公开(公告)号：US08795902B2

公开(公告)日：2014-08-05

申请号：US13386167

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562

CPC分类号： H01M10/052 ,  H01B1/06 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850≦x/(x+y+z)≦0.930, and 0.087≦y/(y+z)≦0.115; “a” is 0≦a≦1; “b” is 0≦b≦1; “δ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由以下通式表示的固体电解质材料：Lix（La1-aM1a）y（Ti1-bM2b）zOδ，其中“x”，“y”和“z”满足关系x + y + z = 1，0.850＆nlE; x /（x + y + z）＆nlE; 0.930和0.087＆nlE; y /（y + z）＆nlE; “a”为0＆nlE; a＆nlE; 1; “b”为0＆nlE; b＆nlE; 1; “δ”为0.8＆nlE;δ＆nlE; 1.2; “M1”是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; “M2”为选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US20120237835A1

公开(公告)日：2012-09-20

申请号：US13512649

申请日：2010-04-13

申请人： Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562

CPC分类号： H01M10/052 ,  H01B1/122 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0562 ,  H01M2300/0068 ,  H01M2300/0071 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a Li-La-Ti-O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3−x)−aM1a) (Ti1−bM2b)O3, wherein “x” is 0

摘要翻译： 本发明的主要目的在于提供在晶界上具有高Li离子传导性的Li-La-Ti-O基固体电解质材料。 本发明的目的是提供由通式Li 3 x（La（2/3-x）-aMa）（Ti1-bM2b）O3表示的固体电解质材料，其中“x”为0

公开(公告)号：US20130022878A1

公开(公告)日：2013-01-24

申请号：US13386167

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562

CPC分类号： H01M10/052 ,  H01B1/06 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850≦x/(x+y+z)≦0.930, and 0.087≦y/(y+z)≦0.115; “a” is 0≦a≦1; “b” is 0≦b≦1; “67 ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La1-aM1a）y（Ti1-bM2b）zOδ表示的固体电解质材料，其中x，y和z满足x + y + z = 1的关系 ，0.850＆nlE; x /（x + y + z）＆nlE; 0.930和0.087＆nlE; y /（y + z）＆nlE; 0.115; a是0＆nlE; a＆nlE; 1; b为0＆nlE; b＆nlE; 1; 67为0.8＆nlE;δ＆nlE; 1.2; M1是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; M2是选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US09300008B2

公开(公告)日：2016-03-29

申请号：US13512649

申请日：2010-04-13

申请人： Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562 ,  H01M10/052 ,  H01B1/12 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC分类号： H01M10/052 ,  H01B1/122 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0562 ,  H01M2300/0068 ,  H01M2300/0071 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a Li—La—Ti—O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3−x)−aM1a) (Ti1−bM2b)O3, wherein “x” is 0

摘要翻译： 本发明的主要目的在于提供在晶界上具有高Li离子传导性的Li-La-Ti-O基固体电解质材料。 本发明的目的是提供由通式Li 3 x（La（2/3-x）-aMa）（Ti1-bM2b）O3表示的固体电解质材料，其中“x”为0

公开(公告)号：US20130071757A1

公开(公告)日：2013-03-21

申请号：US13640413

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562

CPC分类号： H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0561 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, characterized in that “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.652≦x/(x+y+z)≦0.753, and 0.167≦y/(y+z)≦0.232; “a” is 0≦a≦1; “b” is 0≦b≦1; “δ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La1-aM1a）y（Ti1-bM2b）zOδ表示的固体电解质材料，其特征在于x，y和z满足x + y + z = 1，0.652＆nlE; x /（x + y + z）＆nlE; 0.753和0.167＆nlE; y /（y + z）＆nlE; 0.232; a是0＆nlE; a＆nlE; 1; b为0＆nlE; b＆nlE; 1; δ为0.8＆nlE;δ＆nlE; 1.2; M1是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; M2是选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US09196924B2

公开(公告)日：2015-11-24

申请号：US13640371

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562 ,  H01M10/0563 ,  H01B1/06 ,  H01M10/052

CPC分类号： H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0563 ,  Y02E60/122 ,  Y02P70/54

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La2−aM1a)(Ti3−bM2b)O9+δ, characterized in that “x” is 0

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La2-aM1a）（Ti3-bM2b）O9 +δ表示的固体电解质材料，其特征在于“x”为0

公开(公告)号：US08945779B2

公开(公告)日：2015-02-03

申请号：US13640413

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0561 ,  H01M10/0525

CPC分类号： H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0561 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, characterized in that “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.652≦x/(x+y+z)≦0.753, and 0.167≦y/(y+z)≦0.232; “a” is 0≦a≦1; “b” is 0≦b≦1; “δ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La1-aM1a）y（Ti1-bM2b）zOδ表示的固体电解质材料，其特征在于“x”，“y”和“z”满足关系 x + y + z = 1，0.652＆nlE; x /（x + y + z）＆nlE; 0.753和0.167＆lt; lE; y /（y + z）＆nlE; 0.232; “a”为0＆nlE; a＆nlE; 1; “b”为0＆nlE; b＆nlE; 1; “δ”为0.8＆nlE;δ＆nlE; 1.2; “M1”是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; “M2”为选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US20130071756A1

公开(公告)日：2013-03-21

申请号：US13640371

申请日：2010-04-13

申请人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

发明人： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC分类号： H01M10/0562

CPC分类号： H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0563 ,  Y02E60/122 ,  Y02P70/54

摘要： A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La2-aM1a)(Ti3-bM2b)O9+δ, characterized in that “x” is 0

摘要翻译： 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La2-aM1a）（Ti3-bM2b）O9 +δ表示的固体电解质材料，其特征在于x为0

公开(公告)号：US20140287160A1

公开(公告)日：2014-09-25

申请号：US14117823

申请日：2012-07-20

申请人： Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

发明人： Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

IPC分类号： C01B25/30 ,  C01B21/20 ,  C01B25/45

CPC分类号： C01B25/30 ,  C01B21/20 ,  C01B25/45 ,  C23C14/06 ,  C23C14/24 ,  C30B23/066 ,  C30B23/08 ,  H01M4/5825 ,  H01M10/052

摘要： The present invention provides a vapour deposition process for the preparation of a phosphate compound, wherein the process comprises providing each component element of the phosphate compound as a vapour, and co-depositing the component element vapours on a common substrate, wherein the component elements react on the substrate to form the phosphate compound.

摘要翻译： 本发明提供了一种用于制备磷酸盐化合物的气相沉积方法，其中该方法包括提供磷酸盐化合物的每个组分元素作为蒸气，并将组分元素蒸气共沉积在共同的基底上，其中组分元素反应 在底物上形成磷酸盐化合物。

公开(公告)号：US09533886B2

公开(公告)日：2017-01-03

申请号：US14117823

申请日：2012-07-20

申请人： Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

发明人： Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

IPC分类号： C23C14/08 ,  C01B25/30 ,  C23C14/06 ,  C23C14/24 ,  C30B23/06 ,  C30B23/08 ,  H01M4/58 ,  C01B21/20 ,  C01B25/45 ,  H01M10/052

CPC分类号： C01B25/30 ,  C01B21/20 ,  C01B25/45 ,  C23C14/06 ,  C23C14/24 ,  C30B23/066 ,  C30B23/08 ,  H01M4/5825 ,  H01M10/052

摘要： The present invention provides a vapour deposition process for the preparation of a phosphate compound, wherein the process comprises providing each component element of the phosphate compound as a vapour, and co-depositing the component element vapours on a common substrate, wherein the component elements react on the substrate to form the phosphate compound.

摘要翻译： 本发明提供了一种用于制备磷酸盐化合物的气相沉积方法，其中该方法包括提供磷酸盐化合物的每个组分元素作为蒸气，并将组分元素蒸气共沉积在共同的基底上，其中组分元素反应 在底物上形成磷酸盐化合物。