公开(公告)号：US20210354118A1

公开(公告)日：2021-11-18

申请号：US17390123

申请日：2021-07-30

Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING

Inventor： Liang ZHAO ,  Jinsen GAO ,  Butian XIA ,  Lixia DONG ,  Jingye CHEN ,  Yuhao ZHANG ,  Chunming XU

IPC: B01J29/40 ,  B01J37/04 ,  B01J21/04 ,  B01J37/02 ,  B01J37/08 ,  C10G45/12 ,  B01J29/70

Abstract: Provided are an in situ bifunctional catalyst for deep desulfurization and increasing octane number of gasoline, and its preparation method and application. The bifunctional catalyst includes a modified catalyst carrier and a loaded active metal, where the modified catalyst carrier is a composite carrier prepared through mixing γ-Al2O3 and an acidic molecular sieve by a binder and calcining. When the bifunctional catalyst provided by the present application is used for hydrodesulfurization of gasolines, deep desulfurization, olefin reduction and octane number preservation can be realized simultaneously, thereby obtaining a high-quality oil product.

公开(公告)号：US20240109056A1

公开(公告)日：2024-04-04

申请号：US18156979

申请日：2023-01-19

Applicant: China University of Petroleum - Beijing

Inventor： Tao ZHENG ,  Rui ZHANG ,  Zhichang LIU ,  Haiyan LIU ,  Xianghai MENG ,  Chunming XU

IPC: B01J27/24 ,  B01J23/10 ,  B01J27/10 ,  B01J37/04

CPC classification number: B01J27/24 ,  B01J23/10 ,  B01J27/10 ,  B01J37/04

Abstract: The present disclosure provides a composite ionic liquid and a preparation method and a use thereof. A first aspect of the present disclosure provides a preparation method of a composite ionic liquid, where an ammonium salt, a first metal salt, a second metal salt, and a third metal salt are sequentially added into a reactor for performing a reaction under different conditions, and the composite ionic liquid is obtained after the reaction is finished. The composite ionic liquid prepared by the method may be used as a catalyst to catalyze an alkylation reaction of isoparaffin with C4 olefin to obtain alkylated oil, which has the advantages of high catalytic activity, long catalytic life, low consumption, and better distribution of the resulting alkylated oil, etc, and thereby significantly reducing the production costs and improving the quality of the resulted alkylated oil.

公开(公告)号：US20210354119A1

公开(公告)日：2021-11-18

申请号：US17390820

申请日：2021-07-30

Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING

Inventor： Liang ZHAO ,  Jinsen GAO ,  Butian XIA ,  Lixia DONG ,  Jingye CHEN ,  Yuhao ZHANG ,  Chunming XU

IPC: B01J29/40 ,  B01J23/10 ,  B01J21/04 ,  B01J35/00 ,  B01J37/04 ,  B01J37/08 ,  B01J37/02 ,  C10G45/12

Abstract: Provided are a bifunctional catalyst for deep desulfurization and gasoline quality improvement and a preparation method therefore and a use thereof. The bifunctional catalyst includes a modified catalyst and a loaded active metal, where the modified catalyst carrier is a γ-Al2O3 modified with a rare earth element, or the modified catalyst carrier is a composite carrier prepared by mixing and calcinating γ-Al2O3 and an acid molecular sieve through a binder, and then modifying with the rare earth element. The bifunctional catalyst for deep desulfurization and gasoline quality improvement can achieve deep desulfurization of high-sulfur fluid catalytic cracking gasoline, and ensure no significant loss of octane number under relatively mild conditions.

公开(公告)号：US20240052247A1

公开(公告)日：2024-02-15

申请号：US18382750

申请日：2023-10-23

Applicant: China University of Petroleum-Beijing ,  Beijing Carbon Zero Hydrogen Electric Technology Co., Ltd.

Inventor： Hongjun ZHOU ,  Quangui WU ,  Hongmei SONG ,  Fengyun BI ,  Enze ZHOU ,  Guanglin ZHOU ,  Chunming XU

IPC: C10G9/24 ,  C07C4/04

CPC classification number: C10G9/24 ,  C07C4/04

Abstract: The present invention provides a method of steam cracking using electricity to supply energy. This method is to provide energy for steam cracking reaction of a cracking raw material by electromagnetic induction with electricity; the cracking raw material comprises one or more of naphtha, cycloalkane and cycloolefin; wherein the cycloalkane is a C4-C8 cycloalkane, and the cycloolefin is a C4-C8 cycloolefin. The present invention utilizes electricity to provide energy for the steam cracking reaction through an electromagnetic coil, which is a new use of electricity and solve the current problem of excess electricity. Moreover, utilizing the electromagnetic coil to provide power can make the heat distribution in the furnace tube of the cracking furnace more uniform, and it is easier to control the reaction temperature and the progress of the reaction.

公开(公告)号：US20240017232A1

公开(公告)日：2024-01-18

申请号：US18354111

申请日：2023-07-18

Applicant: China University of Petroleum-Beijing

Inventor： Mengxi LIU ,  Chunxi LU ,  Chunming XU ,  Guiyuan JIANG ,  Jian LI

IPC: B01J8/26 ,  B01J8/24 ,  B01J8/00 ,  B01D45/16 ,  B01D45/04 ,  B01D3/38

CPC classification number: B01J8/26 ,  B01J8/24 ,  B01J8/0015 ,  B01J8/005 ,  B01D45/16 ,  B01D45/04 ,  B01D3/38 ,  B01J2208/00769 ,  B01J2208/00893

Abstract: A coupled fluidized beds reactor-regenerator apparatus for catalytic dehydrogenation of propane. The fluidized bed reactor comprising a raw material delivery system, a pre-rising system, a reaction system, a gas-solid separation system and an internal circulation pipeline, the reaction system includes a conical riser and a turbulent bed reactor; the raw material delivery system, the pre-rising system, the conical riser, the turbulent bed reactor, and the gas-solid separation system are consecutively connected in this order from bottom to top; the bottom outlet of the gas-solid separation system is connected to the inlet of the internal circulation pipeline, and the outlet of the internal circulation pipeline is connected to the raw material delivery system and/or the reaction system. The coupled fluidized beds reactor-regenerator apparatus for catalytic dehydrogenation of propane includes the fluidized bed reactor, a gas-solid airlift loop regenerator, a recirculation inclined pipe and a regeneration inclined pipe.

公开(公告)号：US20170320047A1

公开(公告)日：2017-11-09

申请号：US15520484

申请日：2015-10-22

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  CHINA UNIVERSITY OF PETROLEUM (BEIJING)

Inventor： Rui ZHANG ,  Zhichang LIU ,  Xianghai MENG ,  Chunming XU

IPC: B01J31/02 ,  B01J31/30 ,  C07C2/60

CPC classification number: B01J31/0279 ,  B01J31/0278 ,  B01J31/30 ,  B01J2231/32 ,  B01J2531/007 ,  C07C2/60 ,  C07C2527/122 ,  C07C2527/126 ,  C07C2531/02 ,  C10G29/205 ,  C10G2300/1081 ,  C07C9/21

Abstract: The present invention provides a process to prepare a composite ionic liquid, the process at least comprising the steps: (a) mixing an ammonium salt and a solid aluminium salt to obtain a first mixture; (b) stirring under heating the first mixture of step (a); (c) adding to the first mixture of step (b) one or more solid metal salts to obtain a second mixture, wherein the metal salts are selected from halides, sulfates, or nitrates of aluminium, gallium, copper, iron, zinc, nickel, cobalt, molybdenum and platinum; (d) stirring under heating the second mixture of step (c); (e) adding to the second mixture of step (d) a hydrocarbon to obtain a third mixture; (f) stirring under heating the third mixture of step (e) until the solids of the aluminium salt of step (a), and the solids of the metal salts of step (c) disappear and the mixture is converted into a composite ionic liquid; and (g) cooling the composite ionic liquid of step (f).