摘要:
A metallocene complex in which the cyclopentadienyl group is substituted with an alkanediyl silyl group. The yield of the metallocene complex is high, and it can be used as the catalyst for preparing high molecular weight olefin polymers.
摘要:
A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Grcup IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1 or ER.sup.1 R.sup.2, where E is a Group VA or VIA element, and R.sup.1 and R.sup.2, which can be the same or different from each other, are C.sub.1 to C.sub.6 alkyl group or substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
摘要翻译:公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(C5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,Grcup IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1或ER1R2表示的卤素原子或配体,其中E是VA族或VIA族,R1和R2可以 彼此相同或不同,为C1至C6烷基或取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
摘要:
A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (CR.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
摘要翻译:公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(CR5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1表示的卤素原子或配体,其中E是VA族或VIA族,R1是C1-C6烷基, 芳基或卤素取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
摘要:
A catalyst composition for preparing high-syndiotacticity polystyrene polymers which comprises: (a) a titanium complex represented by the following formula of TiR′1R′2R′3R′4 or TiR′1R′2R′3, wherein R′1, R′2, R′3, and R′4 are, independently, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrogen atom, or a halogen atom; (b) a cyclopentadienyl complex represented by the following formula: wherein R1-R13 are, independently, alkyl group, aryl group, silyl group, halogen atom, or hydrogen atom; Ra and Rb are, independently, alkyl group, aryl group, alkoxy, aryloxy group, cyclopentadienyl group, hydrogen atom, or halogen atom; and Xa is a Group IIA element and Xb is a Group IIIA element.
摘要:
A catalyst composition is disclosed for catalyzing the polymerization and copolymerization reactions of ethylene monomers, with or without another olefin monomer. The catalyst composition comprises a metallocene compound represented by the the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY or the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopendadienyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrotrispyrazolyl borate or hydrotris-3,5-dimethyl; (c) M is Group IIIB, Group IVB, or Group VB transitional metal; (d) X is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; (e) Y, which can the same as or different from X, is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; and (f) A.sup.- is non-coordinated or loosely coordinated bulky anion. Examples of the (C.sub.5 R.sub.n H.sub.5-n)(L)MXY and (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- metallocene compounds are represented by the following formulas: ##STR1## respectively.
摘要:
The invention discloses a photovoltaic cell with a high photocurrent. The photovoltaic cell comprises a first electrode, a second electrode, a photoactive layer between the first and second electrodes, and a polar organic layer between the photoactive layer and at least one of the first and second electrodes.
摘要:
A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
摘要翻译:公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(C5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1表示的卤素原子或配体,其中E是VA族或VIA族,R1是C1-C6烷基, 芳基或卤素取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
摘要:
The invention discloses soluble polythiophene derivatives containing highly coplanar repeating units. The coplanar characteristic of side chain conjugated thiophene units improves the degree of the intramolecular conjugation and intermolecular π-π interaction. The polythiophene derivative exhibits good carrier mobility and is suitable for use in photo-electronic device such as organic thin film transistors (OTFT), organic light-emitting diodes (OLEDs), and organic solar cells (OSCs).
摘要:
An active layer utilized in a solar cell. The active layer includes a polymer film having a plurality of hollow column array structures formed therein and a semiconductor material filled in the hollow column structures. The invention also provides a method of fabricating the active layer utilized in a solar cell.