公开(公告)号：US09359226B2

公开(公告)日：2016-06-07

申请号：US13230168

申请日：2011-09-12

Applicant: Chang Hyun Kim ,  Hyun Seok Kim ,  Hyo Rang Kang ,  Ho Jung Yang ,  Joo Wook Lee ,  Bok Soon Kwon ,  Jae Eun Kim

Inventor： Chang Hyun Kim ,  Hyun Seok Kim ,  Hyo Rang Kang ,  Ho Jung Yang ,  Joo Wook Lee ,  Bok Soon Kwon ,  Jae Eun Kim

IPC: B01D61/00 ,  C02F1/28 ,  B01D61/44 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/12 ,  B01J20/18 ,  B01J20/20 ,  B01J20/32 ,  B01J20/34 ,  C02F1/461 ,  C02F1/469 ,  B01J20/02 ,  B01J20/28 ,  B82Y30/00 ,  B01J47/08 ,  B01J49/00 ,  C02F1/00 ,  C02F1/42 ,  C02F1/66 ,  C02F101/10 ,  C02F101/12 ,  C02F101/20 ,  C02F101/36

CPC classification number: C02F1/283 ,  B01D61/00 ,  B01D61/445 ,  B01D2311/2626 ,  B01D2313/345 ,  B01D2313/36 ,  B01D2313/40 ,  B01J20/02 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/12 ,  B01J20/18 ,  B01J20/20 ,  B01J20/205 ,  B01J20/28007 ,  B01J20/3204 ,  B01J20/3234 ,  B01J20/3416 ,  B01J20/3433 ,  B01J20/3441 ,  B01J47/08 ,  B01J49/30 ,  B01J2220/42 ,  B82Y30/00 ,  C02F1/28 ,  C02F1/281 ,  C02F1/285 ,  C02F1/288 ,  C02F1/42 ,  C02F1/46104 ,  C02F1/469 ,  C02F1/66 ,  C02F2001/46119 ,  C02F2101/103 ,  C02F2101/12 ,  C02F2101/20 ,  C02F2101/36 ,  C02F2201/003 ,  C02F2201/46115 ,  C02F2201/46135 ,  C02F2201/46145 ,  C02F2201/4615 ,  C02F2201/4618 ,  C02F2209/05 ,  C02F2301/08 ,  C02F2303/16 ,  C02F2305/08

Abstract: A filter unit may include an electrode structure, a fluid-purifying flow path, and a pH adjusting chamber. The electrode structure may include a cathode, a cation exchange membrane, an anion exchange membrane, and an anode in that order. The fluid-purifying flow path may be at least one of a path in the cathode, between the cathode and the cation exchange membrane, between the anion exchange membrane and the anode, and in the anode. The fluid-purifying flow path may include an adsorption function. The pH adjusting chamber may be between the cation exchange membrane and the anion exchange membrane. The pH adjusting chamber may be configured to control the pH of the fluid in the fluid-purifying flow path.

Abstract translation: 过滤器单元可以包括电极结构，流体净化流路和pH调节室。 电极结构可以依次包括阴极，阳离子交换膜，阴离子交换膜和阳极。 流体净化流路可以是阴极，阴极和阳离子交换膜之间，阴离子交换膜和阳极之间以及阳极中的至少一个。 流体净化流路可以包括吸附功能。 pH调节室可以在阳离子交换膜和阴离子交换膜之间。 pH调节室可以被配置为控制流体净化流路中的流体的pH。

公开(公告)号：US20090114598A1

公开(公告)日：2009-05-07

申请号：US11795998

申请日：2005-12-21

Applicant: Cornelis Gerhard van Kralingen ,  Hank Robert Reinhoudt ,  Harm Jan Riksen

Inventor： Cornelis Gerhard van Kralingen ,  Hank Robert Reinhoudt ,  Harm Jan Riksen

IPC: C02F5/00 ,  B01J47/08 ,  C02F1/42 ,  C02F103/00

CPC classification number: C02F1/4691 ,  A47L15/4229 ,  C02F1/4618 ,  C02F2301/043 ,  D06F39/007

Abstract: The present invention provides a water softening device for application in a household appliance comprising a flow-through capacitor for the production of wash amplified water (WAW) from tap water, having less than 5° FH, being suitable for use in said appliance when the device is in operation; the configuration of the device is such that the capacitor can be regenerated, whereby no added substances are used. Said washing machine being suitable for use with low environmental impact detergent products.

Abstract translation: 本发明提供一种用于家用电器的水软化装置，其包括用于从具有小于5°FH的自来水生产洗涤放大水（WAW）的流通电容器，适用于所述电器 设备正在运行; 该装置的结构使得可以再生电容器，由此不使用添加的物质。 所述洗衣机适用于低环境影响的洗涤剂产品。

公开(公告)号：US20050167271A1

公开(公告)日：2005-08-04

申请号：US10506517

申请日：2002-04-02

Applicant: Ryszard Gajek

Inventor： Ryszard Gajek

IPC: B01D57/02 ,  B01D61/48 ,  B01J47/08 ,  B01J49/00 ,  C02F3/34 ,  G01N1/40 ,  G01N27/27

CPC classification number: C02F3/342 ,  B01D57/02 ,  B01D61/48 ,  B01J47/08 ,  B01J49/30 ,  C02F3/34 ,  C02F2101/306 ,  C02F2101/32 ,  C02F2101/36 ,  C02F2101/366 ,  G01N2001/4038

Abstract: An ion is eluted from an ion exchange resin (132) in a separation system (100) using an eluent generated by electrolysis of a medium. Elution is further assisted by an electrical field between two electrodes (120, 110), wherein the ion exchange resin (132) is at least partially disposed between the electrodes. Particularly preferred aspects of such separation systems include gradient separation and buffered electrodialysis.

Abstract translation: 使用由介质电解产生的洗脱液，在分离系统（100）中从离子交换树脂（132）中洗脱离子。 洗涤进一步由两个电极（120,110）之间的电场辅助，其中离子交换树脂（132）至少部分地设置在电极之间。 这种分离系统的特别优选的方面包括梯度分离和缓冲电渗析。

公开(公告)号：US20050103724A1

公开(公告)日：2005-05-19

申请号：US10712674

申请日：2003-11-13

Applicant: Frederick Wilkins ,  Evgeniya Freydina ,  Aytac Sezgi ,  Reshma Madhusudan ,  Anil Jha

Inventor： Frederick Wilkins ,  Evgeniya Freydina ,  Aytac Sezgi ,  Reshma Madhusudan ,  Anil Jha

IPC: B01D61/48 ,  B01J47/08 ,  C02F1/28 ,  C02F1/32 ,  C02F1/42 ,  C02F1/44 ,  C02F1/46 ,  C02F1/469 ,  C02F1/48 ,  C02F1/78 ,  C02F9/00

CPC classification number: C02F9/005 ,  B01D61/48 ,  B01J47/08 ,  C02F1/001 ,  C02F1/283 ,  C02F1/32 ,  C02F1/42 ,  C02F1/444 ,  C02F1/4602 ,  C02F1/469 ,  C02F1/4695 ,  C02F1/78 ,  C02F2201/4613 ,  C02F2201/4618 ,  C02F2209/05

Abstract: A method and apparatus for producing purified water. An electrochemical system can be configured to pass product water through depletion compartments as well as a cathode compartment. An electrochemical apparatus may also be configured to pass concentrate through both concentrating compartments and an anode compartment.

Abstract translation: 一种生产纯净水的方法和装置。 电化学系统可以被配置为使产品水通过耗尽室和阴极室。 电化学装置也可以被配置为使浓缩物通过两个浓缩室和阳极室。

公开(公告)号：US6024850A

公开(公告)日：2000-02-15

申请号：US815371

申请日：1997-03-10

Applicant: Richard L. Sampson ,  Allison H. Sampson

Inventor： Richard L. Sampson ,  Allison H. Sampson

IPC: B01D61/48 ,  B01J47/08 ,  B01J49/00 ,  C02F1/42 ,  C02F1/461 ,  C02F1/467 ,  C25B13/00

CPC classification number: B01J49/0052 ,  B01D61/48 ,  B01J47/08 ,  C02F1/46114 ,  C02F1/4618 ,  C02F1/4672 ,  C02F1/4674 ,  C02F1/42 ,  C02F1/4676 ,  C02F1/4695 ,  C02F2001/46138 ,  C02F2001/46161 ,  C02F2103/023 ,  C02F2103/42 ,  C02F2201/46115 ,  C02F2201/4613 ,  C02F2201/46145 ,  C02F2201/4617 ,  C02F2303/04

Abstract: Ion exchange materials, as particulate and membranes, are modified by permanently attaching counter ions to a portion of the ion exchange sites. The permanent attachment of the counter ions forms semiconductor junctions which act as mini anodes, or cathodes, to significantly increase the ability to oxidize or reduce a species to be treated, or split water, in an electrolytic reactor. The non-converted transfer sites in the ion exchange material also significantly increase the mobility of the ionic species in the electrolyte. The ion exchange material may be a monobed of either modified anion exchange material or modified cation exchange material, or a suitable mixed bed of both, depending upon the application. When the anode is in direct contact with a modified cation exchange material and under the influence of direct current, free radical hydroxyl and regenerant hydrogen are formed. When the cathode is in direct contact with a modified anion exchange material and under the influence of direct current, free radical hydrogen and regenerant hydroxyl are formed. Alternatively, the modified ion exchange material can be separated from both the anode and the cathode, and regenerant hydrogen and hydroxyl are produced at the semiconductor junctions.

Abstract translation: 作为颗粒和膜的离子交换材料通过将抗衡离子永久地附着到一部分离子交换位点而被修饰。 抗衡离子的永久附着形成用作微型阳极或阴极的半导体结，以显着增加在电解反应器中氧化或还原待处理物质或裂解水的能力。 离子交换材料中未转化的转移位点也显着增加了电解质中离子物质的迁移率。 取决于应用，离子交换材料可以是改性阴离子交换材料或改性阳离子交换材料或两者的合适混合床的单支。 当阳极与改性阳离子交换材料直接接触并在直流电的影响下，形成自由基羟基和再生氢。 当阴极与改性阴离子交换材料直接接触时，在直流影响下，形成自由基氢和再生羟基。 或者，改性离子交换材料可以从阳极和阴极两者分离出来，在半导体结处产生再生氢和羟基。

公开(公告)号：US5948230A

公开(公告)日：1999-09-07

申请号：US119137

申请日：1998-07-20

Applicant: Wayne A. McRae

Inventor： Wayne A. McRae

IPC: A23C9/144 ,  B01D61/44 ,  B01D61/46 ,  B01D61/48 ,  B01D61/58 ,  B01J47/08 ,  C01B11/04 ,  C01B11/06 ,  C02F1/42 ,  C02F1/44 ,  C02F1/467 ,  C02F1/469 ,  C02F9/00

CPC classification number: A23C9/144 ,  B01D61/44 ,  B01D61/48 ,  B01D61/58 ,  B01J47/08 ,  C01B11/04 ,  C01B11/06 ,  C02F1/441 ,  C02F1/469 ,  B01D61/025 ,  B01D61/027 ,  B01D61/145 ,  B01D61/147 ,  B01D61/422 ,  C02F1/42 ,  C02F1/44 ,  C02F1/4674 ,  C02F1/4693 ,  C02F1/4695 ,  C02F2101/163 ,  C02F2201/46115 ,  C02F9/00

Abstract: Improved electrodialysis (ED) stacks are disclosed having one or more components selected from the group:a) cation exchange membranes having ion exchange groups predominantly sulfonic acid groups and a minor amount of weakly acidic and/or weakly basic groups or membranes which are selective to monovalent cations and simultaneously therewith, cation exchange granules selective to monovalent cations as packing in the dilute compartments;b) anion exchange membranes having as ion exchange groups only quaternary ammonium and/or quaternary phosphonium groups and substantially no primary, secondary and/or tertiary amine and/or phosphine groups or membranes which are selective to monovalent anions simultaneously therewith, anion exchange granules selective to monovalent anions as packing in the dilute compartments;c) as packing in the dilute compartment, anion exchange granules which are selective to monovalent anions, or cation exchange granules which are selective to monovalent cations, or cation exchange granules having as exchange groups a predominant amount of sulfonic acid groups and a minor amount of weakly acidic and/or weakly basic groups, or anion exchange granules consisting of organic polymers having as anion exchange groups only quaternary ammonium and/or quaternary phosphonium groups and almost no primary, secondary and/or tertiary amine and/or phosphine groups.

Abstract translation: 公开了改进的电渗析（ED）堆叠，其具有一个或多个选自以下的组分：a）具有主要为磺酸基团的离子交换基团和少量弱酸性和/或弱碱性基团或膜的阳离子交换膜， 一价阳离子，同时具有选择性的阳离子交换颗粒，作为填充在稀室中的一价阳离子; b）具有作为离子交换基团的离子交换基团的阴离子交换膜仅具有季铵和/或季鏻基团，并且基本上不具有与单价阴离子同时选择性的伯，仲和/或叔胺和/或膦基或膜，阴离子交换颗粒选择性 作为包装在稀释室中的单价阴离子; c）作为稀释室中的填料，对单价阴离子有选择性的阴离子交换颗粒，或对一价阳离子有选择性的阳离子交换颗粒，或具有主要量的磺酸基和交替基团的阳离子交换颗粒， 弱酸性和/或弱碱性基团或由具有阴离子交换基团的有机聚合物组成的阴离子交换颗粒仅为季铵和/或季鏻基团，并且几乎不具有伯，仲和/或叔胺和/或膦基团。

公开(公告)号：US5830362A

公开(公告)日：1998-11-03

申请号：US699860

申请日：1996-08-20

Applicant: Olivier Leclerc

Inventor： Olivier Leclerc

IPC: C07D333/16 ,  B01J45/00 ,  B01J47/08 ,  C07D207/32 ,  C07D207/325 ,  C07D207/333 ,  C07D333/34 ,  C07D333/38 ,  C07D498/22 ,  C08G61/12 ,  C08G65/32 ,  C08G65/333 ,  C08L71/02 ,  C08L79/04 ,  C25B3/00 ,  C02F1/62 ,  C08F116/12 ,  C08F126/06 ,  C08F128/06

CPC classification number: C07D207/325 ,  B01J45/00 ,  B01J47/08 ,  C08G61/123 ,  C08G65/33317 ,  C08L71/02 ,  C08L79/04 ,  Y02P20/55 ,  Y10S210/912

Abstract: It concerns a monomer, a polymer obtained from the monomer and a process for obtaining the said polymer. The monomer consists of a polyether containing at least 3 ether units and pyrrole or thiophene units bonded to the ends of the chains of this polyether via, for each of these heterocycic compounds, either their carbon atoms in the 3,3'-positions of their heterocycles or, as regards more particularly the pyrrole groups, via their respective nitrogen atoms, the 2- and 2'-positions of these heterocycles being, however, free of all substitutions or, at the very most, substituted by easily removable groups (protective groups, for example). Application to the purification and recovery of metal ions such as radioactive silver.

Abstract translation: 它涉及单体，从单体获得的聚合物和获得所述聚合物的方法。 单体由含有至少3个醚单元的聚醚和与该聚醚的链末端键合的吡咯或噻吩单元组成，对于这些杂环化合物中的每一个，它们的3,3'位的碳原子 或者更具体地说是吡咯基团，通过它们各自的氮原子，这些杂环的2位和2位不过是全部取代，或者最多被易于除去的基团取代（保护性 组）。 应用于金属离子如放射性银的纯化和回收。

公开(公告)号：US5766442A

公开(公告)日：1998-06-16

申请号：US829614

申请日：1997-03-31

Applicant: Nevill John Bridger ,  Andrew Derek Turner

Inventor： Nevill John Bridger ,  Andrew Derek Turner

IPC: C02F1/42 ,  B01J47/06 ,  B01J47/08 ,  B01J49/00 ,  C25B11/00 ,  C25B11/03 ,  C25B11/04 ,  C25B15/08 ,  G01N27/30 ,  G01N27/38 ,  H02G1/08

CPC classification number: B01J47/08 ,  B01J49/0052

Abstract: An electrode for use in electrochemical ion exchange which includes a hydrolysable metal phosphate such as zirconium phosphate (Zr(HPO.sub.4).sub.2) which has been hydrolysed at least in part is regenerated. The electrode is made the anode of an electrochemical cell in which the electrolyte is an aqueous solution containing one or more phosphate ions provided, for example, by a dissolved salt (eg Na.sub.3 PO.sub.4, Na.sub.2 HPO.sub.4 or NaH.sub.2 PO.sub.4) or orthophosphoric acid, or both. Preferably, the electrolyte is acidic (eg pH 2). Operation of the cell reverses the hydrolysis reaction and enhances the performance of the electrode.

Abstract translation: 用于电化学离子交换的电极，其包括至少部分被水解的可水解金属磷酸盐如磷酸锆（Zr（HPO 4）2）。 电极被制成电化学电池的阳极，其中电解质是含有例如由溶解的盐（例如Na 3 PO 4，Na 2 HPO 4或NaH 2 PO 4）或正磷酸或两者提供的一种或多种磷酸根离子的水溶液。 优选地，电解质是酸性的（例如pH 2）。 电池的操作反转水解反应并提高电极的性能。

公开(公告)号：US5748437A

公开(公告)日：1998-05-05

申请号：US653832

申请日：1996-05-28

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/08 ,  B01D15/00 ,  B01J47/08 ,  C02F1/00 ,  C02F1/46 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96 ,  H01G4/35

CPC classification number: G01N30/6069 ,  B01D15/36 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/6095 ,  G01N30/80

Abstract: A flow-through capacitor and a controlled charge chromatography column system using the capacitor for the purification of a fluid-containing material, which column comprises an inlet for a fluid to be purified and an outlet for the discharge of the purified fluid, and a flow-through capacitor disposed within the column. The flow-through capacitor comprises a plurality of spirally-wound, stacked washer or rods to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to one side of the backing layer, such as carbon fibers, and a second high surface area conductive layer secured to the opposite side of the backing layer, the high surface area material layers arranged to face each other and separated by a nonconductive, ion-permeable spacer layer to insulate electrically the backing and conductive layer. The system includes a DC power source to charge the respective conductive layers with different polarities whereby a fluid-containing material passing through the column is purified by the electrically conductive, high surface area stationary phase and the retention thereof onto the high surface area layer and permitting, for example, the purification of aqueous solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种流通电容器和使用电容器的受控电荷色谱柱系统，用于净化含流体的材料，该柱包括用于待净化的流体的入口和用于排出纯化流体的出口， 通过电容器设置在该列内。 流通电容器包括多个螺旋卷绕的层叠的垫圈或杆，以包括第一导电背衬层，例如石墨，以及固定到背衬层的一侧的第一高表面积导电层，例如 碳纤维和固定到背衬层的相对侧的第二高表面积导电层，高表面积材料层布置为彼此面对并由不导电的离子可渗透间隔层隔开，以使背衬和导电 层。 该系统包括一个直流电源，用于以不同的极性对相应的导电层进行充电，由此通过该柱的含流体的材料被导电的高表面积固定相净化，并将其保留在高表面积层上并允许 例如，纯化诸如盐的液体的水溶液，并提供回收纯化液体。

公开(公告)号：US5744023A

公开(公告)日：1998-04-28

申请号：US602842

申请日：1996-02-27

Applicant: Norihiro Kakimoto ,  Keiji Umeda ,  Takashi Ichimura

Inventor： Norihiro Kakimoto ,  Keiji Umeda ,  Takashi Ichimura

IPC: C12P19/24 ,  B01D61/44 ,  B01D61/54 ,  B01J31/40 ,  B01J47/08 ,  B01J47/12 ,  C07F7/30 ,  C07H1/00 ,  C13D1/00 ,  C13D3/18

CPC classification number: C07F7/30 ,  B01D61/44

Abstract: An electric current is passed through a mixed solution containing a saccharide(s) and an organogermanium compound, in a compartment whose anode side is defined by an anion exchange membrane and whose cathode side is defined by a cation exchange membrane, to separate and remove said organogermanium compound. In the present invention, an organogermanium compound can be very effectively separated and recovered from a mixed solution containing a saccharide(s) and said organogermanium compound. The present invention is particularly effective for separation and recovery of an organogermanium compound from a reaction mixture obtained when a compound having an aldose structure is isomerized into a compound having a ketose structure in the presence of said organogermanium compound.

Abstract translation: PCT No.PCT / JP95 / 01286 Sec。 371日期1996年2月27日 102（e）日期1996年2月27日PCT提交1995年6月28日PCT公布。 公开号WO96 / 00731 日期1996年1月11日电流通过含有糖类和有机锗化合物的混合溶液，其阳极侧由阴离子交换膜限定，阴极侧由阳离子交换膜限定， 以分离和去除所述有机锗化合物。 在本发明中，可以从含有糖类和所述有机锗化合物的混合溶液中非常有效地分离和回收有机锗化合物。 当在所述有机锗化合物存在下将具有醛糖结构的化合物异构化成具有酮糖结构的化合物时，本发明特别有效地从有机锗化合物中分离和回收得到的反应混合物。