摘要:
There is provided a process for converting a silver-mercapto-s-triazine precipitate to a solid containing silver and a solution containing mercapto-s-triazine by contacting the silver-mercapto-s-triazine precipitate with one or more reducing agents. In preferred embodiments, at least one of the reducing agents has a redox potential more negative than about -0.9 V vs. Normal Hydrogen Electrode, NHE.
摘要:
A process for inhibiting the formation of an unwanted precipitate comprising [H.sub.2-n TMT]Na.sub.n [HNR.sub.3 ] during the precipitation of silver mercapto-s-triazine (AgTMT) from a silver containing photoprocessing solution, comprising the steps of:(a) providing a base solution;(b) providing a reagent solution containing mercapto-s-triazine (TMT), or a water soluble salt thereof;(c) mixing the TMT reagent solution with the photoprocessing solution; and(d) adding sufficent base to increase the pH of the mixture of the TMT reagent and photoprocessing solutions above the pH of the mixture before addition of base, and the base is mixed:(i) directly to the photoprocessing solution before mixing TMT reagent with the photoprocessing solution; or(ii) with the photoprocessing solution concurrently with TMT reagent; or(iii) immediately after the point TMT reagent begins mixing with the photoprocessing solution.
摘要:
A process for removing silver from a silver containing photoprocessing solution, including the steps of:a) mixing a mercapto-s-triazine, or a water soluble salt thereof, with the solution thereby causing formation of a mixture of i) precipitates and fines of silver mercapto-s-triazine and ii) the solution;b) mixing a copolymer flocculant with the mixture thereby causing flocculation and agglomeration of the silver TMT fines; wherein the copolymer i) consist of monomers selected from the group consisting of acryloyloxyethyl trimethylamine chloride and acrylamide and ii) has a reduced viscosity of 21 to 30 dL/g.
摘要:
A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.
摘要:
A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.
摘要:
A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.
摘要:
There is provided a method for removing silver from photoprocessing solutions containing hardening agents which comprises:a) adding a chelating agent to the photoprocessing solution in an amount sufficient to inhibit the precipitation of the high valent cations of the hardening agents;b) adding a base to adjust the pH of the photoprocessing solution to a value above 5.5; andc) adding a chemical precipitant for the silver contained in the photoprocessing solution;and optionally adding as a final component a flocculating agent which causes the precipitate to grow in size.
摘要:
A method of treating a solute in a liquid solution in order to render the solution more acceptable for discharge into the environment, comprises electrolyzing the solution with an anode comprising electrically conductive crystalline doped diamond to thereby oxidize the solute.
摘要:
A color developing composition is stable in the presence of calcium ion because of the presence of two specific types of polyphosphonic acid sequestering agents. The composition also comprises a color developing agent in free base form and an antioxidant for the color developing agent. The mixture of sequestering agents includes a polyaminopolyphosphonic acid and either a hydroxyalkylidenediphosphonic acid or morpholinomethanediphosphonic acid. The composition can be used to provide images in various color photographic silver halide materials.
摘要:
A method for making trialkali metal and triammonium salts of 2,4,6 trimercapto-s-triazine comprising the steps of:(a) forming a reaction mixture of an acetone solution of cyanuric chloride and an aqueous solution of sodium hydrosulfide hydrates;(b) stirring the mixture thereby forming 2,4,6-trimercapto-s-triazine;(c) acidifying the mixture to form a precipitate; and(d) dissolving the precipitate in a basic solution selected from alkali metal hydroxides and ammonium hydroxide thereby forming a trialkali metal or triammonium salt of 2,4,6 trimercapto-s-triazine.