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公开(公告)号：US5409783A
公开(公告)日：1995-04-25
申请号：US201292
申请日：1994-02-24
CPC分类号： H05B33/14 , C09K11/06 , Y10S428/917
摘要： Disclosed is a red-emitting organic electroluminescent device comprising in sequence an anode, an organic hole injecting and transporting zone, a doped luminescent zone, an electron transport zone and a cathode, characterized in that said doped luminescent zone is comprised of a fluorescent phthalocyanine compound capable of emitting a wavelength in the range of 660 to 780 nm.
摘要翻译： 公开了一种红色发光有机电致发光器件，其顺序包括阳极，有机空穴注入和传输区，掺杂发光区，电子传输区和阴极，其特征在于所述掺杂发光区由荧光酞菁化合物 能够发射660〜780nm的波长。
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2.发明授权Cascaded organic electroluminescent devices with improved voltage stability 有权具有改善的电压稳定性的级联有机电致发光器件公开(公告)号：US06717358B1
公开(公告)日：2004-04-06
申请号：US10267252
申请日：2002-10-09
IPC分类号： H01J162
CPC分类号： H01L51/5278 , H01L51/5052 , Y10S428/917
摘要： A cascaded organic electroluminescent device with connecting units having improved voltage stability is disclosed. The device comprises an anode, a cathode, a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer, and a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer, an interfacial layer, and a p-type doped organic layer, and wherein the interfacial layer prevents diffusion or reaction between the n-type doped organic layer and the p-type doped organic layer.
摘要翻译： 公开了具有改进的电压稳定性的具有连接单元的级联有机电致发光器件。 该装置包括阳极，阴极，设置在阳极和阴极之间的多个有机电致发光单元，其中有机电致发光单元至少包括空穴传输层和电子传输层，以及连接单元， 相邻的有机电致发光单元，其中所述连接单元依次包括n型掺杂的有机层，界面层和p型掺杂的有机层，并且其中所述界面层防止n型掺杂的扩散或反应 有机层和p型掺杂有机层。
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3.发明授权Cascaded organic electroluminescent device having connecting units with N-type and P-type organic layers 有权具有N型和P型有机层的连接单元的级联有机电致发光器件公开(公告)号：US06936961B2
公开(公告)日：2005-08-30
申请号：US10437195
申请日：2003-05-13
CPC分类号： H01L51/5278
摘要： A cascaded organic electroluminescent device includes an anode and a cathode. The device also includes a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer, an electron-transporting layer, and an electroluminescent zone formed between the hole-transporting layer and the electron-transporting layer wherein the physical spacing between adjacent electroluminescent zones is more than 90 nm; and a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer and a p-type doped organic layer forming a transparent p-n junction structure wherein the resistivity of each of the doped layers is higher than 10 Ω-cm.
摘要翻译： 级联的有机电致发光器件包括阳极和阴极。 该装置还包括设置在阳极和阴极之间的多个有机电致发光单元，其中有机电致发光单元至少包括空穴传输层，电子传输层和形成在空穴传输层和 其中相邻电致发光区之间的物理间隔大于90nm的电子传输层; 以及设置在每个相邻的有机电致发光单元之间的连接单元，其中所述连接单元依次包括n型掺杂有机层和形成透明pn结结构的p型掺杂有机层，其中每个掺杂的有机电致发光单元的电阻率 层高于10Ω·cm。
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公开(公告)号：US5904961A
公开(公告)日：1999-05-18
申请号：US788537
申请日：1997-01-24
IPC分类号： H05B33/10 , B05D1/28 , B05D7/24 , C09K11/02 , H01L51/40 , H01L51/50 , H01L51/56 , H05B33/12 , B05D5/12 , B05D3/00
CPC分类号： H01L51/56 , B05D1/286 , B05D1/60 , H01L51/0008 , H01L51/0013
摘要： A method of depositing organic layers on a substrate in organic light emitting devices is disclosed. The method uses a donor support which is coated with a transferable coating of an organic donor material selected as one of a plurality of organic materials useful in an organic light emitting device. The donor coating is positioned in transferable relationship with the substrate in an environment of reduced pressure. The donor support is heated to cause the transferable coating of organic donor material to transfer to a position on or over the substrate and to form a layer of the organic material on the substrate.
摘要翻译： 公开了一种在有机发光器件中的衬底上沉积有机层的方法。 该方法使用涂覆有可选择的有机供体材料的涂层的供体载体，其被选择为有机发光装置中有用的多种有机材料之一。 供体涂层在减压环境中与基底定位成可转移的关系。 供体载体被加热以使有机供体材料的可转移涂层转移到基底上或上方的位置，并在基底上形成有机材料层。
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公开(公告)号：US06781149B1
公开(公告)日：2004-08-24
申请号：US10366835
申请日：2003-02-14
IPC分类号： H01L5100
CPC分类号： H01L51/50 , H01L51/0051 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0081 , H01L51/0084 , H01L51/0085 , H01L51/0089 , H01L51/5237
摘要： An organic light-emitting device with improved performance including an anode formed over a substrate; a light-emitting layer formed over the anode for producing light in response to hole-electron recombination; and a performance-enhancing layer formed over the light-emitting layer including one or more chemical reducing materials selected to improve the performance of the organic light-emitting device. The device also includes an electron-transporting layer formed over the performance-enhancing layer, and a cathode formed over the electron-transporting layer.
摘要翻译： 一种具有改进性能的有机发光器件，包括形成在衬底上的阳极; 在阳极上形成的发光层，用于响应于空穴 - 电子复合而产生光; 以及形成在包含一种或多种选择用于改善有机发光器件的性能的化学还原材料的发光层上的性能增强层。 该器件还包括形成在性能增强层上的电子传输层和形成在电子传输层上的阴极。
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公开(公告)号：US07560862B2
公开(公告)日：2009-07-14
申请号：US10970928
申请日：2004-10-22
CPC分类号： H01L51/5036 , H01L51/0052 , H01L51/0053 , H01L51/0054 , H01L51/0081 , H01L51/5278 , Y10S428/917
摘要： A tandem white OLED includes an anode; a cathode; at least one broadband electroluminescent unit disposed between the anode and the cathode, wherein the broadband electroluminescent unit includes at least one light-emitting layer and produces at least one color component having an intensity less than desired; at least one color-compensating electroluminescent unit disposed between the anode and the cathode, wherein the color-compensating electroluminescent unit is selected to produce the at least one color component and to increase the color component intensity; and an intermediate connector disposed between each adjacent electroluminescent unit, wherein the intermediate connector has no direct connection to an external power source.
摘要翻译： 串联白色OLED包括阳极; 阴极 设置在所述阳极和所述阴极之间的至少一个宽带电致发光单元，其中所述宽带电致发光单元包括至少一个发光层，并且产生至少一个具有小于期望强度的颜色分量; 设置在阳极和阴极之间的至少一个颜色补偿电致发光单元，其中选择颜色补偿电致发光单元以产生至少一种颜色分量并增加颜色分量强度; 以及设置在每个相邻的电致发光单元之间的中间连接器，其中中间连接器不直接连接到外部电源。
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公开(公告)号：US07075231B1
公开(公告)日：2006-07-11
申请号：US11028033
申请日：2005-01-03
CPC分类号： H01L51/5278 , C09K2211/1029 , C09K2211/1037 , H01L51/002 , H01L51/0059 , H01L51/0073 , H01L51/0081 , H01L51/5052 , H01L2251/558
摘要： A tandem OLED includes an anode, a cathode, and at least two electroluminescent units disposed between the anode and the cathode, wherein each of the electroluminescent units includes at least one hole-injecting layer, one hole-transporting layer, one organic light-emitting layer, one electron-transporting layer, and one electron-injecting layer. The OLED also includes at least one intermediate connector, wherein each of the intermediate connectors includes at least one layer, and wherein each of the intermediate connectors is disposed between electroluminescent units, wherein the thickness of each layer in each of the electroluminescent units and the intermediate connectors is selected to satisfy the test condition that the voltage drop from the anode to the cathode is less than 4.0 V×N (the number of electroluminescent units) at 20 mA/cm2.
摘要翻译： 串联OLED包括阳极，阴极和设置在阳极和阴极之间的至少两个电致发光单元，其中每个电致发光单元包括至少一个空穴注入层，一个空穴传输层，一个有机发光 层，一个电子传输层和一个电子注入层。 OLED还包括至少一个中间连接器，其中每个中间连接器包括至少一个层，并且其中每个中间连接器设置在电致发光单元之间，其中每个电致发光单元和中间层中的每个层的厚度 选择连接器以满足在20mA / cm 2时从阳极到阴极的电压降小于4.0VVN（电致发光单元的数量）的测试条件。
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公开(公告)号：US07494722B2
公开(公告)日：2009-02-24
申请号：US11064386
申请日：2005-02-23
申请人： Liang-Sheng Liao , Wojciech K. Slusarek , Tukaram K. Hatwar , Michele L. Ricks , Dustin L. Comfort
发明人： Liang-Sheng Liao , Wojciech K. Slusarek , Tukaram K. Hatwar , Michele L. Ricks , Dustin L. Comfort
IPC分类号： H01L51/54 , H01L51/52 , C07D241/36
CPC分类号： H01L51/5278 , H01L51/0051 , H01L51/0059 , H01L51/5052 , Y10S428/917
摘要： A tandem OLED includes an anode and a cathode. The OLED also includes at least two electroluminescent units disposed between the anode and the cathode, wherein each of the electroluminescent units includes at least one hole-transporting layer and one organic light-emitting layer. An intermediate connector is disposed between adjacent electroluminescent units, wherein the intermediate connector includes an n-doped organic layer and an electron-accepting layer, the electron-accepting layer being disposed closer to the cathode than the n-doped organic layer, and wherein the electron-accepting layer includes one or more organic materials, each having a reduction potential greater than −0.5 V vs. a Saturated Calomel Electrode, and wherein the one or more organic materials constitute more than 50% by volume of the electron-accepting layer.
摘要翻译： 串联OLED包括阳极和阴极。 OLED还包括设置在阳极和阴极之间的至少两个电致发光单元，其中每个电致发光单元包括至少一个空穴传输层和一个有机发光层。 中间连接器设置在相邻的电致发光单元之间，其中中间连接器包括n掺杂有机层和电子接受层，该电子接受层被设置为比n掺杂有机层更靠近阴极，并且其中 电子接受层包括一种或多种有机材料，每种有机材料相对于饱和碳酸钙电极具有大于-0.5V的还原电位，并且其中所述一种或多种有机材料占电子接受层的体积的50体积％以上。
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公开(公告)号：US07629741B2
公开(公告)日：2009-12-08
申请号：US11124300
申请日：2005-05-06
申请人： Liang-Sheng Liao , Wojciech K. Slusarek , Michele L. Ricks , Ralph H. Young , Dustin L. Comfort
发明人： Liang-Sheng Liao , Wojciech K. Slusarek , Michele L. Ricks , Ralph H. Young , Dustin L. Comfort
IPC分类号： H01L51/54
CPC分类号： H01L51/0051 , H01L51/0053 , H01L51/0067 , H01L51/0071 , H01L51/5052 , H01L51/5092 , Y10S428/917 , Y10T428/24942
摘要： An OLED includes an anode, a light-emitting layer disposed over the anode, and a first electron-injecting layer disposed over the light-emitting layer, wherein the first electron-injecting layer includes at least one organic host material having a reduction potential less than −1.0 V vs. a Saturated Calomel Electrode and at least one dopant material capable of reducing the organic host material. The OLED also includes a second electron-injecting layer disposed in contact with the first electron-injecting layer, wherein the second electron-injecting layer includes at least one organic material having a reduction potential greater than −1.0 V vs. a Saturated Calomel Electrode, and a cathode disposed over the second electron-injecting layer.
摘要翻译： OLED包括阳极，设置在阳极上的发光层和设置在发光层上的第一电子注入层，其中第一电子注入层包括至少一种具有还原电位的有机主体材料 比-1.0V对饱和马氏体电极和能够还原有机主体材料的至少一种掺杂剂材料。 OLED还包括与第一电子注入层接触设置的第二电子注入层，其中第二电子注入层包括至少一种与饱和碳酸钙电极相比具有大于-1.0V的还原电位的有机材料， 以及设置在第二电子注入层上的阴极。
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公开(公告)号：US20080284318A1
公开(公告)日：2008-11-20
申请号：US11749899
申请日：2007-05-17
申请人： Joseph C. Deaton , Denis Y. Kondakov , Marina E. Kondakava , Kevin P. Klubek , Dustin L. Comfort
发明人： Joseph C. Deaton , Denis Y. Kondakov , Marina E. Kondakava , Kevin P. Klubek , Dustin L. Comfort
IPC分类号： H01J1/62
CPC分类号： H01L51/5044 , H01L51/0079 , H01L51/008 , H01L51/0081 , H01L51/0085 , H01L51/5016 , H01L2251/5376
摘要： An electroluminescent device comprises a) a fluorescent light emitting layer comprising a fluorescent emitter and a fluorescent host material wherein the HOMO energy level of the fluorescent host material is not more than 0.1 eV more negative than that of the fluorescent emitter; b) a phosphorescent light emitting layer comprising a phosphorescent emitter and a phosphorescent host material; and c) a spacer layer interposed between the fluorescent light emitting layer and the phosphorescent light emitting layer; wherein the triplet energy of the fluorescent host material is not more than 0.2 eV less than the triplet energy of both the spacer layer material and of the phosphorescent host material. The materials within these layers are selected so that the HOMO and triplet energy levels satisfy certain interrelationships. The invention provides devices that emit light with high luminous efficiency.
摘要翻译： 一种电致发光器件包括：a）包含荧光发射体和荧光主体材料的荧光发光层，其中荧光主体材料的HOMO能级不比荧光发射体的阴离子多0.1eV; b）包含磷光发射体和磷光主体材料的磷光发光层; 以及c）插入在荧光发光层和磷光发光层之间的间隔层; 其中所述荧光主体材料的三重态能量比所述间隔层材料和所述磷光主体材料的三线态能量小不超过0.2eV。 选择这些层内的材料，使得HOMO和三重态能级满足某些相互关系。 本发明提供发光效率高的装置。
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