摘要:
A process for removing undesirable material such as a radioactive contaminant from an underlying material. A solution containing fluoroboric acid and a material which affects the fluoroboric acid solution oxidation potential (Eh) is contacted with the contaminant material to cause its removal. The contaminant material is removed from the fluoroboric acid solution by contacting the fluoroboric acid solution which has been contacted with the contaminant material with a cation exchange resin.
摘要:
Spent nuclear reactor coolant system decontamination solutions are processed to remove the radioactive burden and to separate metallic impurities using ion exchange resins within an electrochemical cell. The application of electric current to the electrochemical cell causes hydrogen ions to replace captured cations held on the ion exchange resin, thereby regenerating the resin for subsequent processing. The displaced cations migrate into the cathode compartment. The radioactive burden and metallic impurities are removed from the cathode compartment of the electrochemical cell. In a particularly preferred process, the cations are plated onto the cathode and disposed of as solids.
摘要:
A method for minimizing the radioactive waste produced by decontamination processes for water-cooled nuclear reactors. The method exposes the decontamination chemicals to the ionizing radiation emitted from the reactor fuel under controlled conditions to convert the decontamination chemicals into harmless gas phase products.
摘要:
Spent nuclear reactor coolant system decontamination solutions are first processed to remove the radioactive burden and to separate metallic impurities using cation exchange resins. The cation-processed waste solution is then flowed through an anion exchange resin held between anion-permeable membranes within an electrochemical cell. The application of electric current to the electrochemical cell causes hydroxide ions to replace captured anions held on the ion exchange resin, thereby regenerating the anion exchange resin for subsequent processing. The displaced anions migrate into the anode compartment where they can be oxidized to carbon dioxide for simple disposal.
摘要:
A method for operating the LOMI decontamination process in a regenerative manner. The method incorporates an initial injection of a dilute LOMI solution (vanadous formate, picolinic acid and sodium hydroxide) into a decontamination circuit followed by operation of a small cluster of cation exchange columns during the decontamination process. The cation exchange resin is used to remove metals in the same manner as in prior decontamination processes but operation of the cation exchange resin is continued to allow picolinic acid initially bound to the cation exchange resin to be released and recycled to the LOMI solution. Operation of the cation exchange columns ceases after the picolinic acid has been released but before the metals (e.g. sodium, iron and vanadium) are released back to the LOMI solution. The cluster of cation exchange columns are operated according to a sequence wherein one column is releasing picolinic acid while another is binding picolinic acid. The method further includes continuous additions of vanadous formate and sodium hydroxide. Clean-up at the end of the method proceeds in the normal manner wherein larger cation and anion exchange columns are utilized. Because the concentration of the components is much lower than conventional LOMI processes, however, the amount of cation exchange resin required at this stage is greatly reduced.
摘要:
A process for the removal of deposits consisting essentially of the oxides of one or more transition metals from a surface, which process comprises contacting the said surface at a pH in the range of from 2.0 to 7.0 with a reagent comprising a one-electron reducing agent which is the complex formed between a low oxidation state transition metal ion and a complexing agent, for destabilizing the metal oxides deposited, thereby increasing their rate of dissolution, the complexing agent being thermally stable at the operating pH and present in order to form the necessary complex reagent and also to increase the thermodynamic solubility of the metal ions released.
摘要:
A dispensing structure is provided for a container that has an opening from which a product can be dispensed. The structure includes a body for extending around the container opening. A foraminous member is provided with a plurality of dispensing holes and is movable between a closed position and an open position. A lid is provided for sealingly occluding the foraminous member and for moving between a closed position and an open position.
摘要:
A dispensing structure is provided for an opening to a container. The dispensing structure includes a body for extending from the container around the opening. The dispensing structure defines a discharge aperture communicating with the container opening. An actuator, which defines a pivot axis, is pivotally mounted on the body for occluding flow from the container through the discharge aperture when the actuator is in a closed position and permitting flow from the container when force is applied to the actuator to tilt the actuator to an open position. The actuator includes a first, generally rigid piece which is molded from a material and which defines a force-receiving region on one side of the pivot axis. The actuator includes a second piece which is molded from a material onto the first, rigid, force-receiving region and is bonded to the first, rigid piece to define a finger pad against which a finger may be pressed to tilt the actuator to the open position.
摘要:
A sealing and dispensing closure for the outlet opening of a package, such as a flexible plastic bottle containing a consumable beverage. The closure comprises a closure base which is threaded onto the outlet opening of the bottle, and a removable overcap which is pivotally connected to the closure base. The closure base includes a spout having a self-sealing dispensing valve therein which is movable from a lowered closed position to a raised open position by an increased pressure in the bottle resulting from the squeezing of the bottle. The valve is positioned at a recessed location within the spout so as to preclude access to the valve by the consumer when the valve is lifted to its raised open position, and the overcap includes a post which seats in the upper end of the spout when the overcap is mounted on the closure base, and so as to form a hermetically sealed chamber above the valve which prevents the valve from lifting to its raised position in the event the bottle is inadvertently squeezed.
摘要:
A dispensing structure is provided for a container which has an opening to the container interior. The structure includes a body for extending around the container opening and a membrane for occluding the container opening. A cover is disposed over the membrane and is sealingly engaged with the body to accommodate axial sliding movement from an outer position to an inwardly displaced position. The cover defines a dispensing orifice and defines an edge for severing at least part of the membrane as the cover is moved from the outer position to the inwardly displaced position. An additive material may be initially stored in the dispensing structure above the membrane and can be combined with the product in the container after the membrane has been severed. A self-sealing, pressure-openable, slit-type valve may be mounted in the cover at the dispensing orifice to control flow through the orifice.