公开(公告)号：US5536434A

公开(公告)日：1996-07-16

申请号：US425292

申请日：1989-10-20

Applicant: Carlo Venturello ,  Claudio Cavallotti ,  Elena Bencini ,  Maria A. Sasso

Inventor： Carlo Venturello ,  Claudio Cavallotti ,  Elena Bencini ,  Maria A. Sasso

IPC: C07D207/40 ,  C07D207/404 ,  C07D207/44 ,  C07D207/444 ,  C07D207/452 ,  C07D209/48 ,  C11D3/395 ,  D06L3/02 ,  C07D487/04

CPC classification number: C07D207/404 ,  C07D207/452 ,  C07D209/48

Abstract: This invention relates to imido-derivative peroxycarboxylic acids having the formula I: ##STR1## wherein R and R.sub.1, which may be the same or different, represent hydrogen atoms, alkyl groups, or, taken together with the carbon atoms to which they are linked, give rise to a cyclic aliphatic ring, all of them being optionally substituted; the . . . symbol indicates a simple or an olefinic bond; R.sub.2 represents a hydrogen atom, an alkyl group, or an OH group, and n is an integer different from 0; the process for their preparation and their use as bleaching agents.

Abstract translation: 本发明涉及具有式I的亚氨基衍生物过氧羧酸：其中R和R 1可以相同或不同，表示氢原子，烷基或与其中的碳原子一起 它们连接，产生环状脂族环，它们全部被任选取代; 的。 。 。 符号表示简单或烯键; R2表示氢原子，烷基或OH基，n是不同于0的整数; 其制备方法及其作为漂白剂的用途。

公开(公告)号：US5294362A

公开(公告)日：1994-03-15

申请号：US45167

申请日：1993-04-13

Applicant: Carlo Venturello ,  Claudio Cavallotti

Inventor： Carlo Venturello ,  Claudio Cavallotti

IPC: C07C409/40 ,  C07D211/34 ,  C11D3/39 ,  C07C409/24 ,  C11D3/395 ,  D06L3/02

CPC classification number: C07C409/40 ,  C07D211/34 ,  C11D3/3945

Abstract: Amino-derivative (poly)peroxycarboxylic acids which have the formula: ##STR1## wherein the symbols have the following meanings: R, R.sub.1, and R.sub.2, which may be equal to or different from one another, represent hydrogen atoms, alkyl groups or groups selected from R, R.sub.1 and R.sub.2, which taken together with the nitrogen atom to which they are linked, give rise to an aliphatic heterocyclic group, all of them being optionally substituted;A represents a (cyclo) alkylene group, an arylene group which may also be condensed with cycloaliphatic groups, a cycloalkylene-alkylene or an alkylene-cycloalkylene group, an arylene-alkylene or an alkylene-arylene group, which may be condensed with cyclo-aliphatic groups, wherein said alkylene group may also be interrupted by --CONR.sub.3 groups, wherein R.sub.3 represents a hydrogen atom or an alkyl or aryl group;X- represents HSO.sub.4.sup.- or CH.sub.3 SO.sub.3.sup.- ;a process for their preparation; and their use as bleaching agents.

Abstract translation: 具有下式的氨基衍生物（聚）过氧羧酸：其中符号具有以下含义：R，R 1和R 2可以相同或不同，表示氢原子，烷基 与它们所连接的氮原子一起选自R，R 1和R 2的基团或基团产生脂族杂环基团，它们全部被任选取代; A表示（环）亚烷基，也可以与脂环族基团缩合的亚芳基，亚环烷基亚烷基或亚烷基 - 亚环烷基，亚芳基 - 亚烷基或亚烷基 - 亚芳基，其可以与环 - 脂族基团，其中所述亚烷基也可被-CONR 3基团中断，其中R 3表示氢原子或烷基或芳基; X-表示HSO4-或CH3SO3-; 其准备过程; 并将其用作漂白剂。

公开(公告)号：US5245075A

公开(公告)日：1993-09-14

申请号：US803721

申请日：1991-12-09

Applicant: Carlo Venturello ,  Claudio Cavallotti

Inventor： Carlo Venturello ,  Claudio Cavallotti

IPC: C07C409/40 ,  C07D211/34 ,  C11D3/39

CPC classification number: C07C409/40 ,  C07D211/34 ,  C11D3/3945

Abstract: Amino-derivative (poly)peroxycarboxylic acids which have the formula: ##STR1## wherein the symbols have the following meanings: R, R.sub.1, and R.sub.2, which may be equal to or different from one another, represent hydrogen atoms, alkyl groups or groups selected from R, R.sub.1 and R.sub.2, which taken together with the nitrogen atom to which they are linked, give rise to an aliphatic heterocyclic group, all of them being optionally substituted;A represents a (cyclo) alkylene group, an arylene group which may also be condensed with cycloaliphatic groups, a cycloalkylene-alkylene or an alkylene-cycloalkylene group, an arylene-alkylene or an alkylene-arylene group, which may be condensed with cyclo-aliphatic groups wherein said alkylene group may also be interrupted by --CONR.sub.3 groups, wherein R.sub.3 represents a hydrogen atom or an alkyl or aryl group;X.sup.- represents HSO.sub.4.sup.- or CH.sub.3 SO.sub.3.sup.- ; a process for their preparation; and their use as bleaching agents.

Abstract translation: 具有下式的氨基衍生物（聚）过氧羧酸：其中符号具有以下含义：R，R 1和R 2可以相同或不同，表示氢原子，烷基 与它们所连接的氮原子一起选自R，R 1和R 2的基团或基团产生脂族杂环基团，它们全部被任选取代; A表示（环）亚烷基，也可以与脂环族基团缩合的亚芳基，亚环烷基亚烷基或亚烷基 - 亚环烷基，亚芳基 - 亚烷基或亚烷基 - 亚芳基，其可以与环 - 其中所述亚烷基也可被-CONR 3基团中断的脂族基团，其中R 3表示氢原子或烷基或芳基; X-表示HSO4-或CH3SO3-; 其准备过程; 并将其用作漂白剂。

公开(公告)号：US5117049A

公开(公告)日：1992-05-26

申请号：US718915

申请日：1991-06-24

Applicant: Carlo Venturello ,  Claudio Cavallotti ,  Fiorella Achilli

Inventor： Carlo Venturello ,  Claudio Cavallotti ,  Fiorella Achilli

IPC: C11D3/395 ,  C07C67/00 ,  C07C407/00 ,  C07C409/24 ,  C07C409/40 ,  C07C409/42 ,  C11D3/39

CPC classification number: C11D3/3945 ,  C07C409/40

Abstract: Amino-derivative (poly)peroxycarboxylic acid monopersulfates having the formula: ##STR1## wherein the symbols have the following meanings: R, R.sub.1 and R.sub.2, which may be alike or different from one another, represent hydrogen atoms, alkyl groups which may be optionally substituted with the proviso that at least one of them is a hydrogen atom;n is an integer different from 0;said --(CH.sub.2).sub.n -- group may be also interrupted by CONR.sub.3 groups;and wherein R.sub.3 represents a hydrogen atom or an alkyl or aryl group. A process for their preparation and their use as bleaching agents are also disclosed.

公开(公告)号：US5423998A

公开(公告)日：1995-06-13

申请号：US45166

申请日：1993-04-13

Applicant: Carlo Venturello ,  Claudio Cavallotti

Inventor： Carlo Venturello ,  Claudio Cavallotti

IPC: C07C409/40 ,  C07D211/34 ,  C11D3/39 ,  C07D211/20 ,  C07D207/04 ,  C07D211/36 ,  C11D7/54

CPC classification number: C07C409/40 ,  C07D211/34 ,  C11D3/3945

Abstract: Amino-derivative (poly)peroxycarboxylic acids which have the formula: ##STR1## wherein the symbols have the following meanings: R, R.sub.1, and R.sub.2, which may be equal to or different from one another, represent hydrogen atoms, alkyl groups or groups selected from R, R.sub.1 and R.sub.2, which taken together with the nitrogen atom to which they are linked, give rise to an aliphatic heterocyclic group, all of them being optionally substituted;A represents a (cyclo)alkylene group, an arylene group which may also be condensed with cycloaliphatic groups, a cycloalkylene-alkylene or an alkylene-cycloalkylene group, an arylene-alkylene or an alkylene-arylene group, which may be condensed with cyclo-aliphatic groups, wherein said alkylene group may also be interrupted by --CONR.sub.3 groups, wherein R.sub.3 represents a hydrogen atom or an alkyl or aryl group;X.sup.- represents HSO.sub.4.sup.- or CH.sub.3 SO.sub.3.sup.- ; a process for their preparation; and their use as bleaching agents.

Abstract translation: 具有下式的氨基衍生物（聚）过氧羧酸：其中符号具有以下含义：R，R 1和R 2可以相同或不同，表示氢原子，烷基 与它们所连接的氮原子一起选自R，R 1和R 2的基团或基团产生脂族杂环基团，它们全部被任选取代; A表示（环）亚烷基，也可以与脂环族基团缩合的亚芳基，亚环烷基亚烷基或亚烷基 - 亚环烷基，亚芳基 - 亚烷基或亚烷基 - 亚芳基，其可以与环 - 脂族基团，其中所述亚烷基也可以被-CONR 3基团中断，其中R 3表示氢原子或烷基或芳基; X-表示HSO4-或CH3SO3-; 其准备过程; 并将其用作漂白剂。

公开(公告)号：US5268472A

公开(公告)日：1993-12-07

申请号：US956567

申请日：1992-10-05

Applicant: Carlo Venturello ,  Claudio Cavallotti ,  Fiorella Achilli

Inventor： Carlo Venturello ,  Claudio Cavallotti ,  Fiorella Achilli

IPC: C07D211/62 ,  C11D3/39 ,  C07D233/04 ,  C07D207/04 ,  C07D211/60

CPC classification number: C11D3/3945 ,  C07D211/62

Abstract: Nitrogen-containing heterocyclic (poly) peroxycarboxylic acid monopersulfates which have the formula: ##STR1## wherein the symbols have the following meanings: R represents a hydrogen atom or an alkyl, (hetero)cycloalkyl, (hetero)aryl, alkyl-aryl or arylalkyl group, wherein said groups are optionally substituted, or a carboxylic group or a peroxycarboxylic group, or any other substituents non-reactive in the presence of the peroxycarboxylic group;R.sup.1 represents an alkyl group > C.sub.5 ;n is a number selected from 0,1 and 2;m is a number selected from 1, 2 and 3;and the heterocyclic ring may be in its turn condensed with at least one further (hetero) aromatic or (hetero)cycloalkylic ring. The invention relates to a preparation process for, and to their use, as bleaching agents.

Abstract translation: 具有下式的含氮杂环（聚）过氧羧酸单过硫酸盐：其中符号具有下列含义：R表示氢原子或烷基，（杂）环烷基，（杂）芳基，烷基 - 芳基或芳烷基，其中所述基团任选被取代，或羧基或过氧羧基，或任何其它在过氧羧酸存在下不反应的取代基; R1表示烷基> C5; n是选自0,1和2的数字; m是选自1,2和3的数字; 并且杂环可以再次与至少一个另外的（杂）芳族或（杂）环烷基环稠合。 本发明涉及作为漂白剂的制备方法及其用途。

公开(公告)号：US5180516A

公开(公告)日：1993-01-19

申请号：US727022

申请日：1991-07-08

Applicant: Carlo Venturello ,  Claudio Cavallotti

Inventor： Carlo Venturello ,  Claudio Cavallotti

IPC: C07D211/60 ,  C07D211/62 ,  C11D3/39

CPC classification number: C11D3/3945 ,  C07D211/60 ,  C07D211/62

Abstract: Heterocyclic (poly)peroxycarboxylic acids having a N-amidic heteroatom, which have the formula:R--(CH.sub.2).sub.m --R' (I)wherein:R and R', alike or different from each other, represent hydrogen atoms or a group: ##STR1## with the proviso that at least one of R and R' shall be different from H, and wherein the other symbols have the following meaning:R" represents a hydrogen atom or any other substituent non-reactive in the presence of the active oxygen of the peroxycarboxylic group and/or under the preparation conditions;m represents a number between 1 to 12;n represents a number selected from 0, 1 and 2;p represents a number between 1 and 3;their process of preparation and their use as bleaching agents.

Abstract translation: 具有N-酰胺基杂原子的具有式R-（CH 2）m -R'（I）的杂环（多）过氧羧酸，其中：R和R'彼此相同或不同，表示氢原子或基团 ：，条件是R和R'中的至少一个不同于H，并且其中其他符号具有以下含义：R“表示氢原子或任何其它在无 过氧羧基的活性氧和/或在制备条件下; m表示1〜12的数; n表示选自0,1和2的数; p表示1和3之间的数字; 其制备方法及其作为漂白剂的用途。

公开(公告)号：US5688434A

公开(公告)日：1997-11-18

申请号：US593655

申请日：1996-01-29

Applicant: Carlo Venturello ,  Claudio Cavallotti ,  Fulvio Burzio

Inventor： Carlo Venturello ,  Claudio Cavallotti ,  Fulvio Burzio

IPC: C11D7/54 ,  C07C67/00 ,  C07C407/00 ,  C07C409/40 ,  C07D209/48 ,  C07D209/66 ,  C11D3/39 ,  C01B15/10 ,  C11D3/395 ,  D06L3/02

CPC classification number: C07D209/48 ,  C11D3/3945

Abstract: A process of bleaching using at least one imide-aromatic (poly)peroxyacid, having a formula: ##STR1## wherein A represents the residue of a benzene or napthalene ring optionally substituted by a COOH or COOOH group, the symbol or symbols R, which may be the same or different from each other, represent a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, an OH group, a COOH group, a COOOH group, a COOR' group, wherein R' represents a C.sub.1 -C.sub.5 alkyl group, or a substituted C.sub.1 -C.sub.5 alkyl group wherein the substituent is nitro, an OH group or a C.sub.1 -C.sub.5 alkoxy group, and n is an integer from 1 to 5.

Abstract translation: 使用至少一种具有下式的酰亚胺 - 芳族（聚）过氧酸的漂白方法：其中A表示任选被COOH或COOOH基团取代的苯或萘环的残基，符号或符号 R可以相同或不同，表示氢原子，C1-C5烷基，OH基，COOH基，COOOH基，COOR'基，其中R'表示C1-C5 烷基或取代的C1-C5烷基，其中取代基是硝基，OH基或C1-C5烷氧基，n是1至5的整数。

公开(公告)号：US5520844A

公开(公告)日：1996-05-28

申请号：US637479

申请日：1991-01-04

Applicant: Carlo Venturello ,  Claudio Cavallotti ,  Fulvio Burzio

Inventor： Carlo Venturello ,  Claudio Cavallotti ,  Fulvio Burzio

IPC: C11D7/54 ,  C07C67/00 ,  C07C407/00 ,  C07C409/40 ,  C07D209/48 ,  C07D209/66 ,  C11D3/39 ,  C01B15/10

CPC classification number: C07D209/48 ,  C11D3/3945

Abstract: Bleaching agents constituted by at least one imidearomatic (poly)peroxyacid, having the formula (I): ##STR1## wherein A represents a residue of a substituted or unsubstituted benzene or naphthalene ring, R is a hydrogen atom, a lower alkyl group, an OH group, a COOH group, a COOOH group or a COOR' group wherein R' represents a C.sub.1 -C.sub.5 alkyl group, and n is an integer from 1 to 5.

Abstract translation: 由至少一种具有式（I）的酰亚胺（poly）过氧酸构成的漂白剂：fa取代或未取代的苯或萘环，R是氢原子，低级烷基，OH基，COOH基，COOOH 基团或COOR'基团，其中R'表示C1-C5烷基，n为1至5的整数。

公开(公告)号：US5292447A

公开(公告)日：1994-03-08

申请号：US946227

申请日：1992-09-18

Applicant: Carlo Venturello ,  Claudio Cavallotti

Inventor： Carlo Venturello ,  Claudio Cavallotti

IPC: C07D211/60 ,  C07D211/62 ,  C11D3/39 ,  C07C409/06 ,  C11D3/28 ,  C11D3/395 ,  D06L3/02

CPC classification number: C11D3/3945 ,  C07D211/60 ,  C07D211/62

Abstract: Heterocyclic (poly)peroxycarboxylic acids having a N-amidic heteroatom, which have the formula:R--(CH.sub.2).sub.m --R' (I)wherein:R and R', alike or different from each other, represent hydrogen atoms or a group: ##STR1## with the proviso that at least one of R and R' shall be different from H, and wherein the other symbols have the following meaning:R" represents a hydrogen atom or any other substituent non-reactive in the presence of the active oxygen of the peroxycarboxylic group and/or under the preparation conditions;m represents a number between 1 to 12;n represents a number selected from 0, 1 and 2;p represents a number between 1 and 3; their process of preparation and their use as bleaching agents.

Abstract translation: 具有N-酰胺基杂原子的杂环（多）过氧羧酸，其具有下式：R-（CH 2）m -R'（I）其中：R和R'彼此相同或不同，表示氢原子或基团 ：（*化学结构*），条件是R和R'中的至少一个不同于H，并且其中其它符号具有以下含义：R“表示氢原子或任何其它取代基未反应的取代基 过氧羧酸基团的活性氧的存在和/或在制备条件下; m表示1至12之间的数; n表示选自0,1和2的数; p表示1至3之间的数;它们的 制剂及其作为漂白剂的用途。