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    Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
    2.
    发明授权
    Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer 失效
    用于制备高分子量烯烃聚合物的双核茂金属催化剂

    公开(公告)号：US06228790B1

    公开(公告)日：2001-05-08

    申请号：US09107074

    申请日：1998-06-29

    申请人： Ching Ting ,  Sung-Song Hua ,  Jing-Cherng Tsai ,  Bor-Ping Wang

    发明人： Ching Ting ,  Sung-Song Hua ,  Jing-Cherng Tsai ,  Bor-Ping Wang

    IPC分类号： B01J3100

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F210/18 ,  C08F2410/03 ,  C08F4/65925 ,  C08F2500/01 ,  C08F2500/03 ,  C08F210/14 ,  C08F210/06 ,  C08F2500/25

    摘要： A novel dinuclear metallocene complex is disclosed, which is represented by the following formula (I): wherein M1 and M2 are the same or different and are independently selected from the group consisting of Group IIIB, Group IVB and Group VB transition metals; each X is the same or different and is indepedently an anionic ligand with −1 valence, which is selected from the group consisting H, C1-20 hydrocarbyl, halogen, C1-20 alkoxy, C1-20 aryloxy, NH2, NHR11, NR11R12, —(C═O)NH2, —(C═O)NHR13, and —(C═O)NR13R14, wherein R11, R12, R13 and R14 are C1-20 alkyl; i is an integer from 1 to 3; j is an integer from 1 to 3, R1, R2, R3, R4, R5, R6, R7, and R8 are the same or different and are independently H, a C1-20 linear, branched or cyclic hydrocarbyl group, or a C2-4 cyclic hydrocarbylene group which forms a C4-6 fused ring system; Y1 and Y2 are the same or different and each is an electron-donating group independently selected from a Group 15 or Group 16 element; R9 and R10 are the same or different and each is a divalent radical selected from (—C(R15)2—)p, (—Z(R15)2—)p, or (—Z(R15)2—C(R15)2—)p, Z being silicon, germanium, or tin, R15 being C1-6 alkyl, p being an integer from 1 to 4; R16 is a divalent unsubstituted or alkyl-substituted cyclic alkylene group; and each R17 is independently a C1-20 linear, branched or cyclic hydrocarbyl group. By using the dinuclear metallocene complex as the catalyst, a high molecular weight olefin polymer can be obtained.

    摘要翻译： 公开了一种新颖的双核茂金属络合物，其由下式（I）表示：其中M1和M2相同或不同并且独立地选自IIIB族，IVB族和VB族过渡金属; 每个X相同或不同，并且独立地是具有-1价的阴离子配体，其选自H，C 1-20烃基，卤素，C 1-20烷氧基，C 1-20芳氧基，NH 2，NHR 11，NR 11 R 12， - （C = O）NH 2， - （C = O）NHR 13和 - （C = O）NR 13 R 14，其中R 11，R 12，R 13和R 14为C 1-20烷基; 我是1到3的整数; j为1〜3的整数，R1，R2，R3，R4，R5，R6，R7和R8相同或不同，独立地为H，C1-20直链，支链或环状烃基或C2 -4环亚烃基，形成C4-6稠环体系; Y1和Y2相同或不同，各自为独立地选自第15族或第16族元素的给电子基团; R 9和R 10相同或不同，并且各自为选自（-C（R 15）2-）p，（-Z（R 15）2-）p或（-Z（R 15）2 -C（R 15） ）2-）p，Z为硅，锗或锡，R 15为C 1-6烷基，p为1至4的整数; R16是二价未取代或烷基取代的环状亚烷基; 并且每个R 17独立地为C 1-20直链，支链或环状烃基。 通过使用双核茂金属络合物作为催化剂，可以得到高分子量的烯烃聚合物。