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1.发明授权Catalyst anneal for durable stoichiometric shift corrected protective coating for oxygen sensors 有权用于氧传感器的耐用化学计量位移校正保护涂层的催化剂退火公开(公告)号：US08211281B2
公开(公告)日：2012-07-03
申请号：US11870206
申请日：2007-10-10
IPC分类号： G01N27/407
CPC分类号： G01N27/4075 , B01J23/40 , B01J23/42 , B01J37/0215 , B01J37/08
摘要： In one embodiment, a protective coating for an electrode of a sensor is described, the protective coating comprising an annealed catalyst, said annealed catalyst comprising at least one metal that has been subjected to thermal energy that is at least equivalent to or greater than that received from calcining the at least one metal for 24 hours at a temperature of 930 degrees C in air. In another embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to or less than that received from calcining the at least one metal for 24 hours at 1030 degrees C in air. In one exemplary embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to that received from calcining the at least one metal for 24 hours at 980 degrees C in air.
摘要翻译： 在一个实施方案中，描述了用于传感器电极的保护涂层，所述保护涂层包括退火催化剂，所述退火催化剂包括至少一种经受至少等于或大于接收的热能的金属 通过在空气中在930℃的温度下煅烧至少一种金属24小时。 在另一个实施方案中，退火的催化剂将包含至少一种已经经受等于或低于在1030℃下在空气中煅烧至少一种金属24小时的热能的金属。 在一个示例性实施方案中，退火的催化剂将包括至少一种已经经受与在空气中980摄氏度煅烧至少一种金属24小时所接受的热能相同的热能。
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2.发明申请CATALYST ANNEAL FOR DURABLE STOICHIOMETRIC SHIFT CORRECTED PROTECTIVE COATING FOR OXYGEN SENSORS 有权用于氧传感器的耐久性转换保护涂层的催化剂公开(公告)号：US20080135407A1
公开(公告)日：2008-06-12
申请号：US11870206
申请日：2007-10-10
CPC分类号： G01N27/4075 , B01J23/40 , B01J23/42 , B01J37/0215 , B01J37/08
摘要： In one embodiment, a protective coating for an electrode of a sensor is described, the protective coating comprising an annealed catalyst, said annealed catalyst comprising at least one metal that has been subjected to thermal energy that is at least equivalent to or greater than that received from calcining the at least one metal for 24 hours at a temperature of 930 degrees C. in air. In another embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to or less than that received from calcining the at least one metal for 24 hours at 1030 degrees C. in air. In one exemplary embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to that received from calcining the at least one metal for 24 hours at 980 degrees C. in air.
摘要翻译： 在一个实施方案中，描述了用于传感器电极的保护涂层，所述保护涂层包括退火催化剂，所述退火催化剂包括至少一种经受至少等于或大于接收的热能的金属 通过在空气中在930℃的温度下煅烧至少一种金属24小时。 在另一个实施方案中，退火的催化剂将包含至少一种已经经受等于或低于在1030℃下在空气中煅烧至少一种金属24小时的热能的金属。 在一个示例性实施方案中，退火的催化剂将包含至少一种已经经受与在空气中980摄氏度煅烧至少一种金属24小时所接受的热能相同的热能。
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公开(公告)号：US5472580A
公开(公告)日：1995-12-05
申请号：US257777
申请日：1994-06-09
IPC分类号： F01N11/00 , G01N27/406 , G01N27/407
CPC分类号： F01N11/00 , G01N27/4065 , G01N27/407 , G01N27/4075 , F02D2041/147 , Y02T10/47
摘要： Generally, the instant invention includes a method of using a sensor having an outer electrode including a gold-containing layer to diagnose the efficiency and useful life of a catalytic converter. The sensor having a gold-containing layer is positioned in an exhaust gas, combustion engine downstream from both the engine and the catalytic converter used to clean the exhaust. The sensor produces an voltage output responsive to the combustibles concentration in the exhaust gas. The voltage output from the sensor is measured and compared to a predetermined threshold correlated to a desirable combustibles concentrations in the exhaust stream or to a threshold output indicative of an inefficiently operating catalytic converter. An electrical output is then provided which is responsive to the comparison. The electrical output may be an indicator light, gauge or other devices for instructing the operator of a vehicle that the catalytic converter requires maintenance. The gold-containing layer of the sensor may be a gold alloy containing at least 28 percent by weight gold. The gold-containing layer may be the sole outer electrode of the sensor, or the gold-containing layer may be formed on a conventional platinum electrode of the sensor.
摘要翻译： 通常，本发明包括使用具有包含含金层的外部电极的传感器来诊断催化转化器的效率和使用寿命的方法。 具有含金层的传感器位于用于清洁排气的发动机和催化转化器下游的废气，内燃机中。 传感器响应于废气中的可燃物浓度产生电压输出。 测量来自传感器的电压输出，并将其与与排气流中期望的可燃物浓度相关联的预定阈值或指示低效操作的催化转化器的阈值输出进行比较。 然后提供响应于比较的电输出。 电输出可以是用于指示车辆的操作者的指示灯，表或其他装置，催化转化器需要维护。 传感器的含金层可以是含有至少28重量％金的金合金。 含金层可以是传感器的唯一外部电极，或者可以在传感器的常规铂电极上形成含金层。
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公开(公告)号：US07828955B2
公开(公告)日：2010-11-09
申请号：US11483448
申请日：2006-07-10
申请人： Da Yu Wang , Walter T. Symons , Robert J. Farhat , Carlos A. Valdes , Elizabeth M. Briggs , Kaius K. Polikarpus , Joachim Kupe
发明人： Da Yu Wang , Walter T. Symons , Robert J. Farhat , Carlos A. Valdes , Elizabeth M. Briggs , Kaius K. Polikarpus , Joachim Kupe
IPC分类号： G01N27/407
CPC分类号： G01N33/0054 , G01N27/4074 , Y02A50/246
摘要： One embodiment of an ammonia gas sensor includes: a reference electrode, an ammonia selective sensing electrode and an electrolyte disposed therebetween. The sensing electrode comprises the reaction product of a main material selected from the group consisting of vanadium, tungsten, molybdenum, vanadium oxides, tungsten oxides, molybdenum oxides, and combinations comprising at least one of the foregoing main materials, and an electrically conducting material selected from the group consisting of electrically conductive metals, electrically conductive metal oxides, and combinations comprising at least one of the foregoing.
摘要翻译： 氨气传感器的一个实施例包括：参比电极，氨选择性感测电极和设置在其间的电解质。 感测电极包括选自钒，钨，钼，氧化钒，氧化钨，氧化钼以及包含至少一种前述主要材料的组合的主要材料的反应产物和选择的导电材料 来自由导电金属，导电金属氧化物组成的组，以及包含前述的至少一种的组合。
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公开(公告)号：US06916384B2
公开(公告)日：2005-07-12
申请号：US10037900
申请日：2001-10-22
IPC分类号： G01N27/407 , B08B3/04
CPC分类号： G01N27/4071
摘要： A method of treating a gas sensor comprising: disposing the gas sensor in a basic agent solution comprising a basic agent selected from the group consisting of Group IA of the Periodic Table of Elements, Group IIA of the Periodic Table of Elements, and combinations comprising at least one of the foregoing metals, wherein the gas sensor comprises an electrolyte disposed between and in ionic communication with a first electrode and a second electrode; disposing the gas sensor in an acidic agent solution; wetting at least a portion of a porous protective layer of the gas sensor with an alkaline-carbonate solution; and heating the gas sensor.
摘要翻译： 一种处理气体传感器的方法，包括：将所述气体传感器设置在碱性试剂溶液中，所述碱性试剂溶液包含选自元素周期表第IA族，元素周期表IIA族的IA， 至少一种上述金属，其中所述气体传感器包括设置在第一电极和第二电极之间且与第一电极和第二电极离子连通的电解质; 将气体传感器置于酸性剂溶液中; 用碱 - 碳酸盐溶液润湿气体传感器的多孔保护层的至少一部分; 并加热气体传感器。
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公开(公告)号：US5492612A
公开(公告)日：1996-02-20
申请号：US310231
申请日：1994-09-21
IPC分类号： G01N27/407 , G01N27/26
CPC分类号： G01N27/4075
摘要： The invention includes the use of a pre-equilibration zone on an exhaust gas sensor to provide catalytic site to catalyze non-reacted components of the exhaust gas prior to the gas sample reaching the sensor's outer electrode. The pre-equilibration zone preferably includes a precious metal on the surface of a porous carrier. The invention also includes a method of making an exhaust sensor including a pre-equilibration zone, and a method of sampling an exhaust gas by passing the same through a pre-equilibration zone.
摘要翻译： 本发明包括在气体样品到达传感器的外部电极之前在废气传感器上使用预平衡区域以提供催化位点以催化废气的未反应组分。 预平衡区优选在多孔载体的表面上包括贵金属。 本发明还包括制造包括预平衡区的排气传感器的方法，以及通过使废气通过预平衡区域来对排气进行取样的方法。
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7.发明申请公开(公告)号：US20090260987A1
公开(公告)日：2009-10-22
申请号：US12105539
申请日：2008-04-18
申请人： Carlos A. Valdes , Jinping Zhang , Raymond L. Bloink , Fenglian Chang , Da Yu Wang , Walter T. Symons , Sheng Yao
发明人： Carlos A. Valdes , Jinping Zhang , Raymond L. Bloink , Fenglian Chang , Da Yu Wang , Walter T. Symons , Sheng Yao
IPC分类号： G01N27/26
CPC分类号： G01N27/4073
摘要： Disclosed herein is a method of making a gas sensor element, comprising calcining a NOx sensor electrode material at a NOx sensor electrode material calcination temperature of about 1200 to about 1600° C. to form a calcined NOx sensor electrode material, disposing the calcined NOx sensor electrode material on a substrate to form a substrate comprising a NOx sensor electrode, and firing the substrate comprising the NOx sensor electrode at a gas sensor element firing temperature to form a gas sensor element comprising a NOx sensor electrode. Also disclosed is a gas sensor comprising the gas sensor element.
摘要翻译： 本发明公开了一种制造气体传感器元件的方法，包括在约1200至约1600℃的NOx传感器电极材料煅烧温度下煅烧NOx传感器电极材料，以形成经煅烧的NOx传感器电极材料，将煅烧的NOx传感器 电极材料，以形成包括NOx传感器电极的基板，并且在气体传感器元件点火温度下烧制包含NOx传感器电极的基板，以形成包括NOx传感器电极的气体传感器元件。 还公开了一种包括气体传感器元件的气体传感器。
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公开(公告)号：US07074319B2
公开(公告)日：2006-07-11
申请号：US10734018
申请日：2003-12-11
申请人： Da Yu Wang , Walter T. Symons , Robert J. Farhat , Carlos A. Valdes , Elizabeth M. Briggs , Kaius K. Polikarpus , Joachim Kupe
发明人： Da Yu Wang , Walter T. Symons , Robert J. Farhat , Carlos A. Valdes , Elizabeth M. Briggs , Kaius K. Polikarpus , Joachim Kupe
IPC分类号： G01N27/407
CPC分类号： G01N33/0054 , G01N27/4074 , Y02A50/246
摘要： One embodiment of an ammonia gas sensor includes: a reference electrode, an ammonia selective sensing electrode and an electrolyte disposed therebetween. The sensing electrode comprises the reaction product of a main material selected from the group consisting of vanadium, tungsten, molybdenum, vanadium oxides, tungsten oxides, molybdenum oxides, and combinations comprising at least one of the foregoing main materials, and an electrically conducting material selected from the group consisting of electrically conductive metals, electrically conductive metal oxides, and combinations comprising at least one of the foregoing.
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公开(公告)号：US07069770B2
公开(公告)日：2006-07-04
申请号：US10909552
申请日：2004-08-02
IPC分类号： G01N9/00
CPC分类号： G01N33/0054 , Y02A50/246 , Y10T29/49002
摘要： A sensor element can comprise a co-fired heater section, a sensing section, and a third insulating layer disposed between the electrode portion and the temperature sensor. The heater section can comprise a heater, a shield, and a temperature sensor, with a first insulating layer disposed between the heater and the shield, and a second insulating layer disposed between the shield and the temperature sensor. The sensing section can comprise an electrode portion and a sensing portion, wherein the sensing portion is disposed on a side of the electrode portion opposite the heater section.
摘要翻译： 传感器元件可以包括共烧加热器部分，感测部分和设置在电极部分和温度传感器之间的第三绝缘层。 加热器部分可以包括加热器，屏蔽件和温度传感器，其中设置在加热器和屏蔽之间的第一绝缘层以及设置在屏蔽件和温度传感器之间的第二绝缘层。 感测部分可以包括电极部分和感测部分，其中感测部分设置在与加热器部分相对的电极部分的一侧。
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10.发明申请AMMONIA SENSOR ELEMENT, METHOD OF MAKING THEREOF, AND AMMONIA SENSOR DERIVED THEREFROM 审中-公开AMMONIA传感器元件，其制造方法和衍生自其的AMMONIA传感器公开(公告)号：US20090301878A1
公开(公告)日：2009-12-10
申请号：US12133962
申请日：2008-06-05
申请人： Da Yu Wang , Carlos A. Valdes , Walter T. Symons , Robert J. Farhat , Sheng Yao , Mustafa U. Unuvar , David K. Chen , David D. Cabush
发明人： Da Yu Wang , Carlos A. Valdes , Walter T. Symons , Robert J. Farhat , Sheng Yao , Mustafa U. Unuvar , David K. Chen , David D. Cabush
IPC分类号： G01N27/407 , B05D5/12
CPC分类号： G01N33/0054 , Y02A50/246
摘要： Disclosed herein is an ammonia sensor element comprising an ammonia selective sensor electrode, a reference electrode, a solid electrolyte in ionic communication with the ammonia selective sensor electrode and the reference electrode, and a protective layer disposed on the ammonia selective sensor electrode, comprising a porous portion comprising an ammonia-inert material. A method of making an ammonia gas sensor element comprises disposing an ammonia selective sensor electrode on and in ionic communication with a solid electrolyte, disposing a reference electrode on and in ionic communication with the solid electrolyte, and disposing a protective layer comprising a porous portion comprising an ammonia-inert material on the ammonia selective sensor electrode.
摘要翻译： 本文公开了一种氨传感器元件，其包括氨选择性传感器电极，参考电极，与氨选择性传感器电极和参考电极离子连通的固体电解质，以及设置在氨选择性传感器电极上的保护层，包括多孔 部分包括氨惰性材料。 一种制造氨气传感器元件的方法包括将氨选择性传感器电极设置在与固体电解质离子连通的位置上，将参考电极设置在固体电解质上并与其固体电解质离子连通，并且设置包括多孔部分的保护层，包括 氨选择性传感器电极上的氨惰性材料。
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