公开(公告)号：US4661613A

公开(公告)日：1987-04-28

申请号：US655715

申请日：1984-09-28

申请人： Christian Prud'Homme ,  Gerard Simon

发明人： Christian Prud'Homme ,  Gerard Simon

IPC分类号： B01J23/00 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  C07B61/00 ,  C07F7/12 ,  C07F7/16

CPC分类号： C07F7/16

摘要： Dimethyldichlorosilane is directly prepared from methyl chloride and silicon, in high productivity, selectivity and degree of silicon conversion, by reacting methyl chloride with a solid contact mass comprising silicon and a catalytically effective amount of a catalyst which includes (1) elemental copper or a copper compound, (2) from about 30 to 1,000 ppm (calculated as metallic tin and/or antimony) of at least one of the metals tin and antimony, or at least one compound of at least one of the metals tin and antimony, and (3) from about 0.05 to 4% by weight, (calculated as cesium metal) of cesium or a cesium compound, or admixture of cesium with up to 90% by weight of the admixture of lithium, sodium, potassium or rubidium, the amounts of said components (2) and (3) being based upon the total weight of said solid contact mass.

摘要翻译： 通过使甲基氯与包含硅和催化有效量的催化剂的固体接触物质反应，以高生产率，选择性和硅转化率由甲基氯和硅直接制备二甲基二氯硅烷，其包括（1）元素铜或铜 化合物，（2）金属锡和锑中的至少一种金属的至少一种或至少一种金属锡和锑的化合物为约30至1,000ppm（以金属锡和/或锑计算）和（ 3）约0.05至4重量％（以铯金属计）铯或铯化合物，或铯与高达90重量％的锂，钠，钾或铷的混合物的混合物，其量为 所述组分（2）和（3）基于所述固体接触物质的总重量。

公开(公告)号：US4656301A

公开(公告)日：1987-04-07

申请号：US655729

申请日：1984-09-28

申请人： Christian Prud'Homme ,  Gerard Simon

发明人： Christian Prud'Homme ,  Gerard Simon

IPC分类号： B01J23/00 ,  B01J23/825 ,  B01J23/835 ,  C07B61/00 ,  C07F7/02 ,  C07F7/12 ,  C07F7/16

CPC分类号： C07F7/16

摘要： Dimethyldichlorosilane is directly prepared from methyl chloride and silicon, in high productivity, selectivity and degree of silicon conversion, by reacting methyl chloride with a solid contact mass comprising silicon and a catalytically effective amount of a catalyst which includes (1) elemental copper or a copper compound, (2) from about 30 to 1,000 ppm (calculated as metallic tin and/or antimony) of at least one of the metals tin and antimony, or at least one compound of at least one of the metals tin and antimony, and (3) from about 0.05 to 2% by weight, (calculated as alkali metal) of at least one of the alkali metals lithium, sodium, potassium and rubidium, or compound thereof, the amounts of said components (2) and (3) being based upon the total weight of said solid contact mass.

摘要翻译： 通过使甲基氯与包含硅和催化有效量的催化剂的固体接触物质反应，以高生产率，选择性和硅转化率由甲基氯和硅直接制备二甲基二氯硅烷，其包括（1）元素铜或铜 化合物，（2）金属锡和锑中的至少一种金属的至少一种或至少一种金属锡和锑的化合物为约30至1,000ppm（以金属锡和/或锑计算）和（ 3）约0.05〜2重量％（以碱金属计）碱金属锂，钠，钾和铷中的至少一种或其化合物，所述组分（2）和（3）的量为 基于所述固体接触物质的总重量。

公开(公告)号：US08596380B2

公开(公告)日：2013-12-03

申请号：US12958054

申请日：2010-12-01

申请人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

发明人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

IPC分类号： E21B47/00

CPC分类号： G01N27/026 ,  G01N33/287

摘要： The level of hydrogen sulfide in drilling fluid within a well formed in the Earth is assessed in an ongoing and/or in situ manner. The well may be constructed for the removal of hydrocarbons from the Earth. The assessment of hydrogen sulfide level may be provided in an ongoing manner such that real time, or near real time, fluctuations in hydrogen sulfide levels in the drilling fluid within the well may be conveyed to users. This may provide various advantages over systems in which drilling fluid must be extracted and separately tested for hydrogen sulfide content, and/or in which assessments of hydrogen sulfide level require time for performance.

公开(公告)号：US20070272056A1

公开(公告)日：2007-11-29

申请号：US10557848

申请日：2004-04-30

申请人： Gerard Simon

发明人： Gerard Simon

IPC分类号： C22B1/244 ,  C07F7/16

CPC分类号： C22B1/24 ,  C22B1/244 ,  C22B15/0058 ,  Y02P10/22

摘要： Process for agglomerating the pulverulent used material and/or the pulverulent fines resulting from the production of organohalosilanes, comprising the mixing of this used material and/or fines with a binder chosen from polysaccharides, in particular starches and dextrins, the addition to this mixture of an amount of water ranging from 3 to 10%, preferably from 4 to 8%, by weight, with respect to the used material+binder combination, the stirring of the solid mixture obtained in the preceding stage, in order to obtain a homogeneous mixture, and the production of a solid agglomerated product by compression in a press. Agglomerated product obtained.

摘要翻译： 包含将所用粉末材料和/或细粉与由多糖特别是淀粉和糊精混合的粘合剂混合使用的粉末使用材料和/或由生产有机卤代硅烷产生的粉状细粒的方法， 相对于所使用的材料+粘合剂组合物，在前一阶段获得的固体混合物的搅拌中，为了获得均匀的混合物，水的量为3至10重量％，优选4至8重量％ ，并且通过在压机中压缩生产固体附聚产物。 得到聚集体。

公开(公告)号：US20120138364A1

公开(公告)日：2012-06-07

申请号：US12958054

申请日：2010-12-01

申请人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

发明人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

IPC分类号： E21B49/00

CPC分类号： G01N27/026 ,  G01N33/287

摘要： The level of hydrogen sulfide in drilling fluid within a well formed in the Earth is assessed in an ongoing and/or in situ manner. The well may be constructed for the removal of hydrocarbons from the Earth. The assessment of hydrogen sulfide level may be provided in an ongoing manner such that real time, or near real time, fluctuations in hydrogen sulfide levels in the drilling fluid within the well may be conveyed to users. This may provide various advantages over systems in which drilling fluid must be extracted and separately tested for hydrogen sulfide content, and/or in which assessments of hydrogen sulfide level require time for performance.

公开(公告)号：US08596379B2

公开(公告)日：2013-12-03

申请号：US12957996

申请日：2010-12-01

申请人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

发明人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

IPC分类号： E21B47/00

CPC分类号： E21B47/102

摘要： The level of hydrogen sulfide in drilling fluid within a well formed in the Earth is assessed in an ongoing and/or in situ manner. The well may be constructed for the removal of hydrocarbons from the Earth. The assessment of hydrogen sulfide level may be provided in an ongoing manner such that real time, or near real time, fluctuations in hydrogen sulfide levels in the drilling fluid within the well may be conveyed to users. This may provide various advantages over systems in which drilling fluid must be extracted and separately tested for hydrogen sulfide content, and/or in which assessments of hydrogen sulfide level require time for performance.

摘要翻译： 在地球内形成的井内的钻井液中的硫化氢水平以持续和/或原位方式进行评估。 该井可能被构造用于从地球上除去碳氢化合物。 可以以持续的方式提供硫化氢水平的评估，使得井内的钻井液中的硫化氢水平的实时或接近实时的波动可以传送给用户。 这可以提供与其中必须提取钻井液并分别测试硫化氢含量的系统相比的系统，和/或其中硫化氢水平的评估需要执行时间的系统。

公开(公告)号：US4836997A

公开(公告)日：1989-06-06

申请号：US516843

申请日：1983-07-25

申请人： Jean-Luc Lepage ,  Gerard Simon

发明人： Jean-Luc Lepage ,  Gerard Simon

IPC分类号： C01B33/02 ,  C01B33/027 ,  C01B33/107

CPC分类号： C01B33/1071 ,  Y10S423/10

摘要： Trichlorosilane, SiHCl.sub.3, is facilely prepared by (i) thermally reducing silicon tetrachloride, SiCl.sub.4, with hydrogen to produce reaction admixture comprising SiHCl.sub.3 and hydrochloric acid, said thermal reduction being carried out in a thermal plasma while tempering the reaction medium with a cooling gas, (ii) reacting said step (i) reaction admixture with elemental silicon at a temperature of from about 250.degree. to 350.degree. C. to produce SiHCl.sub.3 and hydrogen therefrom, and thence (iii) separating (iiia) the plasma-creating, hydrogen and cooling gases, and (iiib) product silicon chlorides therefrom.

摘要翻译： 通过（i）用氢气还原四氯化硅（SiCl 4）以产生包含SiHCl 3和盐酸的反应混合物，容易地制备三氯硅烷，SiHCl 3，所述热还原在热等离子体中进行，同时用冷却气体回火反应介质， （ii）在约250℃至350℃的温度下使所述步骤（i）反应混合物与元素硅反应以从其中产生SiHCl 3和氢，然后（iii）将等离子体产生氢和 冷却气体，和（iiib）产物硅氯化物。

公开(公告)号：US20120138363A1

公开(公告)日：2012-06-07

申请号：US12957996

申请日：2010-12-01

申请人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

发明人： Benjamin Leonard ,  Gerard Simon ,  Gregory Russ Goddard

IPC分类号： E21B49/00 ,  G01R35/00

CPC分类号： E21B47/102

摘要： The level of hydrogen sulfide in drilling fluid within a well formed in the Earth is assessed in an ongoing and/or in situ manner. The well may be constructed for the removal of hydrocarbons from the Earth. The assessment of hydrogen sulfide level may be provided in an ongoing manner such that real time, or near real time, fluctuations in hydrogen sulfide levels in the drilling fluid within the well may be conveyed to users. This may provide various advantages over systems in which drilling fluid must be extracted and separately tested for hydrogen sulfide content, and/or in which assessments of hydrogen sulfide level require time for performance.

摘要翻译： 在地球内形成的井内的钻井液中的硫化氢水平以持续和/或原位方式进行评估。 该井可能被构造用于从地球上除去碳氢化合物。 可以以持续的方式提供硫化氢水平的评估，使得井内的钻井液中的硫化氢水平的实时或接近实时的波动可以传送给用户。 这可以提供与其中必须提取钻井液并分别测试硫化氢含量的系统相比的系统，和/或其中硫化氢水平的评估需要执行时间的系统。

公开(公告)号：US4405590A

公开(公告)日：1983-09-20

申请号：US358387

申请日：1982-03-15

申请人： Gerard Simon ,  Andre Soldat

发明人： Gerard Simon ,  Andre Soldat

IPC分类号： C01B33/04

CPC分类号： C01B33/043

摘要： The dismutation/redistribution of halogenosilanes into silane is carried out by contacting at least one halogenosilane comprising at least one Si-H function with a compound comprising at least one .alpha.-oxoamine group, then by contacting the products of such reaction with a compound also comprising at least one .alpha.-oxoamine group, to selectively dissolve all products of reaction except for the silane therein, and then separating the desired silane therefrom.

摘要翻译： 卤代硅烷对硅烷的歧化/重新分配是通过使包含至少一种Si-H官能团的至少一种卤代硅烷与包含至少一个α-氧代胺基团的化合物接触来进行的，然后通过使这种反应产物与还包含 至少一个α-氧代胺基团，以选择性地溶解除硅烷之外的所有反应产物，然后从其中分离所需的硅烷。