级间加氢处理和定制的催化剂混合物的方法。
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10.发明授权FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds with rare earth promoted catalyst 失效FCC从高氢和低氮和芳香族饲料生产低排放燃料，用稀土促进催化剂
公开(公告)号：US5322619A
公开(公告)日：1994-06-21
申请号：US982917
申请日：1992-11-30
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is relatively low in nitrogen and aromatics and high in hydrogen content and the catalyst is a rare-earth promoted amorphous silica-alumina catalyst. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳族化合物相对较低，氢含量高，催化剂是稀土促进的无定形二氧化硅 - 氧化铝催化剂。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2+环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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